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121.
Daisuke Nagai Tsutomu Imazeki Hisatoyo Morinaga Hiroyuki Oku Ken‐Ichi Kasuya 《Journal of polymer science. Part A, Polymer chemistry》2010,48(4):845-851
The three‐component polyaddition of diamines, carbon disulfide (CS2), and diacrylates in water was successfully achieved without the use of a surfactant or catalyst. Appropriate reaction conditions (i.e., reaction temperature, reaction time, and CS2 feed) enabled the polyaddition of 1,3‐di‐4‐piperidylpropane ( 1a ), CS2, and 1,6‐hexanediol diacrylate ( 2a ) to afford the corresponding poly(dithiourethane‐amine) containing 83% of dithiourethane units in 84% yield. Polyaddition of other monomers also proceeded under the optimum conditions to afford various poly(dithiourethane‐amine)s. Unsuccessful results for polyaddition in organic solvents such as toluene, tetrahydrofuran, and N,N‐dimethylformamide revealed that the polyaddition is accelerated in water. The obtained poly(dithiourethane‐amine)s adsorbed Au (III) efficiently under acidic conditions, due to the strong interaction of the thiocarbonyl sulfur in the dithiourethane unit with Au (III). The poly(dithiourethane‐amine)s also showed selective adsorption for Au (III) from a mixture of metal ions [Au (III), Fe (III), Mn (II), and Zn (II)], which indicates their potential utilization for the collection of gold. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 845–851, 2010 相似文献
122.
Tokuzo Konishi Toshio Tsubata Masaoki Oku Yanko M Todorov Masaki Yoshio 《Analytical sciences》2005,21(7):861-864
High-resolution the Mn Kalpha1 X-ray fluorescence spectra (HRXRF) were measured for a variety of manganese compounds, the oxidation number (valence) of which was from II to VII. Plots of the valence against the full width at half maximum (FWHM) and the chemical shift of the Kalpha1 X-ray fluorescence spectra give a curve and a liniar relation, respectively. The coefficient of correlation (R2) for the latter plot was 0.989 between valency II and VII. More excellent linearlity from III to IV was obtained with R2 = 0.995, which enabled us to determine the oxidation number of manganese atom in a nickel ion doped spinel structure, LiMn2O4 (LiNixMn(2-x)O4, with 0.2 < x < 0.42). From the valence of manganese ion obtained from HRXRF, the oxidation number of nickel ion is concluded to be divalent. 相似文献
123.
Naruhiro Koi Takeo Oku Kat suaki Suganuma 《Physica E: Low-dimensional Systems and Nanostructures》2005,29(3-4):541
Possibility of hydrogen gas storage in boron nitride (BN) clusters was investigated by molecular orbital calculations. Chemisorption calculation was carried out for B24N24 with changing endohedral elements in BN cluster to compare the bonding energy at nitrogen and boron, which showed that Li is a suitable element for hydrogenation to B24N24. 相似文献
124.
Masaoki Oku Toetsu ShishidoHideyuki Matsuta Kazuaki Wagatsuma 《Journal of Electron Spectroscopy and Related Phenomena》2006
The background corrected valence band XPS spectra and the electronic structures of FeAl, FeSi, CoAl and CoSi were studied. Clean surfaces of the polycrystalline samples were obtained by in situ fracturing of the samples in an XPS spectrometer. The energy loss parts of the Fe 2p, Co 2p and valence band spectra were removed by the deconvolution method using Al 2s or Si 2s spectra as response functions. CoAl exhibited a satellite peak in the Co 2p region, but the other compounds had no clear satellite peaks in the Co 2p and Fe 2p regions. The experimentally background corrected valence band spectra were compared with the calculated spectra using the first-principle band calculation. There were large discrepancies between the spectra above the binding energy of 5 eV. These indicated that the experimental spectra could not be explained by the electronic structures of the ground states alone. 相似文献
125.
Kichinosuke Hirokawa Fumihiro Honda Masaoki Oku 《Journal of Electron Spectroscopy and Related Phenomena》1975,6(5):333-345
Metal and oxide surface reactions formed by heating in the spectrometer at 300–400° at a vacuum of ca. 10?9 Torr (oil diffusion pumps) were studied. As a result of spectral observations before and after heating, the metals studied were classified into five groups. In the first group, oxide films on the metal surface are easily evaporated because of the high vapour pressure of oxide; in the second, the oxide films are easily reduced in the spectrometer; in the third, the oxide film formed on the metal is reduced but the bulk oxide is not easily reduced; in the fourth, very stable oxide films are formed and the bulk oxide is also stable; and finally in the fifth, the oxide film formed on the metal is apparently reduced, yet the bulk oxide is very stable. 相似文献
126.
