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81.
82.
We show that using the thermodynamic limit, one can give a simple and natural construction of noncommutative
spaces for quantum systems on a lattice. Within this framework, we discuss the construction and ergodicity properties of stochastic dynamics of spin flip and diffusion type. 相似文献
83.
With nary mention of a tree graph, we obtain a cluster expansion bound that includes and vastly generalizes bounds as obtained by extant tree graph inequalities. This includes applications to both two-body and many-body potential situations of the recently obtained new improved tree graph inequalities that have led to the extra 1/N! factors. We work in a formalism coupling a discrete set of boson variables, such as occurs in a lattice system in classical statistical mechanics, or in Euclidean quantum field theory. The estimates of this Letter apply to numerical factors as arising in cluster expansions, due to essentially arbitrary sequences of the basic operations: interpolation of the covariance, interpolation of the interaction, and integration by parts. This includes complicated evolutions, such as the repeated use of interpolation to decouple the same variables several times, to ensure higher connectivity for renormalization purposes, in quantum field theory.This work was supported in part by the National Science Foundation under grant no. PHY-87-01329. 相似文献
84.
85.
T. Dziembowska Z. Rozwadowski E. Majewski K. Ambroziak 《Magnetic resonance in chemistry : MRC》2001,39(8):484-488
The deuterium isotope effect on the 13C NMR chemical shifts of some α-2-hydroxyaryl-N-phenylnitrones (Schiff base N-oxides) was studied. The existence of an intramolecular hydrogen bond with the proton localized on the phenolic oxygen atom was evidenced. Exceptionally large isotope effects ΔC-2(D) and ΔC-α(D) suggest that the substitution of the proton of the OH group by deuterium leads to a weakening of the hydrogen bond and some conformational changes in the molecule. This conclusion was drawn on the basis of a comparison of the deuterium isotope effects of Schiff base N-oxides and parent Schiff bases. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
86.
The generation of high density 2D hole gases is crucial for further progress in the electronic and optoelectronic nitride devices. In this paper, we present systematic theoretical studies of Mg-doped GaN/AlGaN gated heterostructures and superlattices. Our calculations are based on a self-consistent solution of the multiband k.p Schrödinger and Poisson equation and reveal that the hole 2D sheet density is mainly determined by the polarization induced interface charges. For an aluminium concentration of 30%, the induced hole density in the heterostructure can reach values up to 1.5×1013 cm−2. In the GaN/AlGaN superlattices, the hole sheet density increases with the superlattice period and saturates for a period of 40 nm at a value of 1.5×1013 cm−2. 相似文献
87.
Kurt Majewski 《Queueing Systems》2009,61(2-3):203-241
We consider a single-class queueing network in which the functional network primitives describe the cumulative exogenous arrivals, service times and routing decisions of the queues. The behavior of the network consisting of the cumulative total arrival, cumulative idle time, and queue length developments for each node is specified by conditions which relate the network primitives to the network behavior. For a broad class of network primitives, including discrete customer and fluid models, a network behavior exists, but need not be unique. Nevertheless, the mapping from network primitives to the set of associated network behavior is upper semicontinuous at network primitives with continuous routing. As an application we consider a sequence of random network primitives satisfying a sample path large deviation principle. We take advantage of the partial functional set-valued upper semicontinuity in order to derive a large deviation principle for the sequence of associated random queue length processes and to identify the rate function. This extends the results of Puhalskii (Markov Process. Relat. Fields 13(1), 99–136, 2007) about large deviations for the tail probabilities of generalized Jackson networks. Since the analysis is carried out on the doubly-infinite time axis ?, we can directly treat stationary situations. 相似文献
88.
电感耦合等离子体原子发射光谱法测定钛酸钡纳米粉体中7种杂质元素 总被引:3,自引:0,他引:3
钛酸钡纳米粉体样品用盐酸溶解,在所得样品溶液中用电感耦合等离子体原子发射光谱法测定了以氧化物存在于样品中的7种杂质元素(包括镁、锶、钾、钠、铝、硅及铁),对测定的光谱条件进行了试验并优化达到上述各元素的测定上限为0.1%(质量分数).测得方法的检出限(3S/b)为(单位μg·L-1):2.0(铝),1.0(铁),20.0(钾),0.2(镁),4.0(钠),3.0(硅)及0.5(锶).应用此方法分析了两件实样,所得结果的相对标准偏差(n=6)小于等于2.0%,对其中4种杂质元素(镁、钾、钠和锶)同时用HG/T 3587-1999标准中的方法作分析校核,所得结果与此方法结果一致. 相似文献
89.
We report on the spontaneous covalent growth of monomolecular adlayers on mixed nickel-zinc nanoferrite colloidal suspensions (ferrofluids). Synthesized nanoparticles were subjected to surface modification by means of acid chloride chemistry, leading to the formation of covalent bonds between the hydroxy groups at the nanoparticle surface and the acid chloride molecules. This procedure can be easily tailored to allow for the formation of adlayers containing both hydrophobic and hydrophilic regions stacked at predetermined distances from the magnetic core, and also providing the nanoferrites with functional carboxy groups capable of further modifications with, for example, drug molecules. Here, fluorophore aminopyrene molecules were bound to such modified nanoferrites through amide bonds. We also used the same chemistry to modify the surface with covalently bound long-chain palmitoyl moieties, and for comparison we also modified the nanoferrite surface by simple adsorption of oleic acid. Both procedures made the surface highly hydrophobic. These hydrophobic colloids were subsequently spread on an aqueous surface to form Langmuir monolayers with different characteristics. Moreover, since uniformity of size is crucial in a number of applications, we propose an efficient way of sorting the magnetic nanoparticles by size in their colloidal suspension. The suspension is centrifuged at increasing rotational speed and the fractions are collected after each run. The mean size of nanoferrite in each fraction was measured by the powder X-ray diffraction (PXRD) technique. 相似文献
90.
Roberts MN Nagle JK Majewski MB Finden JG Branda NR Wolf MO 《Inorganic chemistry》2011,50(11):4956-4966
The photophysical behavior for two photochromic Pt-terpyridine acetylide complexes containing pendant dithienylethenes (DTEs) bound to the metal through the alkynyl linkage is presented. Selective excitation of the Pt complex with visible light resulted in the metal-sensitized ring closing of the DTE unit. The central purpose of this study was to understand how excited state interactions govern the photophysics by correlating differences in the linkage of the two components with differences in the intramolecular energy transfer processes that occur between the Pt complex and the DTE. A series of model complexes without photochromic ligands were prepared and studied to elucidate the contributions of the triplet metal-to-ligand charge transfer and triplet intraligand states. It is demonstrated that reducing the orbital overlap of the metal-based and intraligand states by lengthening the linkage and eliminating a conjugated pathway is effective at dramatically decreasing the efficiency of intramolecular energy transfer. This is evidenced by the appearance of Pt-terpyridine based phosphorescence and a significant decrease in the observed rate of metal-sensitized ring closing of the DTE. 相似文献