全文获取类型
收费全文 | 548篇 |
免费 | 9篇 |
国内免费 | 9篇 |
专业分类
化学 | 378篇 |
晶体学 | 47篇 |
力学 | 3篇 |
数学 | 28篇 |
物理学 | 110篇 |
出版年
2022年 | 4篇 |
2021年 | 6篇 |
2019年 | 5篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 3篇 |
2015年 | 4篇 |
2014年 | 13篇 |
2013年 | 10篇 |
2012年 | 29篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 12篇 |
2008年 | 24篇 |
2007年 | 22篇 |
2006年 | 17篇 |
2005年 | 24篇 |
2004年 | 15篇 |
2003年 | 27篇 |
2002年 | 30篇 |
2001年 | 27篇 |
2000年 | 16篇 |
1999年 | 14篇 |
1998年 | 28篇 |
1997年 | 10篇 |
1996年 | 24篇 |
1995年 | 10篇 |
1994年 | 13篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 17篇 |
1990年 | 6篇 |
1989年 | 2篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 13篇 |
1985年 | 15篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1980年 | 2篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 3篇 |
1971年 | 1篇 |
1967年 | 1篇 |
1966年 | 2篇 |
排序方式: 共有566条查询结果,搜索用时 0 毫秒
21.
Zou Jianzhong Hu Xiaodong Duan Chenying Xu Zheng You Xiaozeng Mak Thomas C. W. 《Transition Metal Chemistry》1998,23(4):477-480
Reaction of either K3[Fe(CN)6] or K4[Fe(CN)6] with a macrocyclic CuII complex, [Cu(teta)](ClO4)2 (teta = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacylotetradecane), in aqueous solution gave the same product as shown by spectroscopic and physicochemical characterisation. The crystal structure of the complex shows that it is a one-dimensional linear chain type heterobinuclear FeIII–CuII polymer. The unit is composed of a [Cu(teta)(H2O)2]2+ cationic complex, a FeIII–CuII alternate linear chain unit, a ClO
4
–
ion and four water molecules. The Cu atom is coordinated in a distorted octahedral arrangement by four nitrogen atoms from one teta ligand and two nitrogen atoms of the bridging cyanide groups. The Cu—N bond distances involving the cyanide bridges, 2.522(7) and 2.608(7)Å, respectively, indicate weak antiferromagnetic interactions between the FeIII and CuII atoms. 相似文献
22.
George S Nangia A Lam CK Mak TC Nicoud JF 《Chemical communications (Cambridge, England)》2004,(10):1202-1203
Crystalline nitrodiphenyl ureas adopt the N-H...O tape alpha-network only when stabilization accrues from the I...O(2)N or C[triple bond]C-H...O(2)N synthon, otherwise the ureanitro motif is preferred; soft, weak interactions can direct polar self-assembly in strong N-HO hydrogen-bonded crystals. 相似文献
23.
Dr. Sam C. K. Hau Prof. Dr. Thomas C. W. Mak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(17):5387-5400
Single‐crystal X‐ray diffraction of a series of ten crystalline silver(I)–trifluoroacetate complexes that contained designed ligands, each of which was composed of an aromatic system that was functionalized with terminal and internal ethynyl groups and a vinyl substituent, provided detailed information on the influence of ligand disposition and orientation, coordination preferences, and the co‐existence of different types of silver(I)–carbon bonding interactions (silver–ethynide, silver–ethynyl, silver–ethenyl, and silver–aromatic) on the construction of coordination networks that were consolidated by argentophilic and weak inter/intramolecular interactions. The complex Ag L10? 6 AgCF3CO2 ? H2O ? MeOH ( HL10 =1‐{[4‐(prop‐2‐ynyloxy)‐3‐vinylphenyl]ethynyl}naphthalene) is the first reported example that exhibits all four kinds of silver(I)–carbon bonding interactions in the solid state. 相似文献
24.
Dr. Jeffrey Y. W. Mak Dr. Rebecca H. Pouwer Assoc. Prof. Craig M. Williams 《Angewandte Chemie (International ed. in English)》2014,53(50):13664-13688
Well over a hundred years ago, Professor Julius Bredt embarked on a career pursuing and critiquing bridged bicyclic systems that contained ring strain induced by the presence of a bridgehead olefin. These endeavors founded what we now know as Bredt’s rule (Bredtsche Regel). Physical, theoretical, and synthetic organic chemists have intensely studied this premise, pushing the boundaries of such systems to arrive at a better understood physical phenomenon. Mother nature has also seen fit to construct molecules containing bridgehead double bonds that encompass Bredt’s rule. For the first time, this topic is reviewed in a natural product context. 相似文献
25.
