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951.
通过对脉冲耦合神经网络(pulse coupled neural network,PCNN)和拉曼光谱定性分析的研究,提出了基于PCNN的拉曼光谱定性分析方法.首先,利用PCNN神经元的疲劳与不应期特性将拉曼光谱数据进行编码;然后,基于改进的Horspool算法将检测样品对应编码与基码数据库中的所有基码逐一匹配,并得到各对应的匹配相似度,进而判定样品类别.相关实验和数据分析证明了该文方法的准确性和有效性.同时,该文方法避免了目前基于谱模版定性分析方法中待测样品拉曼光谱特征谱峰难以确定以及匹配分析冗余度高等不足,且对存储空间的要求仅为后者的5.8%. 相似文献
952.
近红外、中红外和拉曼光谱法测定商品农药制剂中溴氰菊酯的含量 总被引:1,自引:0,他引:1
利用近红外、中红外和拉曼光谱法定量分析了商品农药制剂中有效成分溴氰菊酯的含量,采用偏最小二乘法(partial least squares,PLS)建立溴氰菊酯的定量模型并进行了优化,用独立检验集对模型适应性进行评价。近红外和中红外法溴氰菊酯定量模型的相关系数和定标标准差分别是0.9999,0.022和0.9996,0.056,两种方法的定量效果接近;拉曼法溴氰菊酯定量模型的相关系数是0.9967,定标标准差是0.172,预测精度不如近红外和中红外高。MIR-ATR,NIR和Raman方法均能满足现场检测农药质量的需要,对生产企业的连续在线检测、监督部门进行农药质量控制和农产品安全具有重要意义。 相似文献
953.
We present a method for numerical wave propagation in a heterogeneous medium. The medium is defined in terms of an extended scatterer or target which is surrounded by many small scatterers. By extending the classic Foldy-Lax formulation we developed an efficient algorithm for numerical wave propagation in two dimension. In the method that we set forth multiple scattering among the point scatterers and the extended target is fully taken into account via a boundary integral formulation coupled with the Foldy-Lax formulation. This formulation forms the basis for our numerical procedure. 相似文献
954.
An axisymmetric-fold-combination (ASFC) cavity composed of two planar mirrors and spherical mirrors was designed. It is a stable-unstable resonator cavity. The light field of radial direction is Gaussian distribution. And in angular orientation, the distribution keeps invariant. It could generate annular CO2 laser beam with excellent spatial coherence. And the spatial coherence is commendably realized with its stable-unstable cavity structure. The output light intensity distribution of this special model was discussed and simulated. With exterior lenses group, the output beams can be adjusted and controlled better to meet the manufactural requirements. Some references were provided for further research of the cavity with cylindrical discharge region. 相似文献
955.
The thermal infrared imaging system is of greatest importance in modern optics and the image quality closely relies on the accuracy of the optical system. Heat-induced mirror deformation influences the transmission performance of the optical antenna system significantly, which further degrades the accuracy of the whole system. In this work, the simulation on lens deformation circumstances under the thermal environment is carried out using the finite-element analysis software ANSYS. The focus shift property caused by the thermal effect is studied in the cases of reflective and refractive Cassegrain optical antennas, and the athermalizing performance of Cassegrain optical antenna system is also concluded. This work presents a direction to accurate designing of the thermal infrared optical system. 相似文献
956.
Yuan Dong Xi-He Zhang Feng-dong Zhang Guo-Bin Ning Guang-yong Jin Wei Liang Yan-Fei Lü Kai Zhang 《Optik》2010,121(19):1781-1783
A new kind of hollow beams - hollow laser beams with three-dimension trap optical distribution - was put forward. With the help of the Collins formula in paraxial optical system, the analytical equation of propagation and transformation of the hollow laser beams was deduced. According to the analytical equation, the propagation properties of the kind of hollow beams that transform in free space were simulated. In the experiment, we obtained the hollow laser beams by means of the combinational optical system of reflecting positive-axis and negative-axis pyramids. The intensity of the vertical loop in different distances was tested, which shows that the analytical equation of propagation and transformation is in agreement with the result. 相似文献
957.
The reflectivity map is theoretically investigated by applying the transfer matrix method in a metal-dielectric mirror structure at normal incidence. The existence of multiple optical Tamm states (OTSs) is demonstrated in this structure. It is found that an OTS is periodic resonance with the variation of the top-layer thickness of the dielectric mirror for a given wavelength. The energy for the corresponding OTS mainly depends on the thickness of the top layer. The appropriate thicknesses of metal film are proposed for the convenient observation of OTSs. This work may be useful in designing a new type of multichannel filter in optical communication systems. 相似文献
958.
Kai Hu 《Journal of Mathematical Analysis and Applications》2018,457(1):890-921
We investigate the Cauchy problems of Euler equations coupled with chemical reaction equation. The specific heat and adiabatic parameters of compressible fluid are introduced as functions with respect to reactant mass fraction in this paper. By means of fractional step wave-front tracking scheme, we derive the existence of global BV solution, and verify that it is indeed an entropy weak solution. This system is also regarded as balance law with resonant characteristic fields. Hence some decay condition is imposed on the source term, in order to handle the damping effect. 相似文献
959.
Kai Gu 《Archiv der Mathematik》2018,111(1):57-60
Let X and Y be metric spaces with X separable, and let \(f: X\rightarrow Y\) be a Borel function. Is then f(X) separable? In this paper, we prove that this problem is independent of ZFC. We also give a partial answer to an open problem which was asked by A. H. Stone. 相似文献
960.
Bence Paul Kai Kysenius James B. Hilton Michael W. M. Jones Robert W. Hutchinson Daniel D. Buchanan Christophe Rosty Fred Fryer Ashley I. Bush Janet M. Hergt Jon D. Woodhead David P. Bishop Philip A. Doble Michelle M. Hill Peter J. Crouch Dominic J. Hare 《Chemical science》2021,12(30):10321
Tumours are abnormal growths of cells that reproduce by redirecting essential nutrients and resources from surrounding tissue. Changes to cell metabolism that trigger the growth of tumours are reflected in subtle differences between the chemical composition of healthy and malignant cells. We used LA-ICP-MS imaging to investigate whether these chemical differences can be used to spatially identify tumours and support detection of primary colorectal tumours in anatomical pathology. First, we generated quantitative LA-ICP-MS images of three colorectal surgical resections with case-matched normal intestinal wall tissue and used this data in a Monte Carlo optimisation experiment to develop an algorithm that can classify pixels as tumour positive or negative. Blinded testing and interrogation of LA-ICP-MS images with micrographs of haematoxylin and eosin stained and Ki67 immunolabelled sections revealed Monte Carlo optimisation accurately identified primary tumour cells, as well as returning false positive pixels in areas of high cell proliferation. We analysed an additional 11 surgical resections of primary colorectal tumours and re-developed our image processing method to include a random forest regression machine learning model to correctly identify heterogenous tumours and exclude false positive pixels in images of non-malignant tissue. Our final model used over 1.6 billion calculations to correctly discern healthy cells from various types and stages of invasive colorectal tumours. The imaging mass spectrometry and data analysis methods described, developed in partnership with clinical cancer researchers, have the potential to further support cancer detection as part of a comprehensive digital pathology approach to cancer care through validation of a new chemical biomarker of tumour cells.Digital pathology and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) imaging reveals a unique elemental signature of colorectal cancer. 相似文献