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排序方式: 共有379条查询结果,搜索用时 31 毫秒
91.
An organometallic NO‐bidentate Schiff base, (2‐(1‐((1‐carboxyethyl)imino)ethyl) cyclopenta‐2,4‐dien‐1‐yl)(cyclopenta‐2,4‐dien‐1‐yl) iron (HL) was synthesized by condensation of 2‐acetylferrocene with amino acid alanine. Then its octahedral Cr (III), Mn (II), Fe (III), Co (II), Ni (II), Cu (II), Zn (II) and Cd (II) complexes were synthesized. All compounds were characterized on the basis of elemental analysis (C, H, N and M), molar conductivity, FT‐IR, UV–Vis, 1H‐NMR, SEM, mass analysis and thermal studies. Furthermore, computational studies of HL ligand have been carried out by DFT/B3LYP method. HOMO and LUMO energy values, chemical hardness‐softness, electronegativity, electrophilic index and other parameters were calculated. SEM micrographs of HL ligand and its [Cd (HL)(H2O)2Cl2].2H2O complex, showed that they were prepared in nano‐structure forms with particle size 54 and 41 nm, respectively. Antifungal and antibacterial activities of HL ligand and its metal complexes have been screened in vitro against different species such as Aspergillus fumigatus, Candida albicans, Bacillus subtilis, Staphylococcus aureus, Escherichia coli and Salmonella typhimurium. The synthesized compounds were evaluated for their anticancer activities against breast cancer cell line (MCF‐7) and normal melanocytes cell line (HFB‐4). It was found that [Co (HL)(H2O)2Cl2].3H2O complex had the lowest IC50 value (10.9 μg/ml) and hence was the most active one. Finally, the optimized structures of the Schiff base and its Co (II) complex have been used to accomplish molecular docking studies with receptors of 3HB5, 3MIW, 5IBV and 4WM8 to determine the most preferred mode of interaction. 相似文献
92.
Shurbaji M Abu Al Rub MH Saket MM Qaisi AM Salim ML Abu-Nameh ES 《Journal of AOAC International》2010,93(6):1868-1873
A rapid, simple, and sensitive RP-HPLC analytical method was developed for the simultaneous determination of triclabendazole and ivermectin in combination using a C18 RP column. The mobile phase was acetonitrile-methanol-water-acetic acid (56 + 36 + 7.5 + 0.5, v/v/v/v) at a pH of 4.35 and flow rate of 1.0 mL/min. A 245 nm UV detection wavelength was used. Complete validation, including linearity, accuracy, recovery, LOD, LOQ, precision, robustness, stability, and peak purity, was performed. The calibration curve was linear over the range 50.09-150.26 microg/mL for triclabendazole with r = 0.9999 and 27.01-81.02 microg/mL for ivermectin with r = 0.9999. Calculated LOD and LOQ for triclabendazole were 0.03 and 0.08 microg/mL, respectively, and for ivermectin 0.07 and 0.20 microg/mL, respectively. The intraday precision obtained was 98.71% with RSD of 0.87% for triclabendazole and 100.79% with RSD 0.73% for ivermectin. The interday precision obtained was 99.51% with RSD of 0.35% for triclabendazole and 100.55% with RSD of 0.59% for ivermectin. Robustness was also studied, and there was no significant variation of the system suitability of the analytical method with small changes in experimental parameters. 相似文献
93.
Apollonio LG Pianca DJ Whittall IR Kyd JM Maher WA 《Rapid communications in mass spectrometry : RCM》2006,20(18):2777-2780
94.
Maher Boudabra Abderrahmane Nitaj 《Journal of Applied Mathematics and Computing》2018,57(1-2):229-245
The KMOV scheme is a public key cryptosystem based on an RSA modulus \(n=pq\) where p and q are large prime numbers with \(p\equiv q\equiv 2\pmod 3\). It uses the points of an elliptic curve with equation \(y^2\equiv x^3+b\pmod n\). In this paper, we propose a generalization of the KMOV cryptosystem with a prime power modulus of the form \(n=p^{r}q^{s}\) and study its resistance to the known attacks. 相似文献
95.