The wave propagation in a periodic array of micro-perforated tube mufflers is investigated theoretically, numerically and experimentally. Because of the high acoustic resistance and low mass reactance due to the sub-millimeter perforation, the micro-perforated muffler can provide considerable sound attenuation of duct noise. Multiple mufflers are often used to enhance attenuation performance. When mufflers are distributed periodically in a duct, the periodic structure produces special dispersion characteristics in the overall sound transmission loss. The Bloch wave theory and the transfer matrix method are used to study the wave propagation in periodic micro-perforated tube mufflers and the dispersion characteristics of periodic micro-perforated mufflers are examined. The results predicted by the theory are compared with finite element method simulation and experimental results. The results indicate that the periodic structure can influence the performance of micro-perforated mufflers. With different periodic distances, the combination of the periodic structure and the micro-perforated tube muffler can contribute to the control of lower frequency noise with a broader frequency range or improvement of the peak transmission loss around the resonant frequency. 相似文献
26.
Cumulant functions are introduced to describe the statistical state of a radiation field. These functions are simply related
to the optical coherence functions but have some interesting features. It is shown that if the cumulant functions of all orders
greater than some numberN
0 vanish then they also vanish for all orders greater than 2. Thermal field is the only field having this property. This property
holds whether the field is described by a classical stochastic process or by a quantum density operator. Further the particular
operator ordering used in defining these cumulant functions for the quantized field affects only the second order cumulant
function. To describe the statistical state of a vector field such as partially polarized or unpolarized radiation, one would
need to introduce cumulant tensors. 相似文献
27.
Vibration isolation plays an important role in both the vibration and noise control of building services equipment. To evaluate vibration isolation performance, the force transmissibility method is commonly adopted. However, increasing the damping effect in the force transmissibility method reduces both the resonance peak value and the isolation performance in the “isolation region”. The limitation of the method is that the transmitted displacement of a floor structure and the interaction of mounting points are neglected. To include the floor displacement and the interaction of mounting points, Mak and Su recently proposed the power transmissibility method to assess the performance of vibration isolation. In this paper, the effect of viscous damping on power transmissibility is investigated. A practical procedure for experimentally determining the damping ratio is also given. 相似文献
28.
Huatian Shi Jianhui Xie William W. Y. Lam Wai-Lun Man Chi-Keung Mak Shek-Man Yiu Hung Kay Lee Tai-Chu Lau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(56):12895-12899
The synthesis and X-ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N-Mes)]− ( 1 ), are reported. Compound 1 is oxidized by [(p-BrC6H4)3N ]+.[SbCl6]− and the resulting MnVI species readily undergoes H-atom transfer and nitrene transfer reactions. 相似文献
29.
30.
Assessment of bone calcium and phosphorus content using micro X‐ray fluorescence spectrometry (μ‐EDXRF): effects of long‐term cadmium poisoning 下载免费PDF全文
This study assesses whether the concentrations of biologically important elements in bones are altered by long‐term consumption of cadmium (Cd)‐contaminated water. Heavy metal poisoning has significant impact on humans, and pollutants such as Cd are often found at high concentrations in waterways. Twelve Sprague Dawley rats consumed water with 50 p.p.m. Cd (Cd group), and another 12 consumed normal water (control group). Six subjects from each group were sacrificed after 2 weeks and the others after 4 weeks. Spectra were acquired from the femur by using the EDAX Eagle III micro‐XRF setup, and quantitative calculations were performed by using the fundamental parameter method to determine the concentrations of elements. A bone calcium/phosphorus concentration ratio (Ca/P) of 2.07 ± 0.001 is observed in the spectra from control subjects after 2 weeks and 2.07 ± 0.001 after 4 weeks. In Cd subjects, Ca/P after 2 weeks is 2.04 ± 0.001 and after 4 weeks is 1.97 ± 0.003. Statistically significant differences are obtained when comparing controls with Cd subjects at both time points and when comparing Cd subjects at both time points. Cadmium poisoning significantly affects bone Ca and P concentrations, increasing the likelihood of osteoporosis and other bone diseases. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献