Inclusive and exclusive measurements in the projectile breakup of 7Li

The inclusive and exclusive measurements were carried out for ⁷Li projectile breakup on ²⁷Al target at 48 MeV. In the inclusive data we have observed a broad peak around the beam velocity for alphas and tritons. The exclusive data for alpha-triton coincidences show good agreement with the post-form DWBA theory of breakup reactions.     

Effect of alpha-tocopherol on pulmonary antioxidant defence system and lipid peroxidation in cigarette smoke inhaling mice

Background  

Free radicals generated in biological systems by cigarette smoke (CS) inhalation can cause oxidative stress in tissues, resulting in lipid peroxidation (LPO). In view of the antioxidant properties of α-tocopherol (AT), in the present study, effects of AT on antioxidant defence system and LPO were investigated in mice inhaling CS for different time intervals.     

Filament-induced birefringence in Argon

We demonstrate that a driving ultrashort laser pulse undergoing filamentation can induce a remarkably large birefringence in Argon, resulting in an ultrafast “half-wave plate” for a copropagating non-filamenting probe beam. Such femtosecond birefringence, which originates from the difference between the nonlinear refractive indices induced by the filament on the axes parallel and orthogonal to its own polarization, opens the way to potential ultrafast Kerr-gates whose ultimate time-duration is only restricted by the duration of the driving pulse. We also show that the induced birefringence is transversely inhomogeneous, resulting from to the intensity profile of the driving pulse.     

High-pressure synthesis, structural and Raman studies of a two-dimensional polymer crystal of

Two-dimensional polymerisation of a C₆₀ single crystal has been obtained under high-pressure high temperature conditions (700 K - 2 GPa). Crystalline order is preserved but the crystal splits into variants (orientational domains). The analysis of X-ray diffraction and Raman spectroscopy data reveals that the polymer crystal is primarily tetragonal with some admixture of rhombohedral phase. Furthermore, Raman spectroscopy gives evidence for additional C₆₀-C₆₀ dimers, which are probably disordered. For the tetragonal phase, it is shown that successive polymer layers are rotated by about the stacking axis, according to the P4₂/mmc space group symmetry. The structure of the rhombohedral phase is also clarified. The role of the interlayer interactions in stabilising the two-dimensional polymer phases of C₆₀ is discussed. Received 8 October 1999     

Organic-organic epitaxy of incommensurate systems: quaterthiophene on potassium hydrogen phthalate single crystals

Hot-wall epitaxy and molecular-beam epitaxy have been employed for growing quaterthiophene thin films on the (010) cleavage face of potassium hydrogen phthalate, and the results are compared in terms of film properties and growth mode. Even if there is no geometrical match between substrate and overlayer lattices, these films are epitaxially oriented. To investigate the physical rationale for this strong orientation effect, optical microscopy, atomic force microscopy, and X-ray diffraction are employed. A clear correlation between the morphology of the thin films and the crystallographic orientation is found. The results are also validated by surface potential calculations, which demonstrate the primary role played by the corrugation of the substrate surface.     

Facile and selective metalation of 7-dehydro-cholesterol (pro-vitamin D3)

Subsequent treatment of 7-dehydrocholesterol with trimethylsilylmethylpotassium in tetrahydrofuran, dry ice, mineral acid and diazomethane gives a regioisomerically pure, homoconjugated ester as a diastereomeric mixture, the minor component of which turns out to be thermodynamically more stable than a conjugated isomer.