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We present experimental and theoretical work showing that a flat metallic slab can collimate and focus light impinging on the slab from a point source. The effect is optimized when the radiation is around the bulk, not at the surface, plasma frequency. Also, the smaller the imaginary part of the permittivity is, the better the collimation. Experiments for Ag in the visible as well as calculations are presented. We also discuss the interesting case of Al, whose imaginary part of permittivity is very small at the plasma frequency in UV radiation. Generalization to other materials and radiations are also discussed. 相似文献
94.
Morán MC Pinazo A Clapés P Infante MR Pons R 《The journal of physical chemistry. B》2005,109(48):22899-22908
Monoacylglycerol amino acid conjugates constitute a novel class of specific biocompatible surfactants that can be considered analogues to partial glycerides and lysophospholipids. They consist of one aliphatic chain and one polar head, i.e., the amino acid, linked through a glycerol moiety. In a previous work, we synthesized monolauroylated amino acid glyceride conjugates, 1-O-lauroyl-rac-glycero-3-O-(N(alpha)-acetyl-L-amino acid), changing the amino acid headgroup systematically: arginine (compound 2), aspartic acid (compound 3), glutamic acid (compound 4), asparagine (compound 5), glutamine (compound 6), and tyrosine (compound 7), to elucidate the structure-properties relationship governing the occurrence of their polymorphism. The thermotropism of the new compounds was measured with polarizing light microscopy, differential scanning calorimetry, and X-ray diffraction and compared with the classical monoglyceride rac-1-lauroylglycerol (compound 1). The experiments were performed for a sequence of heating, cooling, and reheating scans. The results showed that compounds 1-6 exhibit a thermotropic smectic phase. As a consequence, the substitution of the polar head did not engender any curvature into the system, which might lead to the formation of cubic or columnar phases. Interestingly, liquid crystalline phases were not found in the case of compound 7. Small-angle X-ray diffraction data in the gel phase revealed that the substitution of the polar head by the different amino acid structures did not modify significantly the lamellar repeat distance relative to that of the reference one. The observed area per molecule, however, was larger for the new compounds. Consequently, interdigitation was promoted in compounds 2-7. The diffraction patterns were analyzed in terms of electron density profiles, using a modified Caillé theory plus a Gaussian electron density representation (MCG method) on X-ray diffraction data. 相似文献
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D. Denegri Y. Pons R. Barloutaud A. Borg C. Louedec M. Spiro K. Paler T.P. Shah S.N. Tovey B. Chaurand B. Drevillon G. Labrosse R. Lestienne R.A. Salmeron 《Nuclear Physics B》1975,91(1):54-68
We have studied the reaction K-p → K-π+π-π+π-p at 14.3 GeV/c to search for evidence of the double dissociation process . In the channel π1-π2-Δ++ (1236) there is evidence for simultaneous production of low-mass enhancements in the and Δ++(1236)π2- subsystems which correspond to the and decay modes. In this particular final state the double fragmentation system is produced with a cross section of the order of a few microbarns. Our data are consistent with the factorizable pomeron exchange model of double diffractive dissociation. 相似文献
97.
The differences in color coordinates obtained from the use of different spectral features in the calculation are studied. Seven groups of food (olive oil, vanilla milkshake, brandy, honey, grape juice, vinegar, and orange juice) and an anthocyanin petunidin solution (natural pigment present in several vegetables) with different pH values were selected. Tristimulus values were calculated by considering the different sources of errors (truncation, abridgement, or different bandwidths). Results obtained were corrected by using the methods recommended (see References). These methods of abridgment work well in general, although in some circumstances (20 nm bandwidth or larger), specific spectral weighting functions have to be used to obtain a negligible error. Therefore, it is interesting to know how much difference can be expected from those factors in order to avoid confusion between color differences attributable to instruments and those attributable to actual color changes. 相似文献
98.
Porrès L Mongin O Katan C Charlot M Pons T Mertz J Blanchard-Desce M 《Organic letters》2004,6(1):47-50
[structure: see text] Novel octupolar fluorophores derived from the symmetrical functionalization of a triphenylamine core with strong acceptor peripheral groups via phenylene-ethynylene linkers have been synthesized and shown to exhibit high fluorescence quantum yields, very large TPA cross-sections in the red-NIR region, and suitable photostability. 相似文献
99.
Virtual screening of large libraries of small compounds requires fast and reliable automatic docking methods. In this article we present a parallel implementation of a genetic algorithm (GA) and the implementation of an enhanced genetic algorithm (EGA) with niching that lead to remarkable speedups compared to the original version AutoDock 3.0. The niching concept is introduced naturally by sharing genetic information between evolutions of subpopulations that run independently, each on one CPU. A unique set of additionally introduced search parameters that control this information flow has been obtained for drug‐like molecules based on the detailed study of three test cases of different complexity. The average docking time for one compound is of 8.6 s using eight R10,000 processors running at 200 MHz in an Origin 2000 computer. Different genetic algorithms with and without local search (LS) have been compared on an equal workload basis showing EGA/LS to be superior over all alternatives because it finds lower energy solutions faster and more often, particularly for high dimensionality problems. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 1971–1982, 2001 相似文献
100.