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81.
Mohammad Fallahian Behzad Pourabbas Mehdi Sharif Kamran Froutani Mehrnoosh Mahmoodian Mahdi Mohammadizadeh 《Polymer Science Series B》2017,59(3):308-319
In this study polypyrrole (PPy) nanoparticles were deposited as a thin film on the modified surface of polyethyleneterephthalate (PET) by in situ chemical polymerization in the presence of sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (DBSNa) and mixture of them as the surfactant. The surface of PET was modified by KOH before deposition and was investigated for conductivity and adhesion of PPy nanoparticles to PET. Resulting conductive flexible films were characterized by UV–Vis spectroscopy, fieldemission scanning electron microscopy, contact angle measurements and four-point-probe technique for conductivity. Direct morphological observation (FESEM) and electrical measurements indicated that the morphology, conductivity and the nature of deposited PPy films depend on surfactant, surface modification of PET and monomer concentration. In optimized process condition, uniform conductive films of PPy were obtained with good adhesion to PET. 相似文献
82.
Bahram Hemmateenejad Javad Tashkhourian Mohammad Mahdi Bordbar Nabiollah Mobaraki 《Journal of the Iranian Chemical Society》2017,14(3):595-604
Today, traditional systems of medicines (such as herbal distillates) become important resources for providing healthcare benefits. The ability to discriminate among closely similar herbal products is critical to ensure their efficacy. This article proposes a pattern-based recognition approach for the rapid discrimination of herbal distillates using a low-cost and sensitive colorimetric sensor array composed of 25 indicators. The color changes of the sensor exposed to the vapor of the herbal distillates can be monitored easily with an ordinary flatbed scanner. The digital representation of the array response was analyzed with hierarchical clustering analysis (HCA) and principal component analysis (PCA). Using new variable selection strategy, 6 indicators among the 25 employed indicators were selected as discriminant elements of the array. So, a complete discrimination (with 100% accuracy) of 46 herbal distillates was achieved. The proposed sensor represented a better resolution when analytes were placed in an oven at 85 °C for 45 min. This colorimetric sensor array demonstrates excellent potential for quality assurance/control applications of herbal distillates. 相似文献
83.
This study presents an easy and cost-effective flow-based cloud point extraction (CPE) method for determining partial amounts of two organophosphorus pesticides (phosalone and ethion) in seawater by HPLC–UV–Vis. In continues CPE methodology, the effect of the different column packing type such as carbon nanotube, polyacrylonitrile nanofiber and fiberglass on pesticide extraction was investigated. The Triton X-100 was utilized as nonionic surfactant, and moreover, effect of different parameters such as pH, temperature, extraction time, surfactant concentration, type and volume of the eluent solution on the extraction efficiency was optimized. Under optimum conditions, the figures of merit of the method for phosalone and ethion were obtained as: the enrichment factor (172 and 166), line range (0.8–300 and 0.5–300 µg L?1, R 2 = 0.9973 and 0.9982), relative standard deviation in concentration of 200 µg L?1 (%RSD = %5.4 and %7.99, N = 5) and limit of detection (LOD = 0.24 and 0.14 µg L?1). The suggested method was successfully used for determination of phosalone and ethion in Chabahar Bay seawaters with satisfactory results. 相似文献
84.
Mahdi?Saedshoar?Heris Mohammad?JavidiEmail author 《Mediterranean Journal of Mathematics》2017,14(3):134
In this paper, we study the fractional backward differential formula (FBDF) for the numerical solution of fractional delay differential equations (FDDEs) of the following form: \(\lambda _n {}_0^C D_t^{\alpha _n } y(t - \tau ) + \lambda _{n - 1} {}_0^C D_t^{\alpha _{n - 1} } y(t - \tau ) + \cdots + \lambda _1 {}_0^C D_t^{\alpha _1 } y(t - \tau ) + \lambda _{n + 1} y(t) = f(t), t \in [0,T]\), where \( \lambda _i \in \) \(\mathbb {R}\,(i = 1,\ldots ,n + 1)\,,\,\lambda _{n + 1} \ne 0,\,\, 0 \leqslant \alpha _1< \alpha _2< \cdots< \alpha _n < 1,\,\,T > 0,\) in Caputo sense. We find the Green’s functions for this equation corresponding to periodic/anti-periodic conditions in term of the Mittag-Leffler type. Our investigation is focused on stability properties of the numerical methods and we determine stability regions for the FDDEs. Finally, some numerical examples are given to show the effectiveness of the numerical method and the results are in excellent agreement with the theoretical analysis 相似文献
85.
