全文获取类型
收费全文 | 668篇 |
免费 | 15篇 |
国内免费 | 73篇 |
专业分类
化学 | 493篇 |
晶体学 | 1篇 |
力学 | 32篇 |
数学 | 1篇 |
物理学 | 229篇 |
出版年
2016年 | 2篇 |
2015年 | 10篇 |
2013年 | 7篇 |
2012年 | 7篇 |
2011年 | 158篇 |
2010年 | 69篇 |
2009年 | 80篇 |
2008年 | 10篇 |
2007年 | 8篇 |
2006年 | 17篇 |
2005年 | 34篇 |
2004年 | 108篇 |
2003年 | 58篇 |
2002年 | 60篇 |
2001年 | 47篇 |
2000年 | 21篇 |
1999年 | 7篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 11篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1933年 | 2篇 |
排序方式: 共有756条查询结果,搜索用时 15 毫秒
81.
A self-intermolecular cyclocondensation reaction of 3,4-dihydropyrimidine-2-thione(DHPM) to give a novel tricyclic structure containing DHPM core in the presence of diethyl azodicarboxylate(DEAD) and triphenylphosphine(TPP) at room temperature is reported. 相似文献
82.
YUAN Jing YAN Husheng** CHENG Xiaohui HE Binglin The State Key Laboratory of Functional Polymer Materials for Adsorption Separation Institute of Polymer Chemistry Nankai University Tianjin 《Chinese Journal of Reactive Polymers》2001,(1)
1. INTRODUCTION Biospecific affinity chromatography is a powerful technique for purification of proteins [1]. The biological affinity ligands in common use include enzyme substrates, inhibitors, cofactors, receptors, antibodies, etc. The advantage of these biological ligands is their very high recognition specialty for particular proteins. As a result, proteins can be purified in fewer steps, often to homogeneity, in a laboratory scale. However, scale-up of the analytical and laboratory p… 相似文献
83.
YUAN ChunXue XIN Qian LIU HuiJun WANG Lei JIANG MinHua & TAO XuTang State Key Laboratory of Crystal Materials Sh ong University Jinan China 《中国科学B辑(英文版)》2011,(4)
Trger's base (TB) is a well-known chiral molecule with rigid concave shape that makes it applicable in different areas such as superamolecular chemistry,molecular recognition,biological labeling,and so on.In this article,we briefly summarize some recent research progress in the optoelectronic properties of novel TB analogues and their applications in optoelectronic field with emphasis on the developments achieved in our group. 相似文献
84.
HU Fang ZHANG Chun-hua ZHANG Song MING Xing CHEN Gang WEI Ying-jin WANG Chun-zhong . School of Materials Science Engineering Shenyang University of Technology Shenyang P. R. China . College of Physics State Key Laboratory of Superhard Materials Jilin University Changchun . College of Physical Science Technology Huanggang Normal University Huanggang 《高等学校化学研究》2011,(3):528-530
1 Introduction Low-dimensional nanostructures, such as nanorods, nanowires, and nanotubes, have received much attention for their superior optical, electrical, catalytic and magnetic properties. 相似文献
85.
ZHANG QingChao PANG ShuJie LI Yi & ZHANG Tao Key Laboratory of Aerospace Materials Performance School of Materials Science Engineering Beijing University of Aeronautics Astronautics Beijing China 《中国科学:物理学 力学 天文学(英文版)》2011,(9)
Bulk metallic glasses (BMGs) with large supercooled liquid region are promising materials for superplastic forming. In this paper, we demonstrate a microstructure-based strategy to pinpoint the composition with the largest supercooled liquid region in La 86 x Al 14 Cu x (x=16 at%-20 at%) metallic glass system. By monitoring the changes in crystallization behavior of the glassy alloys with composition to search for the alloys exhibiting eutectic crystallization, the glassy alloys with the largest supercooled... 相似文献
86.
