Liquid Crystal Polymers: Overview of Characteristics and Applications in Communication and Biomedical Technologies

Russian Journal of Applied Chemistry - Liquid crystals polymers (LCPs) are aromatic polymers with unique properties which enable their usage in various applications. LCPs are herein discussed, in...     

Experimental performance analysis of two different passive cooling techniques for solar photovoltaic installations

Journal of Thermal Analysis and Calorimetry - At higher ambient temperatures during summer months, the cell temperature of a photovoltaic (PV) module increases to 50–60 °C and sometimes...     

Quintic spline technique for time fractional fourth‐order partial differential equation

Higher order non‐Fickian diffusion theories involve fourth‐order linear partial differential equations and their solutions. A quintic polynomial spline technique is used for the numerical solutions of fourth‐order partial differential equations with Caputo time fractional derivative on a finite domain. These equations occur in many applications in real life problems such as modeling of plates and thin beams, strain gradient elasticity, and phase separation in binary mixtures, which are basic elements in engineering structures and are of great practical significance to civil, mechanical, and aerospace engineering. The quintic polynomial spline technique is used for space discretization and the time‐stepping is done using a backward Euler method based on the L1 approximation to the Caputo derivative. The stability and convergence analysis are also discussed. The numerical results are given, which demonstrate the effectiveness and accuracy of the numerical method. The numerical results obtained in this article are also compared favorably well with the results of (S. S. Siddiqi and S. Arshed, Int. J. Comput. Math. 92 (2015), 1496–1518). © 2016 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 33: 445–466, 2017     

Intuitionistic fuzzy soft graphs with applications

We present different types of new concepts, including intuitionistic fuzzy soft graphs, complete intuitionistic fuzzy soft graph, strong intuitionistic fuzzy soft graph and self complement of intuitionistic fuzzy soft graph. We describe various methods of their construction, and investigate some of their related properties. We also discuss applications of intuitionistic fuzzy soft graphs in communication network and decision making.     

CuI catalyst heterogenized on melamine-pyridines immobilized SBA-15: Heterogeneous and recyclable nanocatalyst for Ullmann-type CN coupling reactions

The present study reports the procedure conducted in SBA-15/CCPy/CuI preparation as a new Mesoporous nanocatalyst, whereas melamine bearing pyridine groups on SBA-15 are used to secure CuI catalyst as capping agent. The resultant catalyst was specified by conducting TEM, FESEM, WDX, ICP, and EDS. The SBA-15/CCPy/CuI catalytic behavior was studied to N-arylation of indole, imidazole, pyrazole, benzyl amine, and aniline by coupling reactions of Ullmann-type CN. Also, the heterogeneous catalyst may simply be recovered via filtration and used again for seven cycles with no considerable loss in activity. The findings revealed the privileges of the present method, including the high product yield, experimental simplicity, low catalyst loading, broad substrate scope, and short reaction times.     

UV-vis, IR spectra and thermal studies of charge transfer complex formed between poly(amidoamine) dendrimers and iodine

The intermolecular charge-transfer (CT) complexes formed between two poly(amidoamine) dendrimers (PAMAM) from zero (D1) and second generation (D2) as donor and iodine as sigma-acceptor have been studied spectrophotometrically in the chloroform medium. The suggested structures of the solid iodine charge-transfer complexes investigated by several techniques using elemental analysis, mid infrared spectra, and thermal analysis (TGA and DTG) of the solid CT-complexes along with the photometric titration curves for the reactions. The results indicate the formation of two CT-complexes [(D1)]-I(2) and [(D2)]-2I(2) with acceptor:donor molar ratios of 1:1 and 1:2, respectively. The kinetic parameters (non-isothermal method) for their decomposition have been evaluated by graphical methods using the equations of Horowitz-Metzger (HM) and Coats-Redfern (CR).     

Algebraic analysis of a RGB image encryption algorithm based on DNA encoding and chaotic map

Recently a new image encryption method based on DNA encoding and chaotic systems has been proposed. In this paper, several weaknesses of this cryptosystem are pointed out. Equivalent mathematical model of the cryptosystem is designed and algebraic analysis is given. Moreover reduction of the key space has been reached by finding equivalent keys. A recovering scheme is finally given with a lower complexity than the actual decryption scheme.     

Laser irradiation effects on the surface,structural and mechanical properties of Al–Cu alloy 2024

Laser irradiation effects on surface, structural and mechanical properties of Al–Cu–Mg alloy (Al–Cu alloy 2024) have been investigated. The specimens were irradiated for various fluences ranging from 3.8 to 5.5 J/cm² using an Excimer (KrF) laser (248 nm, 18 ns, 30 Hz) under vacuum environment. The surface and structural modifications of the irradiated targets have been investigated by scanning electron microscope (SEM) and X-ray diffractometer (XRD), respectively. SEM analysis reveals the formation of micro-sized craters along the growth of periodic surface structures (ripples) at their peripheries. The size of the craters initially increases and then decreases by increasing the laser fluence. XRD analysis shows an anomalous trend in the peak intensity and crystallite size of the specimen irradiated for various fluences. A universal tensile testing machine and Vickers microhardness tester were employed in order to investigate the mechanical properties of the irradiated targets. The changes in yield strength, ultimate tensile strength and microhardness were found to be anomalous with increasing laser fluences. The changes in the surface and structural properties of Al–Cu alloy 2024 after laser irradiation have been associated with the changes in mechanical properties.     

Ultrasound mediation for efficient synthesis of monoarylidene derivatives of homo- and heterocyclic ketones

Ultrasonic irradiation was efficiently used for high yield synthesis of monoarylidene derivatives of cyclic systems directly from the reaction of ketone with various aldehydes under solvent-free conditions. Reactions took place rapidly in the presence of catalytic amounts of pyrrolidine, while no significant formation of the undesired bis by-products was observed. Moreover, the procedure was applicable to both homo- and heterocyclic ketones.     

Novel, highly selective gold nanoparticle patterning on surfaces using pure water

We present a simple, novel procedure to selectively deposit gold nanoparticles using pure water. It enables patterning of nanoparticle monolayers with a remarkably high degree of selectivity on flat as well as microstructured oxide surfaces. We demonstrate that water molecules form a thin "capping" layer on exposed thiol molecules within the mercaptan self-assembled layer. This reversible capping of water molecules locally "deactivates" the thiol groups, therewith inhibiting the binding of metallic gold nanoparticles to these specific areas. This amazing role of water molecules can be used as a tool to pattern flat as well as structured surfaces with gold nanoparticles.