This paper deals with a characterization of a multivariate stable process using an independence property with a positive random variable. Moreover, we establish a characterization of a multivariate Lévy process based on the notion of cut in a natural exponential family. This allows us to draw some related properties. More precisely, we give the probability density function of this process and the law of the mixture of the Lévy process governed by the convolution semigroup with respect to an exponential random variable. These results are confidentially connected with the univariate case given by [G. Letac and V. Seshadri, Exponential stopping and drifted stable processes, Stat. Probab. Lett., 72:137–143, 2005]. 相似文献
86.
Cross-linked poly(diallyldimethylammonium chloride) and its derivative copolymers were synthesized and used as phase transfer
catalyst in the nucleophilic substitution reaction especially halogen exchange reactions. In addition, the effect of hydrophilic-hydrophobic
character of the polymers in the nucleophilic reactions was investigated. 相似文献
87.
Technical properties of two naphthalimide based disperse dyes on nylon 6 and polyester fibers were investigated in the presence of urea.The two naphthalimide based disperse dyes were synthesized.The dyes were purified and then fully characterized using ~1H-NMR,FTIR and melting point analysis.Dispersion of the dyes was prepared in water and applied on nylon 6 and PET fibers.The dyes offered good build-up properties on the substrates.In order to increase dye adsorption of the substrates,urea was added into... 相似文献
88.
Mahdi Rezaei Sameti 《中国化学》2011,29(2):237-242
13C NMR chemical shifts have been calculated for structures of some substituted 3‐anilino‐2‐nitrobenzo‐[b]thiophenes ( 2 o) and 2‐anilino‐3‐nitrobenzo[b]thiophenes ( 3 o) derivatives containing OH, NH2, OMe, Me, Et, H, F, Cl and Br. The molecular structures were fully optimized using B3LYP/6‐31G(d,p). The calculation of the 13C shielding tensors employed the GAUSSIAN 03 implementation of the gauge‐including atomic orbital (GIAO) and continuous set of gauge transformations (CSGT) by using 6‐311++G(d,p) basis set at density functional levels of theories (DFT). The isotropic and the anisotropy parameters of chemical shielding for all compounds are calculated. The predicted 13C chemical shifts are derived from equation δ=δ0+δ where δ is the chemical shift, δ is the absolute shielding, and δ0 is the absolute shielding of the standard TMS. Excellent linear relationships have been observed between experimental and calculated 13C NMR chemical shifts for all derivatives 相似文献
89.
The application of Co(Ⅲ)/Al2O3 catalyst in Fischer-Tropsch synthesis(FTS)was studied in a wide range of synthesis gas conversions and compared with Fuzzy Simulation results.Present study applies fuzzy model to predicting the product composition of CH4,CO2 and CO in Fischer-Tropsch process for natural gas synthesis,in which the input vector was 4-dimension including four variables(operating pressure, operating temperature,time and CO/H2 ratio)of 70 different experiments and the output product is a composition of CO2,CO and CH4. The Mamdani algorithm has been applied to the training of the fuzzy system and the test set was used to evaluate the performance of the system including R2,ARE,AARE and SD.The results demonstrated that the predicted values from the model were in good consistency with the experimental data.The work indicates how fuzzy inference system(FIS),as a promising predicting technique,would be effectively used in FTS. 相似文献
90.