Stable isotope dilution-mass spectrometry for determining total selenium levels in plants, soils and sewage sludges

Quantitation of selenium in plants, soils and sludges was achieved by isotope dilution-mass spectrometry using a benchtop instrument. Samples for analysis were spiked with (76)Se isotope solution. Plant material was digested on a heating block at 150 degrees C using a mixture of nitric acid and hydrogen peroxide. Selenium in soils and sludges was released by treatment with nitric acid followed by digestion with nitric and hydrofluoric acids. Selenium in the digests was reduced to Se(IV) with hydrochloric acid and derivatised with nitro-1, 2-phenylenediamine to 5'-nitropiazselenol. Analysis by gas chromatography-mass spectrometry using selected ion monitoring was validated using certified reference materials (CRMs) and gave results within the certified range with a low standard deviation. The CRMs plant (Chinese cabbage leaves) and soil (Chinese soil) were found to contain (+/-95% confidence limits) 0.091(+/-0.007) mug g(-1) and 1.67(+/- 0.04) mug g(-1)Se respectively. The certified values were 0.083(+/-0.008) mug g(-1) and 1.56(+/-0.12) mug g(-1) respectively. The selenium content of four different freely drained acid Scottish soils under grasslands was in the range 0.5-0.8 mug g(-1) air-dried soil. Sewage sludges were found to contain measurably more selenium than the soils, and samples of three sludges taken from sites in the UK contained between 1.1 and 3.5 mug g(-1) dry matter.     

Synthesis and Diels-Alder Reactions of a New Kind of Chiral Dienophiles: Cyclic Vinyl-p-tolylsulfilimines

A new kind of chiral dienophiles, cyclic vinyl-p-tolylsulfilimines (2a and 2b), were obtained from the corresponding (Z)-sulfinylacrylonitriles with HBF(4) and methanol. The asymmetric Diels-Alder reaction of optically pure 2a with cyclopentadiene under mild thermal or catalyzed conditions afforded only the endo-4a adduct with complete endo and pi-facial selectivities. The ability of the sulfilimine moiety to enhance the dienophilic reactivity of the double bond is similar to that of the sulfinyl group.     

Applying GIS and Combinatorial Optimization to Fiber Deployment Plans

A decision-support system for the Fiber Deployment Plan problem is developed for the telephone cable network design in the telecommunications industry. The system employs a Geographic Information System (GIS) and uses combinatorial optimization techniques as its components. A mathematical combinatorial optimization model is formulated for the problem and a heuristic solution procedure is developed for the model. A GIS within the ESRI Arc/INFO and ArcView environment is used to provide data needed to build the mathematical combinatorial optimization model and to furnish an interface between the users and computers in data input and in solution result display. Combinatorial optimization techniques are used in the heuristic solution procedure to find good solutions for the optimization model. The developed decision-support system has been used to real life problems and has resulted in tremendous improvements in the telephone cable network design process. The user is completely satisfied with the performance of the system.     

Table-based tests for Bessel function software

A test procedure is developed for software which evaluates the Bessel functionsJ ₀,J ₁,Y ₀,Y ₁. The tests are highly accurate and are applied to various available codes. Results are presented on the performance of the codes.     

Phase diagrams of lyotropic cholesteric fluids

Experimental investigations of lyotropic cholesterics fluids are presented which show that changes in the shape anisotropy and chirality of the micellar population determine the topology of the temperature-concentration phase diagrams. For given amounts of the substances which induce the chirality and modify the shape anisotropy of the micelles, two distinct biaxial cholesteric phases are disclosed in the phase diagrams. This is interpreted in the framework of the catastrophe theory of phase transitions.     

A synthesis of α-aminosulphonic acids

The α-aminosulphonic acid analogues of cysteine and methionine were prepared by sulphonation of the appropriate amines at their α-C atom using Sulfan. It is essential that moisture is excluded at all stages.     

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