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排序方式: 共有212条查询结果,搜索用时 15 毫秒
11.
Sayahi Mohammad Hosein Saghanezhad Seyyed Jafar Mahdavi Mohammad 《Research on Chemical Intermediates》2018,44(1):739-747
Research on Chemical Intermediates - A novel four-component approach for the synthesis of 1-phenyl-1,4-dihydro-2H-9-oxa-4-aza-phenanthrene-3,10-dione derivatives has been presented via the reaction... 相似文献
12.
Niloofar Seydi Behnam Mahdavi Sogand Paydarfard Akram Zangeneh Mohammad Mahdi Zangeneh Fariba Najafi Ali R. Jalalvand Elham Pirabbasi 《应用有机金属化学》2019,33(9)
In recent decades, nanotechnology is growing rapidly owing to its widespread application in science and industry. The aim of the experiment was chemical characterization and evaluation of cytotoxicity, antioxidant, antibacterial, antifungal, and cutaneous wound healing activities of titanium nanoparticles using aqueous extract of Ziziphora clinopodioides Lam leaves (TiNPs@Ziziphora). These nanoparticles were characterized by fourier transformed infrared spectroscopy (FT‐IR), field emission scanning electron microscopy (FE‐SEM), energy dispersive X‐ray spectroscopy (EDS), and UV–visible spectroscopy. The synthesized TiNPs@Ziziphora had great cell viability dose‐dependently (Investigating the effect of the plant on human umbilical vein endothelial cells (HUVECs) cell line) and revealed this method was nontoxic. Then, 2,2‐diphenyl‐1‐picrylhydrazyl (DPPH) free radical scavenging test was done to assess the antioxidant properties, which indicated similar antioxidant potentials for TiNPs@Ziziphora and butylated hydroxytoluene. Agar diffusion tests were applied to determine the antibacterial and antifungal characteristics. Minimum Inhibitory Concentration (MIC), Minimum Bactericidal Concentration (MBC), and Minimum Fungicidal Concentration (MFC) were specified by macro‐broth dilution assay. The data were analyzed by SPSS 21 software (Duncan post‐hoc test). TiNPs@Ziziphora indicated higher antibacterial and antifungal effects than all standard antibiotics (p ≤ 0.01). Also, TiNPs@Ziziphora inhibited the growth of all bacteria at 2‐16 mg/ml concentrations and removed them at 2‐32 mg/ml concentrations (p ≤ 0.01). In case of antifungal properties of TiNPs@Ziziphora, they prevented the growth of all fungi at 2‐8 mg/ml concentrations and destroyed them at 2‐16 mg/ml concentrations (p ≤ 0.01). In vivo experiment, after creating the cutaneous wound, the rats were randomly divided into six groups: untreated control, treatment with Eucerin basal ointment, treatment with 3% tetracycline ointment, treatment with 0.2% TiO2 ointment, treatment with 0.2% Z. clinopodioides ointment, and treatment with 0.2% TiNPs@Ziziphora ointment. These groups were treated for 10 days. For histopathological and biochemical analysis of the healing trend, a 3 × 3 cm section was prepared from all dermal thicknesses at day 10. Use of TiNPs@Ziziphora ointment in the treatment groups substantially reduced (p ≤ 0.01) the wound area, total cells, neutrophil, and lymphocyte and remarkably raised (p ≤ 0.01) the wound contracture, hydroxyl proline, hexosamine, hexuronic acid, fibrocyte, and fibrocytes/fibroblast rate compared to other groups. In conclusion, the results revealed the useful non‐cytotoxic, antioxidant, antibacterial, antifungal, and cutaneous wound healing effects of TiNPs@Ziziphora. 相似文献
13.
Saeed Bahadorikhalili Samira Ansari Haleh Hamedifar Leila Ma'mani Mohsen Babaei Rahim Eqra Mohammad Mahdavi 《应用有机金属化学》2019,33(4)
In this paper, a novel catalyst is introduced based on the immobilization of palladium on modified magnetic graphene oxide nanoparticles. The catalyst is characterized by several methods, including transmission electron microscopy, scanning electron microscopy, X‐ray fluorescence, vibrating‐sample magnetometer, Fourier transform‐infrared and dynamic light scattering (DLS) analysis. The activity of the catalyst was investigated in the synthesis of 4(3H)‐quinazolinones via Pd‐catalyzed carbonylation‐cyclization of N‐(2‐bromoaryl) benzimidamides by Mo (CO)6. The Mo (CO)6 is used as a carbon monoxide source for performing the reaction under mild conditions. The catalyst showed good reusability, and no change in activity was observed after 10 cycles of recovery. 相似文献
14.
