Synthesis and magnetic properties of CdS/α-Fe_2O_3 hierarchical nanostructures

CdS/α-Fe2O3 hierarchical nanostructures, where the CdS nanorods grow irregularly on the side surface of α-Fe2O3 nanorods, were synthesized via a three-step process. The diameters and lengths of CdS nanorods can be tuned by changing the ethylenediamine (EDA) and Cd ion concentrations. The magnetic investigations by superconducting quantum interference device indicate that the hierarchical nanostructures have an Morin transition at lower temperature (230 K) than that of the single bulk α-Fe2O3 materials (263 ...     

掺锌LiNbO3晶体的生长及其光学性能

在LiNbO₃中掺进3mol%、5mol%、7mol%ZnO生长Zn:LiNbO₃晶体.测试Zn:LiNbO₃晶体的吸收光谱,研究Zn:LiNbO₃晶体吸收边紫移的机制.测试Zn:LiNbO₃晶体的红外光谱,研究Zn(7mol%):LiNbO₃晶体OH 吸收峰由3484cm^-1移到3530cm^-1的机制.测试Zn:LiNbO₃晶体倍频转换效率和相位匹配温度,研究Zn:LiNbO₃晶体倍频转换效率增强的机制.     

含Eu3+离子的Na2O-K2 O-SiO2-Al2O3系统玻璃的制备及其变温发射光谱与结构特性

通过高温熔融法制备了含Eu^3 离子的Na2O-K2O-SiO2-Al2O3系统玻璃。在488nm波长光的激发下，系统地研究了上述玻璃从77K到700K温度范围的变温发光特征。发现总的荧光强度首先随温度的升高而大幅度升高，然后随温度的升高而减少，用声子辅助吸收与热激活过程及温度淬灭效应定性地解释了上述强度的变化，同时测量与分析了Eu^3 离子的晶格场参量。结果表明，Eu^3 离子与氧离子的距离随着温度升高而变短，而Eu^3 离子的配位数不随温度而变化。     

Morse势函数和钼单晶等的临界切应力的温度依赖性

综述了以往钼、铁、铝、镁等单晶临界切应力温度依赖性的实验；指出：在滑移系统不变的条件下，在一定的温度范围内，临界切应力和温度呈近似指数关系是相当普遍的规律。Ｍｏｒｓｅ势函数应用和实验的吻合说明原子间力对屈服应力的重要作用。结合近来发展讨论今后的发展，指出金属范性的本质深入到电子结构层次研究的重要意义。     

平面弹性介质多孔多裂纹问题的一种数值方法

提出了平面弹性介质中多孔洞多裂纹相互作用问题的一种数值计算方 法. 通过把适于单一裂纹的Bueckner原理扩充到含有多孔洞多裂纹的一般体系，将原问题 分解为承受远处载荷不含裂纹不含孔洞的均匀问题，和在远处不承受载荷但在裂纹面上和孔 洞表面上承受面力的多孔洞多裂纹问题. 于是，以应力强度因子作为参量的问题可以通过考 虑后者(多孔洞多裂纹问题)来解决，而利用提出的杂交位移不连续法，这种多孔 洞多裂纹问题是容易数值求解的. 算例说明该数值方法对分析平面弹性介质中多孔洞多裂纹 相互作用的问题既简单又有效.     

Effect of chenodeoxycholic acid (CDCA) additive on phenothiazine dyes sensitized photovoltaic performance

The effects of chenodeoxycholic acid (CDCA) in a dye solution as a co-adsorbent on the photovoltaic performance of dye-sensitized solar cells (DSSCs) based on two organic dyes containing phenothiazine and triarylamine segments (P1 and P2) were investigated.It was found that the coadsorption of CDCA can hinder the formation of dye aggregates and improve electron injection yield and thus Jsc.This has also led to a rise in photovoltage,which is attributed to the decrease of charge recombination.The DSSC based ...     

Fabrication and characterization of Ce_(0.7)Zr_( 0.3)O_2 nanorods having high specific surface area and large oxygen storage capacity

Nanorod-like Ce 0.7 Zr 0.3 O 2 solid solutions were synthesized by a sodium dodecyl sulfate-assisted precipi- tation method. The samples were characterized by means of scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and specific surface area measurement. Typical Ce 0.7 Zr 0.3 O 2 nanorods were 40 nm in average diameter and 450 nm in length, with specific surface area and oxygen storage capacity of 194 m 2 /g and 374 mol/g, respectiv...     

Solid-liquid Metastable Equilibria in Quaternary System Li_2SO_4+Li_2CO_3+Li_2B_4O_7+H_2O at 288 K

Metastable equilibrium solubilities and densities of quaternary system Li2SO4+Li2CO3+ Li2B4O7+H2O at 288 K were determined by isothermal evaporation method. According to the experimental data, the metastable equilibrium phase diagram was plotted. The metastable phase diagram had one invariant point F, three double saturated liquid curves E1F, E2F and E3F, and three crystallization fields corresponding to Li2SO4·H2O, Li2CO3 and LiBO2·8H2O. It was found that lithium sulphate(Li2SO4) had the highest concentrat...     

掺杂PVK薄膜的荧光谱及电荷转移

根据PVK掺杂后荧光谱的变化，说明掺杂PVK薄膜的电致发光存在着从基质分子向掺杂分子的能量传递，用一个由单链模型扩展到包括杂质的哈密顿量进行数值求解，结果表明：在PVK和杂质分子之间有效的能量传递是源于它僮之间的电荷转移，且随着杂质浓度的变化，其荧光谱峰位的移动与掺杂前后系统总能量的改变及荧光谱强度与掺杂后转移的电荷数之间分别存在对应关系。该模型较好地解释了有关的实验结果。