Gas-phase pyrolysis of N-(1H-benzimidazol-2-yl)-N′-arylidenehydrazines 1a-e gave the corresponding arylnitriles 2a-e, 2-aminobenzimidazole 3, 2,4,5-triphenylimidazole 4, 1,3-diphenyl-8H-2,3a,8-triazacyclopenta[a]indene 5, and 5,11-diphenyl-6H,12H-dibenzimidazo[1,2-a];1’,2’-d]pyrazine 6. The kinetics and analysis of the products of reaction are reported and used to elucidate the mechanism of the elimination process. 相似文献
96.
Asymmetric acyl-transfer promoted by readily assembled chiral 4-N,N-dialkylaminopyridine derivatives
Dálaigh CO Hynes SJ O'Brien JE McCabe T Maher DJ Watson GW Connon SJ 《Organic & biomolecular chemistry》2006,4(14):2785-2793
The development of a new class of chiral 4-N,N-dialkylaminopyridine acyl-transfer catalysts capable of exploiting both van der Waals (pi) and H-bonding interactions to allow remote chiral information to stereochemically control the kinetic resolution of sec-alcohols with moderate to excellent selectivity (s = 6-30). Catalysts derived from (S)-alpha,alpha-diarylprolinol are considerably superior to analogues devoid of a tertiary hydroxyl moiety and possess high activity and selectivity across a broad range of substrates. 相似文献
97.
Maher RC Cohen LF Gallop JC Le Ru EC Etchegoin PG 《The journal of physical chemistry. B》2006,110(13):6797-6803
We make systematic measurements of Raman anti-Stokes/Stokes (aS/S) ratios using two different laser excitations (514 and 633 nm) of rhodamine 6G (RH6G) on dried Ag colloids over a wide range of temperatures (100 to 350 K). We show that a temperature scan allows the separation of the contributions to the aS/S ratios from resonance effects and heating/pumping, thus decoupling the two main aspects of the problem. The temperature rise is found to be larger when employing the 633 nm laser. In addition, we find evidence for mode specific vibrational pumping at higher laser power densities. We analyze our results in the framework of ongoing discussion on laser heating/pumping under surface-enhanced Raman scattering (SERS) conditions. 相似文献
98.
Maher RC Cohen LF Le Ru EC Etchegoin PG 《The journal of physical chemistry. B》2006,110(39):19469-19478
We present an in-depth analysis of the experimental estimation of cross-sections in surface enhanced raman scattering (SERS) by vibrational pumping. The paper highlights the advantages and disadvantages of the technique, pinpoints the main aspects and limitations, and provides the underlying physical concepts to interpret the experimental results. Examples for several commonly used SERS probes are given, and a discussion on future possible developments is also presented. Obtaining good estimates of SERS cross-sections is, in general, an extremely hard problem and has been a longstanding ambition of the SERS community for reasons that go from the purely applied (quantification of signals) to the more fundamental (comparisons of theoretical electromagnetic enhancement factors with experiment). Any method that can produce a standard protocol for the estimation of cross-sections is, accordingly, of great interest and an effort to understand its principles and limitations is required. 相似文献
99.
100.
Mohammed A. Al-Nuri Mohammed A. Hannoun Nidal A. Zatar Maher A. Abu-Eid Waheed J. Al-Jondi Ahmad I. Hussein 《光谱学快报》2013,46(4):409-416
A new method for isolation and spectrophotometric determination of plumbagin is presented. Plumbagin was isolated by thin layer chromatography (TLC) and column chromatography (CC) techniques, as an orange tinged yellow long crystalline substances. Plumbagin exhibits two absrop-tion maxima at 410 and 510 nm. Stability of the color, pKa value, and the effect of pH were studied. Beer's law is obeyed over the range 0.9-45 ppm. The method is applied to the determination of plumbagin in roots, stems, and leaves of Plumbago europaea L. plant. 相似文献