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51.
A. Steinboeck A. Kugi H.A. Mang 《International Journal of Solids and Structures》2013,50(11-12):1859-1868
An exact computational method for the shear stiffness of beams with circular cross sections and arbitrarily radially inhomogeneous Young’s modulus is presented. We derive the displacement and stress field of a cantilever beam according to 3D theory of elasticity, which requires to solve just a 1D linear boundary value problem. The shear stiffness is obtained by setting the shear strain energy from the exact solution equal to that from technical beam theory. Results and closed analytical formulae are given for several functionally graded and layered cross sections. 相似文献
52.
研究了一种新型的有机/无机杂化钙钛矿材料(3-BrC3H6NH3)2CuBr4薄膜的聚集态形貌和良好的微观有序性特征, 霍尔迁移率测试结果表明该材料为p型半导体, 空穴迁移率为0.0025 cm2•V-1•s-1. 利用其在紫外-可见光谱范围内与C60薄膜具有良好的光吸收互补性, 制备并研究了(3-BrC3H6NH3)2CuBr4/C60层状异质结结构中的暗态传输和光伏性能. 对不同退火温度下杂化钙钛矿薄膜的聚集态特性和器件性能之间的联系进行了探讨, 结果表明在低温退火条件下, 由于钙钛矿结构材料中有机组分排列更加有序, 器件显示更好的性能. 相似文献
53.
莽朝永 《原子与分子物理学报》2014,31(6)
采用梯度校正的密度泛函理论方法,计算了云南松松塔中分离的2种新木脂素的绝对结构为7S,8R的手性结构、电子吸收光谱、电子圆二色谱、红外振动光谱和振动圆二色谱,计算值与实验值相符. 分子轨道和振动模式分析,两种新木质素具有相似的手性光谱. 电荷密度转移对电子圆二色谱具有主要贡献;而振动圆二色谱主要源于分子骨架运动. 相似文献
54.
变压器两侧常建有高大的防火墙,其从声学角度可视为刚性反射壁面,会改变变压器的辐射声场,进而影响变压器声功率测量结果。本文利用有限元、边界元等数值计算方法建立了变压器声辐射的仿真模型用以分析反射壁面对变压器声功率测量结果的影响,并通过实际测量验证了仿真计算所得结论。结果表明,反射壁面对变压器声功率测量结果的影响程度随反射壁面到变压器箱体距离增加而减弱,且当反射壁面距变压器箱体5 m以上时,其对变压器声功率基频及各谐波成份测量结果的影响均在2 dB以内。另外反射壁面对变压器噪声高频成份声功率测量结果的影响较大,而对100 Hz、200 Hz等低频成份测量结果影响较小,基本低于3 dB。 相似文献
55.
Irreversibility of a quantum walk induced by controllable decoherence employing random unitary operations 下载免费PDF全文
Quantum walk is different from random walk in reversibility and interference. Observation of the reduced re- versibility in a realistic quantum walk is of scientific interest in understanding the unique quantum behavior. We propose an idea to experimentally investigate the decoherence-induced irreversibility of quantum walks with trapped ions in phase space via the average fidelity decay. By introducing two controllable decoherence sources, i.e., the phase damping channel (i.e., dephasing) and the high temperature amplitude reservoir (i.e., dissipation), in the intervals between the steps of quantum walk, we find that the high temperature amplitude reservoir shows more detrimental effects than the phase damping channel on quantum walks. Our study also shows that the average fidelity decay works better than the position variance for characterizing the transition from quantum walks to random walk. Experimental feasibility to monitor the irreversibility is justified using currently available techniques. 相似文献
56.
Synthesis of MCM-22 zeolite using rice husk as a silica source under varying-temperature conditions 总被引:1,自引:0,他引:1
Cheng Y Lu M Li J Su X Pan S Jiao C Feng M 《Journal of colloid and interface science》2012,369(1):388-394
In this study, rice husk, an abundant agricultural byproduct, was utilized as an alternative silica source for the synthesis of MCM-22. The zeolite with high crystalline was synthesized using a three-stage varying-temperature hydrothermal method. The prepared silica and MCM-22 were characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The results showed that the duration required for zeolite crystallization was significantly decreased under varying-temperature conditions. The MCM-22 was in the form of thin platelet-like crystals, and no amorphous material existed in the framework of the MCM-22 after calcination and ammonium exchange. Cationic brilliant red 5GN, a basic dye used in the wool and blanket factories for fiber dyeing, was selected as the adsorptive to study the adsorption performance of the MCM-22. Adsorption experiments indicated that the maximum extent of adsorption was obtained at pH of 10, contact time of 60 min, and MCM-22 dose of 1.0 g/L. The adsorption kinetic has been described by first-order and pseudo-second-order models. It was observed that the rate of dye adsorption followed pseudo-second-order model. 相似文献
57.
A small shielding effect on the hydrogen atoms of chiral carbons of β-cyclodextrin (β-CD) was detected by 1H nuclear magnetic resonance, but a large environmental change of the chiral carbon atoms at high concentration ratios of lithium carbonate (Li2CO3) to β-CD was observed by polarimetry in aqueous solution. These findings urged us to investigate whether different formation conditions of the molecule-ion system between Li2CO3 and β-CD in solid state were involved in different spectral performances. To answer the question, we prepared three adducts of Li2CO3 to β-CD, i.e., samples 1, 2, and 3, by magnetic stirring, solvothermal and grinding conditions, respectively. Powder X-ray diffraction and Fourier transformation infrared spectroscopy provided the information of formation of the three molecule-ion adducts. Besides, scanning electron microscope images provided different surface information of the three adducts. Further, significant spectral differences in thermal behavior of these adducts were found by thermogravimetry and derivative thermogravimetry. 相似文献
58.
We propose a practical scheme to generate cluster states by simultaneously accomplishing two-qubit conditional gating on an array of equidistant ions by using transverse modes. Our operation is robust to heating and insensitive to Lamb--Dicke parameter. Meanwhile, as it is carried out in a geometric quantum computing fashion, our scheme enables the fast and high-fidelity generation of cluster states. The experimental feasibility is discussed with sophisticated ion trap techniques. 相似文献
59.
In the absence of the requirements of the Lamb-Dicke limit and rotating wave approximation, we semi-classically investigate the dynamics of a trapped ultra-cold ion in the standing-wave laser, with the consideration of the time-dependent potential and pseudo-potential of the Paul trap. The specific calculations show that the larger the Lamb-Dicke parameter η and the Rabi frequency Ω, the greater the difference between the dynamics in the time-dependent potential and the pseudo-potential. 相似文献
60.
近几年来,可溶性高分子C60衍生物的合成已取得明显的进展.Weis等[1]报道了以C60封端的聚苯乙烯大分子衍生物,Hawker等[2]合成出聚苯乙烯C60的共聚物.这些单取代的C60衍生物很好地保持了C60原有的性质,加工性能和机械性能均较好.唐本忠等[3]用紫外光照射聚碳酸酯和C60溶液或在AIBN存在的条件下加热以上溶液,得到可溶的聚碳酸酯C60衍生物,该法产率很高(可达99%),且简单易行.Patil等[5]也用类似的方法通过自由基聚合将C60接枝到聚烯烃的高分子链上.我们已报道了将C60接枝到聚烯烃上所得到的共聚物的性能[5,6],但C60高分子衍生物的用途尚不清楚. 相似文献