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Four N,N-disubstituted 2-cyano-Δ7-hexahydroindolium salts, 1, have been reduced at a mercury cathode in aqueous buffered solutions at intermediate pH-values. From the catholyte the following products were isolated and identified: 2-(β-cyanoethyl)-cyclohexanone, 5, a secondary amine, 4, and a mixture of cis-trans isomeric tertiary 2-(β-cyanoethyl) cyclohexylamines, 6. A reaction path via the protonated enamine 3 is proposed based on the pH-dependence of the composition of the product mixture and a few reductions in DMF solution. 相似文献
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Modified nucleosides in human serum. 总被引:1,自引:0,他引:1
E P Mitchell L Evans P Schultz R Madsen J W Yarbro C W Gehrke K Kuo 《Journal of chromatography. A》1992,581(1):31-40
Methylated purines and pyrimidines derived from the degradation of transfer ribonucleic acid have been shown to be excreted in abnormal amounts in the urine of patients with cancer. Recent technology developed by Gehrke and Kuo has allowed the separation and quantification of modified nucleosides in serum using reversed-phase high-performance liquid chromatography with diode-array measurement. Serum levels of ten modified nucleosides were measured in 37 normal healthy adults to establish normal values and to correlate activity with age and sex. In addition, serum levels of patients with several malignancies were measured to determine activity in these diseases. Levels of modified nucleosides in normal individuals were consistently reproducible and showed no significant variation among males versus females or with age. Patients with malignant diseases showed consistent elevations and these were highest in patients with more advanced disease. The evidence of no significant differences in the mean levels of modified nucleosides in serum with age or sex in normal adults and elevations in patients with malignancies demonstrate the potential value of modified nucleosides as cancer biomarkers. 相似文献
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The present investigation is part of a project concerning improvements of the working environment for polymer manufacturing processes at high temperatures; for example, welding and extrusion coating.The evolution of gaseous degradation products from unstabilized and antioxidant stabilized low-density polyethylene during thermo-oxidation in air at 210°C has been studied by a simple technique using a modified gas chromatograph. Of the thirteen antioxidants investigated (phenols, phosphites, phosphonites, sulphides and metal dithiocarbamates), only phenols (radical scavengers) effectively suppress the formation of gaseous degradation products from the polymer during an induction period.The gaseous degradation products were analysed with combined gas chromatography-mass spectrometry (GC-MS), using direct trapping on the GC column (Porapak® QS). Apart from water and carbon dioxide, the major products are formaldehyde, acetaldehyde, formic and acetic acids. The addition of effective antioxidants strongly reduces the absolute amounts of the degradation products during the induction period, but does not change their relative quantities. 相似文献
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An efficient strategy is described for the synthesis of enantiopure calystegine alkaloids. The key step employs a zinc-mediated fragmentation of benzyl-protected methyl 6-iodo-glycosides followed by in situ formation of the benzyl imine and Barbier-type allylation with zinc, magnesium, or indium metal. Stereochemistry in the pivotal allylation is controlled by the choice of the metal. The functionalized 1,8-nonadienes, thus formed, are converted into cycloheptenes by ring-closing olefin metathesis. Regioselective hydroboration and oxidation give the corresponding cycloheptanones, which are deprotected to afford the desired calystegines. Hereby, calystegine B(2), B(3), and B(4) are prepared from D-glucose, D-galactose, and D-mannose, respectively. This route constitutes the shortest synthesis of calystegine B(2) and gives rise to the first total syntheses of calystegine B(3) and B(4). 相似文献
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