Eulerian-Eulerian two-phase numerical simulation of nanofluid laminar forced convection in a microchannel

In this paper, laminar forced convection heat transfer of a copper-water nanofluid inside an isothermally heated microchannel is studied numerically. An Eulerian two-fluid model is considered to simulate the nanofluid flow inside the microchannel and the governing mass, momentum and energy equations for both phases are solved using the finite volume method. For the first time, the detailed study of the relative velocity and temperature of the phases are presented and it has been observed that the relative velocity and temperature between the phases is very small and negligible and the nanoparticle concentration distribution is uniform. However, the two-phase modeling results show higher heat transfer enhancement in comparison to the homogeneous single-phase model. Also, the heat transfer enhancement increases with increase in Reynolds number and nanoparticle volume concentration as well as with decrease in the nanoparticle diameter, while the pressure drop increases only slightly.     

Steady and Unsteady Heat Transfer in a Channel Partially Filled with Porous Media Under Thermal Non-Equilibrium Condition

Steady and pulsatile flow and heat transfer in a channel lined with two porous layers subject to constant wall heat flux under local thermal non-equilibrium (LTNE) condition is numerically investigated. To do this, a physical boundary condition in the interface of porous media and clear region of the channel is derived. The objective of this work is, first, to assess the effects of local solid-to-fluid heat transfer (a criterion indicating on departure from local thermal equilibrium (LTE) condition), solid-to-fluid thermal conductivity ratio and porous layer thickness on convective heat transfer in steady condition inside a channel partially filled with porous media; second, to examine the impact of pulsatile flow on heat transfer in the same channel. The effects of LTNE condition and thermal conductivity ratio in pulsatile flow are also briefly discussed. It is observed that Nusselt number inside the channel increases when the problem is tending to LTE condition. Therefore, careless consideration of LTE may lead to overestimation of heat transfer. Solid-to-fluid thermal conductivity ratio is also shown to enhance heat transfer in constant porous media thickness. It is also revealed that an increase in the amplitude of pulsation may result in enhancement of Nusselt number, while Nusselt number has a minimum in a certain frequency for each value of amplitude.     

Molecular dynamics simulations of hydrogen adsorption/desorption by palladium decorated single-walled carbon nanotube bundle

Utilising molecular dynamics simulations, the hydrogen molecules adsorption isotherms of the (8,?0) palladium decorated single-walled carbon nanotube (SWNT) were obtained. The hydrogen adsorption was studied on the external, interstial and internal surfaces of the SWNT bundle at several temperatures ranging from 77 to 400?K. The results were compared with the bare single-walled carbon nanotube bundle under the same conditions. The decorated carbon nanotube bundle hydrogen adsorption was significantly higher than that of the bare one. The hydrogen desorption and readsorption were studied using temperature as the readsorption/desorption variable. The rate constants were calculated for the hydrogen desorption at different temperatures. The calculated decorated SWNT bundle hydrogen desorption activation energy was higher than that for the bare SWNT bundle. The calculated activation energies for the hydrogen desorption in both nanotube bundles specified the temperature dependency of hydrogen desorption.     

Synthesis and Photochemistry of Novel 3,5-Diacetyl-1,4-dihydropyridines

 Some novel 3,5-diacetyl-1,4-dihydropyridine derivatives were synthesized; their photochemical behaviour was studied under oxygen or argon atmosphere. Irradiation of these compounds resulted in the aromatization of the ring and formation of 3,5-diacetylpyridine derivatives. The presence of oxygen plays an important role in the type, rate, or failure of oxidation. Irradiation of these compounds with of 2-furyl or 5-methyl-2-furyl substituents in position 4 under argon resulted in the formation of a pyridine ring with retention of these substituents, whereas loss of these substituents and ring aromatization was observed upon irradiation under oxygen.     

Note from the Publishers Pyroelectric behavior and dielectric properties of linear copolysiloxane/eicosylamine superlattice by A.R.M. Yusoff and W.H. Abd. Majid

In spite of the precautions taken to check the originality of the articles, it happens, unfortunately that our scientific colleagues' vigilance is sometimes caught up unprepared. Today, it has come to our attention that the following article results from a plagiarism. We apologize to the authors who suffered from it. You will find hereafter a note written by Dr Majid which summarizes the situation.     

Highly Efficient,Four Component,One-pot Synthesis of Tetrasubstituted Imidazoles Using a Catalytic Amount of FeCl<Subscript>3</Subscript> · 6H<Subscript>2</Subscript>O

Summary. An efficient and improved procedure for the synthesis of tetrasubstituted imidazoles by FeCl₃ · 6H₂O catalyzed four-component one-pot synthesis in refluxing ethanol is described.     

Rapid and Efficient Synthesis of Imidazolines and Bisimidazolines Under Microwave and Ultrasonic Irradiation

Small assemblies of 2-imidazolines and bisimidazolines from appropriate nitriles and ethylenediamine with catalytic amounts of P₂S₅ employing a microwave assisted protocol were prepared. Sonication of this system also led to successful synthesis of 2-imidazolines and bisimidazolines. Another advantage of these systems is the ability to carry out large scale reactions.     

Variations in,and Relationships of Surface Area,internal angle of friction and compact diametral fracture strength with degree of compaction

The progress of the compaction process to produce from an assembly of particles a coherent mass can be achieved by the application of shear and normal stress. The achievement of a densified coherent mass necessitates, together with the yielding of material, the movement of particles over and between each other. In uniaxial compaction the angle of internal friction, δ_E, is a projection of the unique critical state line which divides a three dimensional relationship between volume change (V), shear stress (?) and normal stress (σ) into yield domains and surfaces. There is one region for failure and flow (the Hvorslev surface) and another region for failure and consolidation (the Roscoe surface). In this paper the concepts of the Roscoe and Hvorslev surfaces together with the Coulomb yield criterion have been applied to the uniaxial compaction, over a range of compactable stresses, of titanium dioxide (20–2000 kPa). The characteristics of applied and shear stress, angle of internal friction (δ_E), angle of shearing resistance (?) and surface area (S_BET) were measured and correlated with the compaction stress (σ_c) and diametral strength (σ_f) of the compacts to investigate the phenomena of uniaxial compaction.     

Macro-Scale Dynamic Effects in Homogeneous and Heterogeneous Porous Media

It is known that the classical capillary pressure-saturation relationship may be deficient under non-equilibrium conditions when large saturation changes may occur. An extended relationship has been proposed in the literature which correlates the rate of change of saturation to the difference between the phase pressures and the equilibrium capillary pressure. This linear relationship contains a damping coefficient, \tau, that may be a function of saturation. The extended relationship is examined at the macro-scale through simulations using the two-phase simulator MUFTE-UG. In these simulations, it is assumed that the traditional equilibrium relationship between the water saturation and the difference in fluid pressures holds locally. Steady-state and dynamic numerical experiments are performed where a non-wetting phase displaces a wetting phase in homogeneous and heterogeneous domains with varying boundary conditions, domain size, and soil parameters. From these simulations the damping coefficient can be identified as a (non-linear) function of the water saturation. It is shown that the value of increases with an increased domain size and/or with decreased intrinsic permeability. Also, the value of for a domain with a spatially correlated random distribution of intrinsic permeability is compared to a homogeneous domain with equivalent permeability; they are shown to be almost equal.