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22.
WANG Qilin ZHANG Yinghui QU Aiqin WANG Hairen XU Zhenguo College of Life Science Shandong University Jinan Rongcheng Hongyangshen Group Shandong Province 《Chinese Journal of Reactive Polymers》2001,(2)
1. INTRODUCTION Blood fat primarily contains cholesterol, cholesterol ester, phosphatide, triglyceride and free fatty acid in serum of human being and mammalian. Under physiological conditions, the lipids transport in the form of lipoproteins linked with the proteins. Except for the free fatty acid linked with albumin, the other lipids are linked with the globular proteins into high-density lipoproteins (HDL), low density lipoproteins (LDL), very low density lipoproteins (VLDL) and so… 相似文献
23.
CUI Xiao-bing ZHENG Shou-tian SUN Yan-qiong YANG Guo-yu ** . Coordination Hydrothermal Chemistry Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P. R. China . State Key Laboratory of Coordination Chemistry Najing University Nanjing P. R. China 《高等学校化学研究》2004,(1)
IntroductionPolyoxometalatesarewidelystudiedfortheirin terestingapplicationsincatalysis ,electronicconduc tivity ,magnetism ,nonlinearopticsandmedicine[1— 4 ] .Whilethemechanismofthesynthesisofpolyoxometalatesremainselusiveandisoftende scribedasself assembly ,thereseemstobeanincreas inguseofthecombinationofthehydrothermalmethodandthestructure directingtemplate .There searchwiththismethodhasdemonstratedthatanum beroftransitionmetaloxides ,typicallyreducedmolybdenumoxides ,mixedvalancevanadiumo… 相似文献
24.
ICP-AES内标法测定硅铝钡合金中铝和钡 总被引:3,自引:0,他引:3
研究了以电感耦合等离子体发射光谱仪测定硅铝钡合金中铝和钡的方法。考查了方法的线性范围,检测限和RSD等指标,实验表明,方法简便,结果准确。 相似文献
25.
综述了以往钼、铁、铝、镁等单晶临界切应力温度依赖性的实验;指出:在滑移系统不变的条件下,在一定的温度范围内,临界切应力和温度呈近似指数关系是相当普遍的规律。Morse势函数应用和实验的吻合说明原子间力对屈服应力的重要作用。结合近来发展讨论今后的发展,指出金属范性的本质深入到电子结构层次研究的重要意义。 相似文献
26.
Surface and interior straini fields in thick specimens of polycarbonate have been measured by an embedded-multiple-grid moiré
method. Interior gratings are photographed through intervening gratings. Coherent optical processing of grating records creates
moiré fringe pattern. A correction procedure was developed to eliminate moiré errors caused by strain-induced gradients of
refractive index. This procedure utilizes the refraction distribution as obtained from observation of a grating from opposite
sides of a specimen. No measurements other than the normal moiré observations are required in order to find actual strains.
The correction technique should be useful in refining the results obtained when other optical methods are used in three-dimensional
situations. The method is utilized to determine strains on the surfaces and at the mid-and quarter-planes of thick compact
tension specimens. Results obtained, after correction, agree with measurements made with embedded strain gages. Maximum tensile
strain occurs on the midplane. The findings are rationalized by consideration of thickness and proximity to the crack tip. 相似文献
27.
Clementi M Bianca S Benedicenti F Tenconi R;Working Group on Down Syndrome 《Community genetics》1999,2(1):18-22
OBJECTIVE: To investigate the effect of parity on Down syndrome (DS). METHODS: The study was conducted on data from Northeast Italy (NEI) (1981-1996) and Sicily (ISMAC) (1991-1996) Congenital Malformation Registries. In these areas, all DS births are recorded and confirmed by chromosomal analysis; the NEI Registry also registers pregnancy terminations (TOPs) after prenatal diagnosis of DS. In order to estimate the effect of parity independently of the mother's age and to reduce the truncation effect, different age classes and three classes of parity (1, 2-4, >4) were defined. RESULTS: The study sample consisted of 1,088 consecutive newborns and 169 consecutive fetuses affected by DS. In both NEI and ISMAC samples, we found a significantly increased risk of having a DS child for multiparas > or =35 years of age. In the NEI sample, the inclusion of TOP data did not seem to modify this finding. In the ISMAC sample, a significantly reduced risk for primiparas was found at all ages. CONCLUSIONS: Our data confirm a higher risk of having a DS child in women with parity >4. As this effect is evident only in women > or =35 years age, its practical impact is null because these women are usually offered prenatal diagnosis in any case. However, the mechanisms involved, if this association is true, are very intriguing and the observation should stimulate scientific studies allowing a better knowledge of the nondisjunction mechanism. 相似文献
28.
Cheong KW Leow TC Rahman RN Basri M Rahman MB Salleh AB;Enzyme Microbial Technology Research Group 《Applied biochemistry and biotechnology》2011,164(3):362-375
A thermostable lipase from Geobacillus zalihae strain T1 was chemically modified using propionaldehyde via reductive alkylation. The targeted alkylation sites were lysines,
in which T1 lipase possessed 11 residues. Far-UV circular dichroism (CD) spectra of both native and alkylated enzyme showed
a similar broad minimum between 208 and 222 nm, thus suggesting a substantial amount of secondary structures in modified enzyme,
as compared with the corresponding native enzyme. The hydrolytic activity of the modified enzymes dropped drastically by nearly
15-fold upon chemical modification, despite both the native and modified form showed distinctive α-helical bands at 208 and
222 nm in CD spectra, leading us to the hypothesis of formation of a molten globule (MG)-like structure. As cooperative unfolding
transitions were observed, the modified lipase was distinguished from the native state, in which the former possessed a denaturation
temperature (T
m) in lower temperature range at 61 °C while the latter at 68 °C. This was further supported by 8-anilino-1-naphthalenesulfonic
acid (ANS) probed fluorescence which indicated higher exposure of hydrophobic residues, consequential of chemical modification.
Based on matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, a small number
of lysine residues were confirmed to be alkylated. 相似文献
29.
A new homologous series of isoflavone-based ethers,7-(4-bromoalkyloxy)-3-(4’-decyloxyprienyl)-4H-1-benzopyran-4-ones were synthesized and characterized.The mesomorphic properties of all homologues were investigated by differential scanning calorimetry(DSC) and polarizing optical microscopy(POM).Enantiotropic smectic A(SmA) phase was observed for all homologues.The structure-property study was carried out by comparing the mesomorphic behavior of the homologues with those previously reported analogues.The bromine atom from the alkyloxy side chain of the benzene ring fused to the heterocyclic moiety was found to be capable of changing the mesomorphic properties. 相似文献
30.
G.Rezaei Behbehani A.A.Saboury M.Mohebbian S.Tahmasbi Sarvestani M.Poorheravi 《中国化学快报》2009,20(11):1389-1392
Cyanide ion was studied as an inhibitor of Jack bean urease at 300 K in 30 mmol/L tris buffer,pH 7.The inhibition was investigated by isothermal titration calorimetry(ITC).The extended solvation model was used for CN~- + JBU interaction over the whole range of CN~- concentrations.The binding parameters recovered from the solvation model were attributed to the cyanide ion interaction.It was found that cyanide ion acted as a non-cooperative inhibitor of urease,and there is a set of 12±0.12 identical and in... 相似文献