排序方式: 共有146条查询结果,搜索用时 15 毫秒
141.
Soraia Meghdadi Mahsa Kiani Farzaneh Fadaei Tirani Maryam Bagheri Kurt Job Schenk 《Journal of Coordination Chemistry》2017,70(14):2409-2424
Two carboxamide ligands, H2bqbenzo {3,4-bis(2-quinolinecarboxamido)benzophenone} and H2bqb {N,N′-bis[(2-quinolinecarboxamide)-1,2-benzene]}, have been prepared using tetrabutylammonium bromide as an environmentally benign reaction medium. Two new Pd(II) complexes, [PdII(bqbenzo)] (1) and [PdII(bqb)] (2), have been synthesized, characterized, and their structures determined by single crystal X-ray diffraction. The di-anionic ligands, bqbenzo2? and bqb2?, are coordinated via two Namide atoms and the nitrogens of the two quinoline rings, with Pd?Namide < Pd–Nquinoline bond lengths. The geometry around palladium(II) in both complexes is distorted square planar. The electrochemical behaviors of the ligands and their Pd(II) complexes have been investigated by cyclic voltammetry in DMF. An irreversible PdII/I reduction is observed at ?1.06 V for 1 and at ?1.177 V for 2, indicating the influence of the R substituent on the central phenyl ring of carboxamide ligands on the PdII/I reduction potential. The ligands and palladium complexes were also screened for in vitro antibacterial activity. The Pd(II) complexes show strong biological activity against S.typhi and E.coli as Gram ?ve and B.cereus and S.aureus as Gram +ve bacteria comparable to the antibiotic penicillin. The antibacterial results also reveal that coordination of Pd(II) significantly improves the activity. 相似文献
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Karimian Somaye Ranjbar Sara Dadfar Mahsa Khoshneviszadeh Mahsima Gholampour Maryam Sakhteman Amirhossein Khoshneviszadeh Mehdi 《Molecular diversity》2021,25(4):2339-2349
Molecular Diversity - A series of ethyl 2-amino-4H-benzo[h]chromene-3-carboxylate derivatives, having phenyl ring with diverse substituents at C4 position of 4H-benzochromene nucleus, were... 相似文献
144.
Gholivand Khodayar Mohammadpanah Fahimeh Yaghoubi Rouhollah Rahimzadeh Dashtaki Maryam Pooyan Mahsa Rahmani Hamidreza Roshanian Zahra Sharifi Mahboobeh EbrahimiValmoozi Ali Asghar Roohzadeh Roohollah 《Molecular diversity》2022,26(3):1519-1530
Molecular Diversity - In an attempt to obtain the modified and novel insecticides with low human toxicity, a series of novel mono-, bis-, and tetraphosphonic acid derivatives were designed and... 相似文献
145.
Ansari Mahsa Montazeri Mahbobeh Daryani Ahmad Farshadfar Kaveh Emami Saeed 《Molecular diversity》2020,24(4):1223-1234
Molecular Diversity - A new series of aryloxyacetophenone thiosemicarbazones 4a–q have been synthesized as anti-Toxoplasma gondii agents. All compounds showed significant inhibitory activity... 相似文献
146.
Mahsa Pourmirza Shahla Ebrahimnezhad Ali Ramazani Aidin Bahrami Sholeh.Alaei Ali.Reza Dadrass 《无机化学学报》2019,(2)
通过2-溴-1-(对甲苯基)乙醛与三(对甲苯基)膦的反应制备α-磷配体:1-(对甲苯基)-2-(三对甲苯基-5-亚磷酰基)乙醛(L)。氯化镉和溴化汞与L分别反应,生成配合物[Cd(L)Cl_2]_2(C1)和[Hg(L)(μ_2-Br)Br]_2(C2)。用IR和NMR(~1H,~(13)C,~(31)P)对配合物进行了表征。通过单晶X射线衍射测定了C2的结构,并在B3LYP/6-31G~*水平对C2的结构进行了DFT计算研究,以揭示C2的复合反应位点与Schiff碱等亲核基团的相互作用。 相似文献