Real-time quantitative measurement of the mode beating of an injection-seeded optical parametric oscillator

In this paper we present the dependency of a quantitative measurement of the first-order longitudinal mode beating of an injection-seeded optical parametric oscillator (OPO) on its injection-seeding state. We show the correlation of the intensity of the first-order longitudinal mode beating and the side-mode suppression of an injection-seeded OPO. We further demonstrate that the mode-beating intensity can be used as an indicator for the spectral purity of an injection-seeded OPO.     

Metastable P-Tellurium-Substituted Phosphaalkenes: Formation, 125Te- and 31P-NMR Spectroscopic Characterization,and Decomposition

Abstract

The formation and decomposition of P-tellurium-substituted phosphaalkenes was followed by ³¹P- and ¹²⁵Te-NMR spectroscopy. Acyclic compounds with C?P-Te moieties are in general thermally labile, but bulky substituents enhance the lifetime of a number of species. The P-chlorophosphaalkene (Me₃Si)₂C?PCl (1a) reacts with the disilyltelluride (iPrMe₂Si)₂Te (2) leading to the mixed-substituted telluride (Me₃Si)₂C?PTeSiMe₂iPr 3a which reacts with another equivalent of 1a furnishing the tellurobis(phosphaalkene) [(Me₃Si)₂C?P]₂Te (4a). 4a is a shortlived compound decomposing thermally with precipitation of elemental tellurium, leading to a known diphosphabicyclobutane 5a. In a similar way, the bulkier P-chlorophosphaalkene (iPrMe₂Si)₂C?PCl (1b) reacts with (iPrMe₃Si)₂Te furnishing [(iPrMe₂Si)₂C?P]₂Te (4b), which loses tellurium much more slowly than 4a and can be kept in cold solutions for an extended time. Reactions of in situ-prepared lithium aryltellurolates LiTeAr 6 – 9 [Ar?Ph: 6, Ar?2,4,6-Me₃Ph (?Mes): 7, Ar?2,4,6-iPr₃Ph (?TIP): 8, Ar?2,4,6-tBu₃Ph (?Mes*): 9] with 1a provide P-aryltellurophosphaalkenes 10 – 13, which decompose with the loss of diarylditellurides leading to 5a. After a 2 + 4 cycloaddition trapping experiment of 12 with cyclopentadiene, a metastable P-aryltelluro phosphanorbornene 14 was detected by ³¹P-NMR. Reactions of elemental tellurium with P-phosphanylphosphaalkenes (Me₃Si)₂C?PPR′R′;′ 15 – 17 (R′, R′′?iPr: 15; R′?iPr, R′′?tBu: 16; R′, R′′?tBu: 17) lead to metastable insertion products (Me₃Si)₂C?PTePR′R′′ 18 – 20 that decompose with formation of the tellurobisphosphanes (R′R′′P)₂Te 21 – 23, and of the bicyclic diphosphane 5a, which isomerises thermally to the diphosphabicyclooctane 24. The P-di-i-propylphosphanyl-phosphanorbornene 25 dismutates under the action of tellurium into the symmetric diphosphanes iPr₄P₂ and bis-phosphanorbornene 26. The tellurium-free products 24 and 26 were characterized by X-ray crystallography.     

Probe atom dependence of the electric field gradient in bismuth

The electric field gradient of T1 in Bi has been determined with the PAD method. The observed value follows the general trend of sp-probe atoms in the group V semimetals in accordance with a covalent bond picture.     

Magnetic moments of (νi132)−n isomers in neutron-deficient lead isotopes

The magnetic moments of the 12⁺ isomers in ^{192, 196, 198, 200, 206}Pb and of the $\text{33}\text{2}{}^{\mathrm{+}}$ isomer in ²⁰⁵Pb have been measured using the PAD technique. The results for the g-factors are: g(192) = ?0.173(2), g(196) = ?0.1600(15), g(198) = ?0.1552(15), g(200) = ?0.1512(15), g(206) = ?0.1496(18), and g(205) = ?0.148(5). As all states have a rather pure $\text{(νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?n}}$ configuration, the values reflect directly the $\text{νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ orbital. They show a decrease towards the more neutron-deficient isotopes attributed to the reduced core polarisation as a result of decreasing occupation of the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ neutron shell. The measured systematics are discussed regarding core polarisation, mesonic corrections, and small admixtures of core-excited states to the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ wave function.     

Soluble Hetero-Polyoxovanadates and Their Solution Chemistry Analyzed by Electrospray Ionization Mass Spectrometry

Polyoxometalates (POMs) are an intriguing class of compounds due to their tremendous structural variety and the wide spectrum of resulting properties, which make them interesting for applications in fields such as catalysis, material science or nanotechnology. Their ability to form large supramolecular architectures by self-assembly offers an entry to complex, functional systems. After an introduction into the structure and synthesis of POMs of the early transition metals, recently discovered water-soluble antimonato polyoxovanadates (Sb-POVs) and the investigation of their chemical reactivity are discussed. Electrospray ionization mass spectrometry (ESI-MS) is presented as an analytical technique suitable to investigate the structure of complex POM assemblies in solution and to probe the underlying reactivity and formation mechanisms. This Minireview highlights the first studies on the soluble Sb-POVs and how the knowledge of their reactivity obtained by ESI-MS has fostered the syntheses of numerous novel Sb-POV compounds.     

Antimony in cadmium — An extreme case of probe atom dependent EFG

The electric field gradient of Sb in Cd was determined by a PAD measurement on¹¹²Sb recoil-implanted into a Cd single crystal. We observe an extremely small value compared with known values on the probes Cd, In, and Sn in a Cd matrix. Strong local electronic effects may be responsible for this result.     

Soliton molecules for advanced optical telecommunications

Recent developments in the technology of optical telecommunications are pushed forward by the rapidly growing demand for data-carrying capacity. Current approaches are discussed; most lines of investigation are limited to the linear (i.e. low power) regime. It is shown how this restriction poses a limit for further evolution. If, on the other hand, the nonlinear regime is entered, recent developments about soliton molecules offer a possibility to advance further.