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161.
The hole-drilling method is a residual-stress measurement technique in which a blind hole (usually 1.6 mm or 3.2 mm in diameter) is drilled into a material and the strain perturbances around the hole are measured by surfacemounted strain gages. The conventional hole-drilling-method procedure is to analyze the net strain changes due to the drilling of the full-depth hole (usually about 100 percent of hole diameter) and to interpret the resulting stress calculations insofar as they represent the average stresses through the hole depth. It has been determined that this procedure may lead to significant errors, particularly where there are large stress variations through the hole depth. Such errors may be difficult to detect simply by observing the strain data. This paper describes a finite-element procedure which was used to develop calibration constants to allow measurements of residual-stress variation with depth to be routinely performed by the hole-drilling method. 相似文献
162.
A stability index is computed for the n-covered circular equilibria of inextensible-unshearable elastic rods with constant planar intrinsic curvature û and constant values for the twisting stiffness and two bending stiffnesses. A simple expression is derived for the index as a function of û, (the ratio of bending stiffness out of the plane of curvature to bending stiffness in the plane of curvature), and (the ratio of twisting stiffness to bending stiffness in the plane of curvature). In particular, for intrinsically straight rods (û = 0) we prove that the 1-covered circle is stable if and only if 1, and the n-covered circle (n>1) is stable if and only if >1, >1, and
The index is computed by framing the standard Euler–Lagrange equations of equilibrium within a constrained variational principle with an isoperimetric constraint ensuring the ring closure. The fact that
appears linearly in the second variation allows the second variation to be diagonalized using the eigenfunctions of an appropriate eigenvalue problem similar to a Sturm–Liouville problem. This diagonalization allows the direct computation of an unconstrained index (disregarding ring closure). We then apply a result of Maddocks (SIAM J. Math. Anal.
16 (1985) 47–68) to find the constrained index in terms of this unconstrained index and a correction computable from the linearized constraint.With numerical computations, we verify these analytic results on n-covered circles and determine the index of non-circular equilibria bifurcating from the branches of n-covered circles. 相似文献
163.
Evans J Levason W Manning JM Reid G Tsoureas N Webster M 《Dalton transactions (Cambridge, England : 2003)》2007,(20):1986-1988
Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described. 相似文献
164.
荧光寿命的快速傅里叶变换拟合方法 总被引:5,自引:2,他引:5
介绍了一种利用快速傅里叶变换算法对稀土掺杂物质的荧光寿命进行数据拟合的方法。稀土掺杂物质可用来制备多种光学传感器,用于温度、pH值等多种参量测量领域。本方法利用快速傅里叶变换(FFT)结果作为基础,从非零项的相位角的正切值得出被测的荧光寿命,具有速度快、误差小、不受本底干扰等一系列优点。以掺铒光纤为例,通过数字仿真将本方法与其它几种传统的拟合方法进行了比较。快速傅里叶变换方法的测量偏差不到Prony方法的50%,为对数似合(log-fit)方法测量偏差的1/6。另外,快速傅里叶变换方法由于不受本底噪声影响,可以不必在信号处理时去掉本底噪声,因而可以明显缩短测量时间。 相似文献
165.
Abstract A 27.12 MHz low flow (3 1/min), laminar flow, atmospheric pressure neon ICP has been generated. The forward power used is 500 W with a reflected power of less than 5 W. Using higher powers caused the plasma to either extinguish or form numerous filaments. The Hß line is used to determine an electron number density of 8 × 1013cm?3. The N2 +(0, 0) and OH(0, 0) transitions did not readily emit. This fact, coupled with the low electron density and low input power, indicates a relatively cool plasma. 相似文献
166.
167.
