Photopolymerization of oxetane based systems

Oxetane based systems were investigated in cationic photopolymerization process. The effect on the rate of polymerization induced by the presence of epoxy monofunctional monomers and vinyl ether monomers were investigated. In both cases an increase of the rate of polymerization is evidenced either induced by a flexibilization effect due to a copolymerization or to a cross-propagation mechanism. Acrylate comonomers were also investigated and the formation of an IPN tightly cross-linked evidenced.     

Optimal blending to improve the combustibility of biofuels: a waste-to-energy approach

Journal of Thermal Analysis and Calorimetry - Increasing awareness due to climate change have been stimulating the development of renewable energies. Slow pyrolysis is considered a good method to...     

New fluorinated acrylic monomers for the surface modification of UV‐curable systems

New fluorinated acrylates were synthesized and used as modifying additives for acrylic UV‐curable systems. Their chemical structure is: C_nF_2n+1 R—OCO—CHCH₂, where the linear perfluorinated chain contains from 4 to 10 carbon atoms, while R is a linear alkyl group containing or not a thioether group. Notwithstanding their very low concentration, the fluorinated monomers caused a dramatic change of the surface properties of the films, without changing their curing conditions and their bulk properties. X‐ray photoelectron spectroscopy measurements showed that the monomers were able to concentrate selectively on the surfaces of the films, depending on their chemical structure and on the kind of substrate employed. The synthesis of the fluorinated monomers and the relationship between their chemical structure and the final surface properties of the UV‐cured films will be discussed. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 77–87, 1999     

Cotton fabrics treated with hybrid organic–inorganic coatings obtained through dual-cure processes

Cotton fabrics were treated with a hybrid organic–inorganic coating obtained through a dual-cure process, i.e. a photopolymerization reaction followed by a thermal treatment for promoting the formation of silica phases through a sol–gel process. To this aim, different amounts of a silica precursor were added to an acrylic UV-curable formulation in the presence of a suitable coupling agent. The thermo-mechanical properties of the treated fabrics were investigated and correlated to the composition and morphology of the hybrid organic–inorganic system. Furthermore, their flame retardancy and combustion behavior were evaluated by flammability tests and cone calorimetry and compared with the performances of pure cotton.     

Frontal polymerization of diurethane diacrylates

This work deals with the preparation of poly(urethane acrylates) by using two different polymerization techniques. Namely, the classical batch procedure has been compared with frontal polymerization (FP). A thorough study on the effect of initiator type, concentration, and on the velocity of the front and its maximum temperature has been carried out. Moreover, two different synthetic ways have been studied: the one step poly(urethane acrylate) preparation starting directly from 1,6 diisocyanato hexane and 2‐hydroxyethyl acrylate, and the two step procedure consisting of the synthesis of the corresponding diurethane diacrylate and of its subsequent polymerization. The first method has the advantage of being faster but some caution is necessary due to the excessive heat that is generated if the reaction conditions are not properly chosen. The second approach requires a further step but has the advantage of being more controlled. DSC analysis did not show any significant difference by comparing the thermal properties of the materials obtained by the two techniques (batch and FP). However, since FP runs are very easy and fast to be performed, FP should be seriously taken into proper account when these materials have to be prepared. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3344–3352, 2008     

A simple branching scheme for vertex coloring problems

We present a branching scheme for some vertex coloring problems based on a new graph operator called extension. The extension operator is used to generalize the branching scheme proposed by Zykov for the basic problem to a broad class of coloring problems, such as graph multicoloring, where each vertex requires a multiplicity of colors, graph bandwidth coloring, where the colors assigned to adjacent vertices must differ by at least a given distance, and graph bandwidth multicoloring, which generalizes both the multicoloring and the bandwidth coloring problems. We report some computational evidence of the effectiveness of the new branching scheme.     

Natural-like Chalcones with Antitumor Activity on Human MG63 Osteosarcoma Cells

Osteosarcoma (OS) is a malignant disease characterized by poor prognosis due to a high incidence of metastasis and chemoresistance. Recently, Licochalcone A (Lic-A) has been reported as a promising agent against OS. Starting from chalcones selected from a wide in-house library, a new series was designed and synthetized. The antitumor activity of the compounds was tested on the MG63 OS cell line through the innovative Quantitative Phase Imaging technique and MTT assay. To further investigate the biological profile of active derivatives, cell cycle progression and apoptosis induction were evaluated. An earlier and more consistent arrest in the G2-M phase with respect to Lic-A was observed. Moreover, apoptosis was assessed by Annexin V staining as well as by the detection of typical morphological features of apoptotic cells. Among the selected compounds, 1e, 1q, and 1r proved to be the most promising antitumor molecules. This study pointed out that an integrated methodological approach may constitute a valuable platform for the rapid screening of large series of compounds.     

UV-curable epoxy systems containing hyperbranched polymers: Kinetics investigation by photo-DSC and real-time FT-IR experiments

The effect of the presence of a hyperbranched OH-functionalized polymer (HBP) on the kinetics of cationic photopolymerization of an epoxy system was investigated employing two complementary techniques, photo-DSC and real-time FT-IR spectroscopy.Lower rates of cross-linking reactions and higher conversion degrees were obtained in photo-DSC experiments with respect to real-time FT-IR spectroscopy. A limited amount (10% wt) of HBP influenced to a certain extent the cure kinetics of the epoxy resin followed by RT-IR; a final conversion of epoxy groups equal to 100% was achieved by increasing the content up to 20% wt The addition of 10% wt of HBP leaves the cure kinetics of the CE resin studied by p-DSC almost unchanged. By increasing the HBP content, a slightly lower reaction rate is observed at lower reaction times. The presence of the HBP produced a continuous decrease of the T_g of the UV-cured epoxy resin but only modest reductions in its thermo-oxidative stability.     

Rheological,mechanical, thermal and electrical properties of UHMWPE/CNC composites

Cellulose - In this work, composites of ultra high molecular weight polyethylene (UHMWPE) and various loadings of cellulose nanocrystals (CNCs) were prepared exploiting different methods. Besides,...