Frottements et pertes de pression des fluides non newtoniens dans des conduites non circulaires

The study of fluid flow in a duct requires characteristic parameters of the flow and dimensionless numbers to correlate and compare experimental results. For Newtonian fluids in simple configurations, the definition of the Reynolds number is quite standard, but for non-Newtonian fluid flows in ducts with arbitrary shape of cross section, the dependence of the apparent viscosity with the shear rate requires a generalization of this dimensionless number. This note proposes a general method valid for a large class of non-Newtonian fluids and for all duct shapes. An application is developed for a viscoelastic flow through a rectangular duct. Results obtained in the present investigation are in a good agreement with available correlations. To cite this article: M. Mahfoud et al., C. R. Mecanique 333 (2005).     

The role of thermal analysis in detecting impurity levels during aluminum recycling

Recycling of aluminum scrap has gained interest owing to its economic and ecological benefits. Unfortunately, during the collection of scrap from a mixer of junk from various sectors it is difficult to ensure that the recycled alloy has the same chemical composition as that of already existing commercial alloys. Consequently, some of the alloying elements become trace/tramp elements in the recycled alloy. Therefore, in order to obtain high performance recycled alloys, controlling the impurity levels of the aluminum melt is of vital importance. Normally, computer aided cooling curve analysis (CA-CCA) is used to find the relationship between cooling curve parameters, melt treatments, alloy composition, and properties. In the present study, the first differential thermal analysis (DTA) approach has been used to detect and quantify impurity elements in scrap-like liquid aluminum alloys.     

Conductance and Thermodynamic Study of Thallium and Silver Ion Complexes with Crown Ethers in Different Binary Acetonitrile–Water Solvent Mixtures

The complexation reactions between Ag⁺ andTl⁺ ions with 15-crown-5 (15C5) and phenyl-aza-15-crown-5(PhA15C5) have been studied conductometrically in 90%acetonitrile-water and 50% acetonitrile - water mixed solvents attemperatures of 293, 298, 303 and 308 K. The stability constants of theresulting 1 : 1 complexes were determined, indicating that theTl⁺ complexes are more stable than the Ag⁺complexes. The enthalpy and entropy of crown complexation reactions were determined from the temperature dependence of the complexation constants.The enthalpy and entropy changes depend on solvent composition and the T S⁰ _o–H⁰ plotshows a good linear correlation, indicating the existence of entropy –enthalpy compensation in the crown complexation reactions.     

Effect of hoisting cable elasticity on anti-sway controllers of quay-side container cranes

Oscillation frequency of crane payloads is the main and most important factor in crane anti-sway control systems design. In the summer of 2005, a Smart Sway Control system (SSC) was installed on a 65-ton quay-side container crane at Jeddah Port. During the calibration phase of the installation, it was observed that heavy payloads combined with the dynamic stretch of the hoist cables had a significant impact on the configuration of the hoisting mechanism and the pattern of oscillation. This introduced considerable change in the oscillation frequency of the payload, which resulted in a significant impact on the performance of the anti-sway control system. Empirical formulas had to be used to compensate for the change in the frequency approximation used in the controller algorithm. In this work, an analytic approximation of the oscillation frequency of the hoisting mechanism of a quay-side container crane is developed, which takes into consideration the elasticity of the hoisting cables. A parametric study is performed to investigate the extent of the effect of the hoisting cables stretch on the system behavior for a typical range of payload masses and cable lengths. The performance of the delayed feedback control system used in the SSC controller is simulated on an elastic cables model using both the elastic and rigid cable frequency approximations.     

Threshold gain analysis of second order distributed feedback lasers based on [2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene]

We present a theoretical study of the threshold analysis of second order surface emitting distributed feedback lasers based on the polymer [2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). A coupled mode formalism that includes radiation modes is used to describe the propagation of the waves in the periodically corrugated region. A detailed calculation of the threshold gain of the laser that includes the effects of the radiation modes is described.     