Matthew Bennett Vyjayanthi Chari R. J. Dolbin Nathan Manning 《Journal of Algebraic Combinatorics》2011,34(1):1-18
For each integer k≥1, we define an algorithm which associates to a partition whose maximal value is at most k a certain subset of all partitions. In the case when we begin with a partition λ which is square-bounded, i.e. λ=(λ
1≥⋅⋅⋅≥λ
k
) with λ
1=k and λ
k
=1, applying the algorithm ℓ times gives rise to a set whose cardinality is either the Catalan number c
ℓ−k+1 (the self dual case) or twice that Catalan number. The algorithm defines a tree and we study the propagation of the tree,
which is not in the isomorphism class of the usual Catalan tree. The algorithm can also be modified to produce a two-parameter
family of sets and the resulting cardinalities of the sets are the ballot numbers. Finally, we give a conjecture on the rank
of a particular module for the ring of symmetric functions in 2ℓ+m variables. 相似文献
168.
Ashraf M. El-Sayed C. Rikard Unelius Andrew Twidle Lee-Anne Manning David M. Suckling Tania Zaviezo 《Tetrahedron letters》2010,51(7):1075-1078
Headspace volatiles collected from virgin females of the citrophilous mealybug, Pseudococcus calceolariae, contain three compounds not present in the headspace of control samples. The main female-specific compound is identified as [2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropyl]methyl 2-acetoxy-3-methylbutanoate (chrysanthemyl 2-acetoxy-3-methylbutanoate). The other two compounds are identified as [2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropyl]methanol (chrysanthemol) and [2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropyl]methyl 2-hydroxy-3-methylbutanoate (chrysanthemyl 2-hydroxy-3-methylbutanoate). Traps baited with 100 μg and 1000 μg of chrysanthemyl 2-acetoxy-3-methylbutanoate captured 4- and 20-fold more males than traps baited with virgin females. 相似文献
169.
N. P. Edwards R. A. Wogelius U. Bergmann P. Larson W. I. Sellers P. L. Manning 《Applied Physics A: Materials Science & Processing》2013,111(1):147-155
The detailed chemical analysis of fossils has the potential to reveal great insight to the composition, preservation and biochemistry of ancient life. Such analyses would ideally identify, quantify, and spatially resolve the chemical composition of preserved bone and soft tissue structures, but also the embedding matrix. Mapping the chemistry of a fossil in situ can place constraints on mass transfer between the enclosing matrix and the preserved organism(s), and therefore aid in distinguishing taphonomic processes from original chemical zonation remnant within the fossils themselves. Conventional analytical methods, such as scanning electron microscopy (SEM) and pyrolysis–gas chromatography/mass spectrometry (Py-GC/MS) have serious limitations in this case, primarily, an inability to provide large (i.e., decimeter) scale chemical maps. Additionally, vacuum chamber size and the need for destructive sampling preclude analysis of large and precious fossil specimens. However, the recent development of Synchrotron Rapid Scanning X-ray Fluorescence (SRS-XRF) at the Stanford Synchrotron Radiation Lightsource (SSRL) allows the non-destructive chemical analysis and imaging of major, minor, and trace element concentrations of large paleontological and archeological specimens in rapid scanning times. Here we present elemental maps of a fossil reptile produced using the new SRS-XRF method. Our results unequivocally show that preserved biological structures are not simply impressions or carbonized remains, but possess a remnant of the original organismal biochemistry. We show that SRS-XRF is a powerful new tool for the study of paleontological and archaeological samples. 相似文献
170.
The protonation sequence of DTPA is evaluated using a 300 MHz H NMR instrument. A terminal nitrogen is protonated first (pKa1,2=10.02, 8.45). Upon the first protonation a dynamic hydrogen bonded five membered ring is formed between the terminal nitrogen and the central nitrogen. The second equivalent of protons protonates the opposite terminal amine and causes the ring to open. The third protonation (pKa3=4.65) takes place on the central acetate and forms a ring with the central amine. The fourth protonation is assigned to a terminal acetate. The formation of five membered rings involving hydrogen bonding gives a better quantitative and qualitative account for the unusual shifts observed in the H NMR spectra than previous explanations. 相似文献