LI Ming DAI ChangJian & XIE Jun Key Laboratory of Display Materials Photoelectric Devices Ministry of Education Tianjin China School of Science Tianjin University of Technology Tianjin 《中国科学:物理学 力学 天文学(英文版)》2011,(6)
The odd-parity high-lying states of the Sm atom are investigated systematically by a three-color resonant excitation scheme with two different excitation paths.The two intermediate states,4f 6 6s7s 7 F 0 and 4f 6 6s7s 7 F 1 are employed for paths I and II,respectively.Fifty-seven bound states are detected with paths I and II in the energy range between 44188 and 45515 cm 1,while 64 autoionizing states are found in the energy range from 45528 to 45761 cm 1.Not only the level energies of all observed states,b... 相似文献
87.
ZHANG Hong YU Yaoting PAN Jilun XU Yuanping ZHU Hesun Bioactive Materials Research Laboratory Nankai University Tianjin The Center of Materials Research Beijing Institute of Technology Beijing 《Chinese Journal of Reactive Polymers》2001,(1)
1. INTRODUCTION Bioreactors using membranes as substrates of cell cultures have become widely used for hybrid liver support systems [1]. For enhancing and prolonging the metabolism of the bioreactors, cytocompatible membranes are necessary because the cell culture is closely affected by the substrate surface. Surface factors considered to be important in cell culture are the concentration of ionic groups, the nature of polar and non-polar groups and the hydrophilic-hydrophobic balance [2].… 相似文献
88.
CHEN YuJin SHI XiaoLing CAO MaoSheng & ZHU ChunLing School of Materials Science Engineering Beijing Institute of Technology Beijing China Micro-Nano Technologies Research Center Hunan University Changsha College of Science Harbin Engineering University Harbin College of Material Science Chemical Engineering 《中国科学G辑(英文版)》2009,(7)
CdS/α-Fe2O3 hierarchical nanostructures, where the CdS nanorods grow irregularly on the side surface of α-Fe2O3 nanorods, were synthesized via a three-step process. The diameters and lengths of CdS nanorods can be tuned by changing the ethylenediamine (EDA) and Cd ion concentrations. The magnetic investigations by superconducting quantum interference device indicate that the hierarchical nanostructures have an Morin transition at lower temperature (230 K) than that of the single bulk α-Fe2O3 materials (263 ... 相似文献
89.
γ射线辐照石英玻璃吸收光谱的研究 总被引:2,自引:0,他引:2
石英玻璃以其低热膨胀系数、高紫外透过率而成为不可缺少的光学材料,但并不是所有的石英玻璃都可以作为光学材料。有些石英玻璃在短波长射线环境运行一段时间后,透过率下降,甚至变黑。哪些石英玻璃能够用于射线环境、哪些不能用?这要求对石英玻璃分类。美国Lawerence Livemore国家实验室提出的LL分类法中隐藏一个理论缺陷,即它暗中假定石英玻璃在γ射线照射下,只感生E′,D_0,B_1,Al等4条吸收带,虽然他们所接触的石英玻璃是这种情况,但缺乏理论依据,没有理由认为任何石英玻璃在γ射线照射下只有这4条感生吸收带,事实上确实有的石英玻璃在γ射线照射下还有其他感生吸收带,LL分类法就无法对这种石英玻璃归类。石英玻璃对γ射线的响应有三类,一是有响应的辐照变色石英玻璃,另一是没有响应的耐辐照石英玻璃,第三类是介于这两类之间的、不产生可见的感生吸收带但产生紫外感生吸收带的过渡类石英玻璃。石英玻璃耐γ射线照射的能力取决于杂质总量和羟基含量的比值;比值越大,耐辐照能力越差;比值大于2为变色石英玻璃,比值小于0.01为耐辐照石英玻璃;比值介于其间为紫外透过下降的石英玻璃,即过渡类石英玻璃。 相似文献
90.