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61.
The Er3+ -Yb3+ codoped in Li2O content tungsten -tellurite (TWL) transparent glasses are synthesized and measured the absorption, Raman and upconversion
luminescence (UPL) spectra. At room temperature intense green emission peak at 560 nm ( 4S3/2→4I15/2) and red emission peak at 670 nm ( 4F9/2→4I15/2) of Er3+ observed even at minimum 86 mW pumping power of infrared 980 nm excitation. For structure of the TWL glass, Raman spectrum
result revealed that an important role of WO3 in the formation of glass network linkage with Li2O. Under this influence estimated lifetime of the 4I11/2 of Er3+ was 1.89 μs and due to lower phonon energy of the glass produce strong upconversion signal. The effect of Er2O3 concentration on emission intensity result indicated that green emission intensity initially increase in compare to red emission.
Under the 980 nm pump power variation measured the relatively increases the red emission to the green emission intensity and
analyze the possible upconversion mechanism and process. 相似文献
62.
It is shown that a vorticity, constructed from the spin field of a quantum spinning plasma, combines with the classical generalized vorticity (representing the magnetic and the velocity fields) to yield a new grand generalized vorticity that obeys the standard vortex dynamics. Expressions for the quantum or spin vorticity and for the resulting generalized helicity invariant are derived. Reduction of the rather complex spinning quantum system to a well known and highly investigated classical form opens familiar channels for the delineation of physics peculiar to dense plasmas spanning solid state to astrophysical objects. A simple example is worked out to show that the magnetics of a spinning plasma can be much richer than that of the corresponding classical system. 相似文献
63.
64.
Synovial sarcoma: MR imaging 总被引:2,自引:0,他引:2
Ten patients with biopsy-proved synovial sarcoma were evaluated by magnetic resonance (MR) imaging on a 1.5-T unit. The lesions showed intermediate signal intensity on T1-weighted images and heterogeneous high signal intensity on T2-weighted images. Tumors were well-demarcated from normal tissues. Additional information included adjacent bone involvement (one case), femoral vein invasion by tumor (one case), and hemorrhage within the tumors (one case). Four patients underwent a repeat MR examination following chemotherapy. This showed a decrease in size and increase in the signal intensity of three tumors on T2-weighted images, proven to be due to necrosis in one. These changes correlated with clinical regression of disease. While MR in synovial sarcoma does not have any specific signal intensity, it proved to be useful in defining the extent of disease and in determining the response to chemotherapy. 相似文献
65.
66.
Nature is a generous source of compounds with the potential for prevention of infections. Antimicrobial screening of aqueous extract from bark of wild Himalayan cherry (Prunus cerasoides) was carried out against various pathogenic microorganisms with inhibition zone ranging from 19 to 24 mm. An optimization strategy, which included classical method and statistical method (RSM), was applied to optimize the effect of process variables. Fifteen percent plant material extracted at 40 °C for 60 min and at its natural pH (4.5) exhibited best antimicrobial activity with an average zone of inhibition ranging from 19 to 29 mm. Statistical optimization using RSM further enhanced the activity by 1.09–1.24 folds. Minimum inhibitory concentration of the aqueous extract against different microorganism ranged from 1 to 10 mg/ml. The aqueous extract was found to be reasonably thermostable at boiling temperature for 1 h. Viable cell count (VCC) studies of the extract showed it to be bactericidal in nature. Further, the aqueous extract was found to be neither cytotoxic nor mutagenic, when evaluated by MTT assay and Ames mutagenicity test. The results suggest that the aqueous extract of P. cerasoides could be a potential source to obtain new antimicrobials and effective herbal medicines to combat the problem of ever emerging microbial resistance. 相似文献
67.
Vishal A. Mahajan 《Tetrahedron letters》2005,46(6):1009-1012
A synthesis of novel 4-(substituted)benzyl-5-methylene-2(5H)-furanones involving Stobbe condensation of substituted aldehydes with ethyl levulinate followed by treatment with acetic anhydride in the presence of sodium acetate, has been developed. 相似文献
68.
The stability constants of the fluoride complexes of cerium(IV) in 1 M (HClO(4), NaClO(4)) medium have been measured potentiometrically using a fluoride ion-selective electrode. Quantitative oxidation of cerium to its tetravalent state and its stabilisation in the perchlorate medium were accomplished by oxidation with AgO followed by quick addition of a known amount of fluoride ion. This procedure ensures stability of the oxidation state and prevents hydrolysis and polymerisation of Ce(IV). Logarithms of the average values of beta(1), beta(2), beta(3) and beta(4) were estimated to be 7.57+/-0.04, 14.50+/-0.03, 20.13+/-0.37 and 24.14+/-0.10 respectively. 相似文献
69.
Chemoselective hydrogenation of substituted nitroaromatics using novel water-soluble iron complex catalysts 总被引:2,自引:0,他引:2
Deshpande RM Mahajan AN Diwakar MM Ozarde PS Chaudhari RV 《The Journal of organic chemistry》2004,69(14):4835-4838
Chemoselective hydrogenation of substituted nitroaromatic compounds by water-soluble iron complex catalysts with molecular hydrogen has been reported for the first time. This biphasic catalyst presents an opportunity for a solvent-free hydrogenation. This catalyst system provides a low-cost, efficient alternative to the selective but environmentally unacceptable stoichiometric reductions as well as the supported noble metal catalysts used for hydrogenation. An efficient recycling strategy has resulted in a cumulative turnover number above 6000. 相似文献
70.
Determination of fluoride by spectrophotometry of Arsenazo(III) complex of the back-extracted Th(IV)
R. K. Rastogi M. A. Mahajan N. K. Chaudhuri 《Journal of Radioanalytical and Nuclear Chemistry》1994,188(4):291-298
A method based on the back-extraction of Th(IV) from its TTA complex in benzene by aqueous F– followed by spectrophotometric measurement of Th(IV), for the determination of fluoride has been developed. The coefficients of variation obtained are 2.4% and 1.4% in 11 determinations at F– concentration levels of 1.0 g ml–1, respectively. 相似文献