The structure of poly(ethylene oxide)-poly(dimethyl-siloxane) triblock copolymers in solution

A series of triblock copolymers consisting of oligomeric segments of poly(ethylene oxide)(PEO) and poly(dimethylsiloxane) (PDMS) were synthesized. These amphiphilic polymers have the general structure (PEO)_n-Z-(PDMS)_m-Z-(PEO)_n or inversely (PDMS)_m-Z–(PEO)_n-Z-(PDMS)_m where “Z” is the group linking the chains of different polarity. n and m varied in the range m, n < 77. These polymers spontaneously form lyotropic mesphases if mixed with water. The phasediagrams and symmetry of the phases were determined. Moreover, photoreactive groups were attached at exactly and only the positions “Z” of the block copolymers. When photocrosslinking was induced in a particular lyotropic mesophase, the arrangement of the molecules in this phase structure was fixed. Although the phase structure collapsed when the systems were freed from water, the structure returned on reswelling. Some rules concerning the tendency of such molecules to self-organize as a function of the molecular structures are obtained.     

Scattering approach to backaction in coherent nanoelectromechanical systems

We present theoretical results for the backaction force noise and damping of a mechanical oscillator whose position is measured by a mesoscopic conductor. Our scattering approach is applicable to a wide class of systems; in particular, it may be used to describe point contact position detectors far from the weak tunneling limit. We find that the backaction depends not only on the mechanical modulation of transmission probabilities, but also on the modulation of scattering phases, even in the absence of a magnetic field. We illustrate our general approach with several simple examples, and use it to calculate the backaction for a movable, Au atomic point contact modeled by ab initio density functional theory.     

A highly-enriched 244Pu reference material for nuclear safeguards and nuclear forensics measurements

Journal of Radioanalytical and Nuclear Chemistry - A highly-enriched 244Pu isotope dilution reference material has been prepared and characterized for metrologically traceable measurements of very...     

Flexibilized styrene‐N‐substituted maleimide copolymers. I. Multiblock copolymers prepared from styrene‐maleimide telechelics and polytetrahydrofuran

Telechelic copolymers of styrene and different N‐substituted‐maleimides (SMIs) with a molecular weight of 2000–8000 g/mol were synthesized using the starved‐feed‐reactor technique and were nearly bifunctional when the monomer feed had a high styrene concentration. The COOH‐terminated rigid SMI blocks were polycondensated with OH‐terminated poly(tetrahydrofuran) (PTHF) blocks, with a molecular weight of 250–1000 g/mol, which are the flexible parts in the generated homogeneous multiblock copolymer. The entanglement density, which is closely related to the toughness of materials, increased in these flexible SMI copolymers (ν_e = 5.2 · 10²⁵ m⁻³) compared to the unflexibilized ones (ν_e = 2.4 · 10²⁵ m⁻³). The glass transition temperature of these flexibilized, single‐phase multiblock copolymers was still high enough to qualify them as engineering plastics. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3550–3557, 2000     

Nuclear orbiting and anomalies in nuclear reactions

In this paper, we report our measurements of back-angle oxygen and carbon particle yields from ¹⁶O+⁸⁹Y, ¹²C+⁹³Nb reactions forming the same compound nucleus ¹⁰⁵Ag at the same excitation energy and spin distribution. We find anomalously large oxygen yield and entrance channel dependence at high excitation energies from ¹⁶O+⁸⁹Y reaction implying formation of a dinuclear orbiting complex. Possible connection between nuclear orbiting and fast fission is also discussed.     

A Galton–Watson Estimate for Dyson Series

We consider the question of convergence of particular series of integrals, which are labeled by rooted trees. Necessary and sufficient criteria for convergence are obtained, together with an explicit expression for the sum. The technique used is strongly reminiscent of the generating function approach of Galton and Watson to branching processes. The interest in these series derives from the Dyson series expansion for the perturbation of a free quantum dynamics by a local potential: the convergence of the series implies that the perturbed dynamics exists and is unitarily equivalent with the free one.     

Zum biologischen Nachweis von Arsen

Ohne ZusammenfassungVergl. diese Zeitschrift39, 479 und41, 137.     

Analysis of sub-picogram quantities of 238Pu by thermal ionization mass spectrometry

Journal of Radioanalytical and Nuclear Chemistry - A multiple ion-counting total evaporation technique has been developed for precise analysis of sub-picogram (pg) quantities of 238Pu by thermal...