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11.
The use of wet and dry ashing procedures to decompose marine biological tissues and to degrade organoarsenic compounds to inorganic arsenic for analysis by zinc-column arsine generation and atomic-absorption spectrophotometry was investigated. Wet ashing with nitric, sulphuric and perchloric acids (10:2:3 v/v) released the largest percentage of arsenic from fish tissue and quantitatively degraded methylated and other organoarsenic compounds to inorganic arsenic. The arsenic concentrations found when standard reference materials were ashed with this acid mixture were in agreement with the certified values. 相似文献
12.
Laser Dopple anemometry (LDA) measurements of the particle velocity are carried out during an induction plasma spraying operation. The velocity of nickel alloy particles, or molten droplets, at the exit of an induction plasma torch prior to impact on the substrate is shown to vary with the plasma and powder injection conditions. Plasma spraying under soft vacuum (150–450 Torr) gives rise to substantially higher particle velocities (40–60 m/sec) compared to those attained at atmospheric pressure (10–20 m/sec). 相似文献
13.
Micro-Raman spectroscopy was used to investigate the selective adsorption of methanol/water mixtures on the surface of [60] fullerene nanospheres. C60 molecules were dispersed in methanol/water mixtures with different methanol molar fractions ranging between 1 and 0.5. The Raman active pentagon pinch mode shifted significantly (±4 cm−1) as the mixture composition was changed. The shift in the Raman mode was sinusoidal in nature indicating that methanol then water is adsorbed preferentially on the fullerene surface at different mixture compositions. The observed behavior is attributed to structure forming effects of alcohol/water mixtures and the shape and size effect of fullerene surface. 相似文献
14.
R. Abu-Eittah Maher M. Hamed A. A. Mohamed 《International journal of quantum chemistry》1991,39(2):211-226
The electronic absorption spectra of 2-, 3-, and 4-vinylpyridines and 1,2-(2,3-dipyridyl), 1,2-(2,4-dipyridyl), 1,2-(3,4-dipyridyl), and 1,2-(4,4-dipyridyl) ethylenes have been investigated in polar and nonpolar solvents. A correlation has been made between the geometry of the molecule and the observed spectrum. Molecular orbital calculations have been carried out using the INDO/S? CI procedure and a limited geometry optimization. The solvent effect at the MO level has been calculated. MO calculations predicted the existence of nπ* transitions that were not observed experimentally. The wave functions of the different CI states were calculated. The experimental transition energy as well as oscillator strength corresponded satisfactorily with the calculated ones. The observed transitions were assigned according to the results of MO calculations. 相似文献
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A method for the determination of cadmium, copper, lead, and zinc in biological tissues using small volumes of digest is described. An aluminium heating block is used to digest samples and elements are determined by spike-height flame atomic absorption spectrometry. Interferences have been assessed and the sample decomposition procedure evaluated. 相似文献