A study of np annihilations around 0.65 GeV/c

$\text{n}\text{p}$ annihilations with ? 3 prongs with an incident antineutron momentum between 0.5 and 0.8 GeV/c are analysed. We present the topological branching ratios and cross sections, the resonance production rates and possible ?-ω interference effects.     

Polymerization of styrene with ZrCl4 and ZrCl3 in combination with Al(C2H5)3

The polymerization of styrene with two catalyst systems consisting of Al(C₂H₅)₃ in combination with ZrCl₄ or ZrCl₃ has been studied. The rate of polymerization with catalyst concentration was first-order with ZrCl₄ system and second-order with ZrCl₃ system, but at higher catalyst concentrations in both cases, the rate progressively decreases and finally attains a low value. The rate of polymerization is, however, proportional to the square of the monomer concentration in both the cases. The overall energy of activation was 10.9 kcal./mole and 6.45 kcal./mole in these systems. The polymers obtained with ZrCl₄ were of lower molecular weights as compared to those obtained with ZrCl₃. The polymers in both the cases had amorphous character.     

Zero field splittings of Gd3+IN Nd2(SO4)3 · 8H2O and Sm2(SO4)3 · 8H2O crystals at 273 K

The electron paramagnetic resonance (EPR) of Nd₂(SO₄)₃ · 8H₂O and Sm₂(SO₄)₃ · 8H₂O doped with Gd³⁺ has been carried out at 273 K and the spin-Hamiltonian parameters are deduced. The zero field splittings have been computed and compared with those observed directly by Bogle and Symmons. It is found that the discrepancy in the zero field splittings. between computed and directly observed values falls within the range of linewidths of directly observed values.     

Trityl-initiated copolymerizations of propylene oxide with tetrahydrofuran. VIII. Influence of reaction parameters

The copolymerization of propylene oxide (PO) with tetrahydrofuran (THF) in dichloroethane (DCE) has been studied at ?10, 0, +10, and +20°C. The reactions were initiated by triphenylmethyl cations associated with the following gegenions: PF₆^?, SbF₆^?, and AsF₆^?. The overall energies of activation (E_α of PO and E_a of THF) obtained with the three gegenions increase as one passes from PF₆^? to AsF₆^? then to SbF₆^?, though the magnitude of the increase in each case is not substantial. On the other hand, the associated frequency factors A show a considerable variation with the gegenion. The bimodal distributions of the molecular weights, obtained by GPC with the copolymer produced from reactions initiated with triphenylmethyl hexafluorophosphate, show that the proportions of the lower molecular weight component (L) decrease as the solvent is changed from DCE to toluene, and this is even more marked when bulk polymerization conditions are adopted. The proportions of the higher molecular weight component (H) however increase, as does its molecular weight. The GPC molecular weight distributions of the copolymers initiated with triphenylmethyl hexafluorophosphate in DCE to which water has been added, show that the molecular weight of component H decreases with increasing concentration of water, while that of component L remains practically unchanged at a value of 308. This corresponds to an average degree of polymerization (DP ) of 4 to 5. The NMR and infrared spectra of copolymers prepared in the presence of still higher initial water concentrations indicate that the PO-based polymer segments are present in excess of those required for a 1:1 copolymer.     

Eta and omega meson production in medium energy π+-p and K−p interactions

The production of η(550) and ω(780) mesons is studied in π^±p interactions at 16 GeV/c and K^?p interactions at 10 and 16 GeV/c. Cross sections for exclusive channels are presented, and for the π⁺p data differential cross sections are given for quasi-inclusive production where the η or ω is required to be accompanied by charged particles only. Close similarities are observed between η, ω and also ?⁰(770) production in terms of longitudinal and transverse variables. By a rough estimate, the η, ω and ?⁰ inclusive yields are found to be in the ratio 0.32 : 0.85 : 1, respectively, for 16 GeV/cπ⁺p collisions. For non-peripheral production we estimate this same ratio to be 0.34 : 0.9 : 1.     

Kationische Copolymerisation von Tetrahydrofuran mit Propylenoxid. 7. Mitt. Einflu? von Wasser auf die Reaktion

Ohne Zusammenfassung     

Study of the D(1285) and E(1420) resonances produced in pp annihilations at 700–760 MeV/c

In this paper we have investigated the properties of the D(1285) and E(1420) meson resonances using the five-body annihilation channels $\text{p}\text{p}\text{→}\text{K}\text{K}\text{πππ}$ obtained in a large statistics experiment (28 events/μb). The analysis favours the 1⁺ spin-parity assignment for the D(1285) meson. The dominant decay mode of the D(1285) into $\text{K}\text{K}\text{π}$ is found to be δ(970)π. The situation concerning the E(1420) meson remains confused although not inconsistent with previous analyses. Partial cross sections on resonance production are also presented.     

Structure of 72,74Se at high spin

Lifetimes of high spin states up to { }=22⁺ in the yrast positive parity bands have been measured to investigate the shape evolution with increasing spin in ^{72, 74}Se. The Q _t values derived from these measurements indicate that prolate shape stabilizes for ⁷²Se, while a triaxial shape develops for ⁷⁴Se at higher spins. Comparison of the observed trend in Q _t with spin for ^{72, 74}Se with that of the corresponding kryptones isotones emphasizes the stability provided by N=38 prolate shell gap even at high rotational frequency.     

6‐Hydroxy‐2,2‐di­methyl‐3,4‐di­hydro‐2H‐benzo[b]pyran

The title compound, 2,2‐di­methyl­chroman‐6‐ol, C₁₁H₁₄O₂, has been identified as a side product from the condensation of hydro­quinone with 2‐methyl­but‐3‐en‐2‐ol. The pyran ring has a half‐chair conformation. The hydroxyl groups are involved in intermolecular hydrogen bonding which generates infinite spiral chains around the fourfold screw axes; the O?O hydrogen‐bonded distances are 2.661 (1) Å.     

Performance estimation of 100 GB/s hybrid SACOCDMA-FSO-MDM system under atmospheric turbulences

Optical and Quantum Electronics - A D-shape elliptical stoma photonic crystal fiber (PCF) based on surface plasmon resonance is proposed and investigated with finite element method. The gold film...