127.
A perfluorinated vinyl ether monomer, 2-bromotetrafluoroethyl trifluorovinyl ether (BrTFF) was grafted into crosslinked poly(tetrafluoroethylene) (cPTFE) films by γ-rays irradiation under different conditions. The irradiation with absorbed doses more than 550 kGy gave the poly(BrTFF) grafted cPTFE membranes with grafting yields of more than 20%. FTIR spectra and SEM-EDS testified that BrTFF was successfully grafted into cPTFE films homogeneously in the film perpendicular direction. TGA analysis of the grafted films indicated that the perfluorinated poly(BrTFF) grafts were phase-separated from the PTFE region due to the crosslinked structure of the cPTFE based film, but the grafted films still had high thermal stability (above 300 °C). DSC measurements showed the decrease of melting temperature, but the increase of both heat of fusion and degree of crystallinity in cPTFE film after grafting. The grafted film, a new kind of perfluorinated polymer with bromine active groups and good mechanical properties, is expected to be modified for new applications. 相似文献
128.
Masaoki Oku Shigeru Suzuki Naofumi Ohtsu Toetsu Shishido Kazuaki Wagatsuma 《Applied Surface Science》2008,254(16):5141-5148
The intrinsic zero-energy loss profiles of transition metal 2p and 3p XPS spectra for Cr, Mn, and Fe oxides are obtained by spectral deconvolution and compared with Shirley-type background corrected profiles. The metal core level spectra are deconvoluted by O 1s spectra as the response function of each oxide. As the O 1s spectra include intrinsic and extrinsic energy loss parts, the background corrected core level spectra are zero-energy loss spectra. The good agreement of the deconvoluted spectra with the reported spectra obtained by the many body effect theory indicates that the background subtraction method is accurate. A comparison of the deconvoluted with the background corrected spectra of the Shirely-type subtraction reveals that almost all the spectra coincide with each other except for Fe 3p with -Fe2O3. The good coincidence of the Shirley-type corrected spectra with the deconvoluted and calculated spectra indicates that Shirley-type background correction can be used for daily quantitative surface analysis. 相似文献
129.
Takenao Shinohara Jun-ichi Suzuki Takayuki Oku Shin-ichi Takata Hiroshi Kira Kentaro Suzuya Kazuya Aizawa Masatoshi Arai Toshiya Otomo Masaaki Sugiyama 《Physica B: Condensed Matter》2009,404(17):2640-2642
Small-angle neutron scattering technique using polarized neutrons is powerful for studying structures in the range between nm and μm of magnetic materials. In addition, they have been used for the incident beam of focusing-geometry SANS instruments using a magnetic neutron lens, where a high polarization degree of about 99.9% is necessary because the imperfectness of the neutron polarization increases the background level. We are going to install such a magnetic focusing system on the new time-of-flight SANS (TOF-SANS) instrument at the J-PARC so as to make qmin smaller than 10−3 Å−1 and improve the resolution of the conventional TOF-SANS at low q. As a polarizing device of the instrument, two V-shaped polarizing super mirrors arranged in crossed geometry to enhance the polarization degree has been considered. In this paper, we present the concept and the detailed design of this device and its performance estimated by Monte Carlo simulations. 相似文献
130.
Masako Yamada Yoshihisa Iwashita Masahiro Ichikawa Takanori Sugimoto Hiromu Tongu Hiroshi Fujisawa Hirohiko M. Shimizu Takashi Ino Kenji Mishima Kaoru Taketani Tamaki Yoshioka Suguru Muto Takahiro Morishima Takayuki Oku Jun-ichi Suzuki Takenao Shinohara Kenji Sakai Hiromi Sato Katsuya Hirota Yoshie Otake Yoshichika Seki Shinsuke Kawasaki Sachio Komamiya Yoshio Kamiya Hidetoshi Otono Satoru Yamashita Peter Geltenbort 《Physica B: Condensed Matter》2009,404(17):2646-2651
Modulating permanent magnet sextupole lens (PMSx) for focusing pulsed cold neutrons is under development. The synchronized modulation of its field gradient suppresses the chromatic aberration which arises from the Time Of Flight method. The strength of the magnetic field, the torque, and the rise of temperature during its operation are studied on a fabricated prototype. Experiments on focusing pulsed very cold neutrons (VCN) at ILL (Institute of Laue Langevin, France) were carried out and VCN with around λ=40 Å were focused by the PMSx at a focal length of about 0.5 m. The experimental results are presented in conjunction with the principle of the neutron focusing and the modulating method of the focal strength of permanent magnet lens with the double ring structure. 相似文献