MICRO-MOTION EFFECT OF A TRAPPED ULTRA-COLD ION IN A STANDING-WAVE LASER

In the absence of the requirements of the Lamb-Dicke limit and rotating wave approximation, we semi-classically investigate the dynamics of a trapped ultra-cold ion in the standing-wave laser, with the consideration of the time-dependent potential and pseudo-potential of the Paul trap. The specific calculations show that the larger the Lamb-Dicke parameter η and the Rabi frequency Ω, the greater the difference between the dynamics in the time-dependent potential and the pseudo-potential.     

Natural products in combinatorial chemistry: an andrographolide-based library

The generation of a natural-product-based library starting from andrographolide is described. Utilizing andrographolide itself in parallel solution-phase synthesis leads to a 360-membered library. The initial transformation of the starting material via ozonolysis is followed by the conversion into a suitable template by introduction of a thiazole moiety. Subsequent decoration at two points of diversity yields the desired natural product derivatives. The selection of actually synthesized compounds is based on a virtually generated library and the assessment of its members with respect to physicochemical parameters, thus ensuring pharmacological relevance of the compounds.     

变压器典型工作环境对声功率测量结果的影响

变压器两侧常建有高大的防火墙,其从声学角度可视为刚性反射壁面,会改变变压器的辐射声场,进而影响变压器声功率测量结果。本文利用有限元、边界元等数值计算方法建立了变压器声辐射的仿真模型用以分析反射壁面对变压器声功率测量结果的影响,并通过实际测量验证了仿真计算所得结论。结果表明,反射壁面对变压器声功率测量结果的影响程度随反射壁面到变压器箱体距离增加而减弱,且当反射壁面距变压器箱体5 m以上时,其对变压器声功率基频及各谐波成份测量结果的影响均在2 dB以内。另外反射壁面对变压器噪声高频成份声功率测量结果的影响较大,而对100 Hz、200 Hz等低频成份测量结果影响较小,基本低于3 dB。     

Low Dimension Semiconducting Composite Nanomaterials

Recently, low dimension nanostructures have gained considerable attention due to their technological potential as unique types of nanoscale building blocks for future optoelectronic devices and systems. Semiconducting composite nanomaterials, which can combine the advantages of two or more components, have been the focus in the area of nanomaterials synthesis and device application.In this paper, we report our work on the preparation of composite nanomaterials based on CNTs.CNTs were coated by organic or inorganic species via novel and facile methods (Fig. 1 and Fig.2).These functional CNTs based composites show eminent prospects and opportunities for new applications in a wide variation of areas.     

Enantioselective iodolactonization catalyzed by chiral quaternary ammonium salts derived from cinchonidine

Chiral quaternary ammonium salts derived from cinchonidine have been applied to catalyze the stereoselective iodolactonizations of trans-5-aryl-4-pentenoic acids leading to a mixture of two regioselectively iodolactonized products with fair to excellent yield (37-98%) and moderate enantioselectivity (exo = 42.0% ee, endo = 31.0% ee) under mild conditions. This work is the first example of asymmetric iodolactonization reaction in the presence of less than a stoichiometric amount of chiral reagent.     

Unexpected hydrobromic acid-catalyzed C-C bond-forming reactions and facile synthesis of coumarins and benzofurans based on ketene dithioacetals

Hydrobromic acid was found to be a unique catalyst in C? C bond‐forming reactions with ketene dithioacetals. Distinctly different from other acids (including Lewis and Brønsted acids), the remarkable catalytic performance of hydrobromic acid in catalytic amounts was observed in the “acid”‐catalyzed reactions of readily available functionalized ketene dithioacetals 1 with various electrophiles. Under the catalysis of 0.1 equivalents of hydrobromic acid, the reaction of 1 with carbonyl compounds 2 a – l gave polyfunctionalized penta‐1,4‐dienes 3 or conjugated dienes 4 in good to excellent yields. The reaction tolerated a broad range of substituents on both the ketene dithioacetals 1 and the carbonyl compounds 2 . Application of this efficient C? C bond‐forming method generated coumarins 5 and benzofurans 7 under mild, metal‐free conditions by hydrobromic acid‐catalyzed reactions of 1 with salicylaldehydes 2 m – o and p‐quinones 6 a – d , respectively. A new reactive species, a sulfur‐stabilized carbonium ylide, formed depending on the nature of the counterion, and this was proposed as the key intermediate in the unique catalysis of hydrobromic acid.     

磁搅拌条件下β-环糊精与亚砷酸钠加合物的形成、谱学特性与热分解行为

傅里叶变换利用红外光谱、粉末X射线衍射、微分热重分析、气相色谱-飞行时间质谱、紫外光谱、1H核磁滴定以及电喷雾质谱等分析手段对β-环糊精(β-CD)和亚砷酸钠(SA)形成的分子-离子加合物SA-β-CD进行详细表征.结果显示,主-客体之间分子-离子相互作用是导致SA-β-CD的谱学特性(在固态或在溶液中)与热分解行为相异于主、客体自身行为的重要原因.而在气相色谱-飞行时间质谱条件下发生的氧化还原反应以及在电喷雾质谱条件下出现的Na+-β-CD(摩尔比为1∶1)超分子离子复合体进一步揭示了这种分子-离子加合作用的复杂性与独特性.     

Intramolecular Aldol Condensation ofα- Oxo Ketene Dibenzylthioacetals: A Facile Route to Substituted Thiophenes

As a kind of intermediates, a-oxo ketene dithioacetals I are important in organicsynthesis"'. In our recent studies, we found that the difference of dialkythio group canbestow various properties on these kinds of compounds"'. To exploit the reactivityadjusted by the dialkythio groups in l, a-oxo ketene dibenzylthioacetals 2 were chosenand studied. Some interesting new results were obtained in these experiments. Here wereport the new results.When studying the reaction of a-oxo ketene dibenzylt…