Hossein Mahdavi B. O. Mahdi Sadeghzadeh Nader Taheri Qazvini 《Journal of Polymer Science.Polymer Physics》2009,47(5):455-462
The phase behavior of poly(N‐tertbutylacrylamide‐co‐acrylamide) (PNTBAM) in pure water and mixture of water–methanol is studied at different temperatures. The different compositions of PNTBAM are prepared by free‐radical polymerization technique and their phase behavior is studied by turbidimetry. The effects of copolymer and solvent composition on the phase behavior of the copolymers are discussed. It has been suggested that the inhomogenities in polymer chains are responsible for lowering the rate of phase transition by increasing the N‐tertbutylacrylamide (NTBAM) and methanol contents in copolymer and mixture, respectively. For the first time we have revealed that there are second‐order binary interactions in the water–methanol which are dominant in the special range of copolymer composition. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 455–462, 2009 相似文献
15.
Abedinifar Fahimeh Babazadeh Rezaei Elham Biglar Mahmood Larijani Bagher Hamedifar Halleh Ansari Samira Mahdavi Mohammad 《Molecular diversity》2021,25(4):2571-2604
Molecular Diversity - Thiophene-based analogs have been fascinated by a growing number of scientists as a potential class of biologically active compounds. Furthermore, they play a vital role for... 相似文献
16.
Bamoharram Fatemeh F Roshani Mina Heravi Majid M Mahdavi Masoumeh Javid Ali Emampour Jalal Sh 《中国化学》2010,28(6):974-976
Isoxazolo[5,4‐d]pyrimidine‐4,6(5H,7H)diones 2a – 2f have been synthesized from the reaction of ethyl 5‐amino‐3‐methyl‐4‐isoxazole carboxylate ( 1 ) with aryl isocyanates in the presence of Keggin heteropolyacid H3[PW12O40] as a green solid acid catalyst at room temperature in a one‐pot process in good yields. 相似文献
17.
Nahid Shahabadi Soheila Kashanian Marzieh Khosravi Maryam Mahdavi 《Transition Metal Chemistry》2010,35(6):699-705
The water-soluble Ni(II) complex, [Ni(bipy)2(phen-dione)](OAc)2·2H2O (bipy = 2,2′-bipyridine and phen-dione = 1,10-phenanthroline-5,6-dione) has been synthesized and characterized by physico-chemical
and spectroscopic methods. The binding interactions of this complex with calf thymus DNA (CT-DNA) were investigated using
fluorimetry, spectrophotometry, circular dichroism and viscosimetry. In fluorimetric studies, the enthalpy and entropy of
the reaction between the complex and CT-DNA showed that the reaction is exothermic (ΔH = −123.9 kJ mol−1; ΔS = −323.5 J mol−1 K−1). The competitive binding studies showed that the complex could not release methylene blue completely. The complex showed
absorption hyperchromism in its UV–Vis spectrum with DNA. The calculated binding constant, K
b obtained from UV–Vis absorption studies was 2 × 105 M−1. Moreover, the complex induced detectable changes in the CD spectrum of CT-DNA, as well as changes in its viscosity. The
results suggest that this nickel(II) complex interact with CT-DNA via a groove-binding mode. 相似文献
18.
Samaneh Zarei Golzar Komeili Saeed Bahadorikhalili Azadeh Yahya-Meymandi Morteza Karami-Zarandi Bagher Larijani Mahmood Biglar Seyed Esmaeil Sadat Ebrahimi Mohammad Mahdavi 《Journal of heterocyclic chemistry》2020,57(12):4254-4261
In this paper, a novel series of 2-(4-((1-aryl-1H-1,2,3-triazol-4-yl)methoxy)phenyl)2-(2-oxoazetidin-1-yl)acetamide derivatives are synthesized in two steps. The first step involved Ugi multicomponent reaction of β-alanine, o-(propargyl)benzaldehyde and isocyanide derivatives. The product of this step, underwent a click 1,3-dipolar cycloaddition reaction with benzyl azide derivatives. The 2-(4-((1-aryl-1H-1,2,3-triazol-4-yl)methoxy)phenyl)2-(2-oxoazetidin-1-yl)acetamide product was characterized and their antibacterial activities were evaluated against various G-positive (Staphylococcus aureus and Bacillus subtilis) and G-negative (Pseudomonas aeruginosa and Escherichia coli) bacteria, using minimal inhibition concentration. The compounds showed very good antimicrobial activity and a number of products have been more active than ciprofloxacin. 相似文献
19.
Maryam Sadat Hosseini-ZareMohammad Mahdavi Mina SaeediMehdi Asadi Shahrzad JavanshirAbbas Shafiee Alireza Foroumadi 《Tetrahedron letters》2012,53(27):3448-3451
We describe a new one-pot synthesis of 2,3-diaryl-5H-imidazo[2,1-a]isoindol-5-ones via the reaction of 1,2-diketones, 2-formylbenzoic acids, and ammonium acetate in acetic acid under reflux conditions and in the absence of a catalyst. 相似文献
20.
Cross-linked poly(diallyldimethylammonium chloride) and its derivative copolymers were synthesized and used as phase transfer
catalyst in the nucleophilic substitution reaction especially halogen exchange reactions. In addition, the effect of hydrophilic-hydrophobic
character of the polymers in the nucleophilic reactions was investigated. 相似文献