Evaluation of various DFT protocols for computing 1H and 13C chemical shifts to distinguish stereoisomers: diastereomeric 2‐, 3‐, and 4‐methylcyclohexanols as a test set

¹H and ¹³C NMR chemical shifts were measured for a set of six isomers—the cis and trans 2‐, 3‐, and 4‐methylcyclohexanols. ¹H and ¹³C NMR chemical shifts were computed at the B3LYP, WP04, WC04, and PBE1 density functional levels for the same compounds, taking into account the Boltzmann distribution among conformational isomers (chair–chair forms and hydroxyl rotamers). The experimental versus computed chemical shift values for proton and carbon were compared and evaluated (using linear correlation (r²), total absolute error (|Δδ|_T), and mean unsigned error (MUE) criteria) with respect to the relative ability of each method to distinguish between cis and trans stereoisomers for each of the three constitutional isomers. For ¹³C shift data, results from the B3LYP and PBE1 density functionals were not sufficiently accurate to distinguish all three pairs of stereoisomers, while results using the WC04 functional did do so. For ¹H shift data, each of the WP04, B3LYP, and PBE1 methods was sufficiently accurate to make the proper stereochemical distinction for each of the three pairs. Applying a linear correction to the computed data improved both the absolute accuracy and the degree of discrimination for most of the methods. The nature of the cavity definition used for continuum solvation had little effect. Overall, use of proton chemical shift data was more discriminating than use of carbon data. Copyright © 2007 John Wiley & Sons, Ltd.     

氮掺杂碳纳米管负载的Ru和Pd催化剂上异丙醇的转化(英文)

Ru and Pd (2 wt%) loaded on pure and on Ndoped carbon nanotubes (NCNTs) were prepared and tested using the isopropyl alcohol decomposition reaction as probe reaction. The presence of nitrogen functionalities (pyridinic, pyrrolic, and quaternary nitrogen) on the nitrogen doped support induced a higher metal dispersion: Pd/NCNT (1.8 nm) Pd/CNT (4.9 nm), and Ru/NCNT (2.4 nm) Ru/CNT (3.0 nm). The catalytic activity of the supports was determined first. Isopropyl alcohol conversion produces acetone on CNTs while on NCNTs it led to both dehydration and dehydrogenation products. At 210 °C and in the presence of air, the isopropyl alcohol conversion was higher on the NCNTs (25%) than on the CNTs (11%). The Pd loaded catalysts were more active and more selective than the Ru ones. At 115 °C, the Pd catalysts were 100% selective towards acetone for a conversion of 100%, whereas the Ru catalysts led to dehydration and dehydrogenation products. The nitrogen doping induced the appearance of redox properties when oxygen is present in the reaction mixture.     

A Thermodynamic Study of Complexation of Iron Ions with Clarithromycin and Roxithromycin in Methanol Using a Conductometric Method

The formation constants K _ML of Clarithromycin (CLA) and Roxithromycin (ROX) with Fe(III) and Fe(II) ions in methanol have been determined at various temperatures using a conductometric technique. The interaction yields complexes with metal-to-ligand compositions of 1:1. The conductivity data were analyzed using a computer program based on 1:1 stoichiometry from which the stability constants and the limiting molar conductance were obtained. The stability of these complexes was found to increase with temperature. Compared with Fe(II), Fe(III) forms more stable complexes with ROX and CLA. The values of the thermodynamic parameters enthalpies (??H ^°), entropies (??S ^°), and the derived Gibbs energies (??G ^°) were deduced from the dependence of the formation constants on temperature. The positive values of ??H ^° and ??S ^° indicate that the complexation processes is enthalpically unfavorable but entropically favored. The negative values of ??G ^° show the ability of the studied ligand to form stable complexes and that the complexation process is favorable.     

Synthesis,characterization, luminescence properties and antioxidant activity of Ln(III) complexes with a new aryl amide bridging ligand

A novel Aryl amide ligand H₂L and its eight complexes, [LnH₂L(NO₃)₂·H₂O]NO₃ [Ln=Sm(III), Er(III), Tb(III), Dy(III), La(III), Gd(III), Nd(III), and Pr(III)], are presented. The ligand and complexes were synthesized and characterized based on elemental analyses, molar conductance, IR, ¹H and ¹³C-NMR, UV–VIS., and TGA studies. The conductivity data show a 1:1 electrolytic nature with a general formula [LnH₂L(NO₃)₂·2H₂O]NO₃ The IR spectra reveal coordination of the ligand through the azomethine nitrogen and the phenolic hydroxyl of the ligand to the lanthanide ion. The coordinated nitrate ions behave in a bidentate fashion. The thermal decomposition studies indicate the presence of two water molecules in the inner coordination sphere. Under the excitation at 319 nm, the luminescence emission properties for Sm, Tb, and Dy complexes are observed. These observations show that the ligand favors energy transfers to the emitting energy level of these lanthanide ions. Furthermore, the antioxidant activity of the ligand and its Ln(III) complexes was determined by DPPH radical scavenging method, which indicates that the Ln(III) complexes exhibit more effective antioxidant activity than the ligand alone.