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排序方式: 共有428条查询结果,搜索用时 78 毫秒
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Niels van der Laan Ward Romeijnders Maarten H. van der Vlerk 《Computational Management Science》2018,15(3-4):325-349
We derive bounds on the expectation of a class of periodic functions using the total variations of higher-order derivatives of the underlying probability density function. These bounds are a strict improvement over those of Romeijnders et al. (Math Program 157:3–46, 2016b), and we use them to derive error bounds for convex approximations of simple integer recourse models. In fact, we obtain a hierarchy of error bounds that become tighter if the total variations of additional higher-order derivatives are taken into account. Moreover, each error bound decreases if these total variations become smaller. The improved bounds may be used to derive tighter error bounds for convex approximations of more general recourse models involving integer decision variables. 相似文献
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Simon Smolders Tom Willhammar Andra Krajnc Kadir Sentosun Michael T. Wharmby Kirill A. Lomachenko Sara Bals Gregor Mali Maarten B. J. Roeffaers Dirk E. DeVos Bart Bueken 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(27):9258-9263
While titanium‐based metal–organic frameworks (MOFs) have been widely studied for their (photo)catalytic potential, only a few TiIV MOFs have been reported owing to the high reactivity of the employed titanium precursors. The synthesis of COK‐47 is now presented, the first Ti carboxylate MOF based on sheets of TiIVO6 octahedra, which can be synthesized with a range of different linkers. COK‐47 can be synthesized as an inherently defective nanoparticulate material, rendering it a highly efficient catalyst for the oxidation of thiophenes. Its structure was determined by continuous rotation electron diffraction and studied in depth by X‐ray total scattering, EXAFS, and solid‐state NMR. Furthermore, its photoactivity was investigated by electron paramagnetic resonance and demonstrated by catalytic photodegradation of rhodamine 6G. 相似文献
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We establish a connection between measurement-based quantum computation and the field of mathematical logic. We show that the computational power of an important class of quantum states called graph states, representing resources for measurement-based quantum computation, is reflected in the expressive power of (classical) formal logic languages defined on the underlying mathematical graphs. In particular, we show that for all graph state resources which can yield a computational speed-up with respect to classical computation, the underlying graphs—describing the quantum correlations of the states—are associated with undecidable logic theories. Here undecidability is to be interpreted in a sense similar to Gödel’s incompleteness results, meaning that there exist propositions, expressible in the above classical formal logic, which cannot be proven or disproven. 相似文献
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We investigate the time-dependent Kondo effect in a single-molecule magnet (SMM) strongly coupled to metallic electrodes. Describing the SMM by a Kondo model with large spin S>1/2, we analyze the underscreening of the local moment and the effect of anisotropy terms on the relaxation dynamics of the magnetization. Underscreening by single-channel Kondo processes leads to a logarithmically slow relaxation, while finite uniaxial anisotropy causes a saturation of the SMM's magnetization. Additional transverse anisotropy terms induce quantum spin tunneling and a pseudospin-1/2 Kondo effect sensitive to the spin parity. 相似文献
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van der Heden van Noort GJ Verhagen CP van der Horst MG Overkleeft HS van der Marel GA Filippov DV 《Organic letters》2008,10(20):4461-4464
A one-pot procedure for the preparation of phosphoramidates, phosphorothioates, pyrophosphates, phosphodiesters, and phosphofluoridates has been devised using di(p-methoxybenzyl)-N,N-diisopropylphosphoramidite as the common phosphitylating reagent. 相似文献