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91.
We present experimental and theoretical evidence of the role played by the spin–orbit coupling in the electronic structure of a pseudomorphic Au monolayer on Nb(001) substrate. The bands found with the help of the angle‐resolved ultraviolet photoelectron spectroscopy (ARUPS) are compared with those obtained from ab initio self‐consistent calculations by the VASP and WIEN2k codes. The slab calculations are performed including geometric relaxation and using both the generalized‐gradient (GGA) and local‐density (LDA) approximations for the exchange–correlation energy. The dispersions and energy positions of the calculated bands agree with the experimentally determined band structure only if the LDA is used and the spin–orbit coupling is included. Therefore, both the structure relaxation and spin–orbit coupling are essential in understanding the electronic structure of the Au/Nb(001) system.
92.
K. V. Lukyanov E. V. Zemlyanaya V. K. Lukyanov Z. Metawei B. Šloviñski K. M. Hanna 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(3):361-365
Excitation of low-lying nuclear collective states upon scattering of heavy ions with energies of several tens of MeV/nucleon has been studied. The interaction potential leading to excitation is chosen in the form of a derivative of the microscopic (or semimicroscopic) nucleus-nucleus double-folding optical potential. Elastic and inelastic scattering cross sections have been calculated within the high-energy approximation; the inelastic scattering amplitude was obtained in the first order in the deformation parameter. The cross sections are compared with the experimental data on scattering of 17O from a series of nuclei with excitation of the 2+ level. 相似文献
93.
For the fast characteristics of mixtures of Aluminium, Gallium and Indium the fluorimetric evaluation in the form of complexes
with 8-Hydroxyquinoline-5-sulphonic acid is described at selected pH. The highly collinear correlated fluorescent spectra
and their first derivation were evaluated under various experimental conditions with the Multiple Linear Regression (MLR),
Partial Least Squares (PLS) methods and Kalman filtering. When comparing the results, the PLS gives the least relative prediction
errors under optimal conditions, 5.6–15.9% for the concentration range of Al 0.025–0.2 μg cm−3, Ga 0.1–0.8 μg cm−3 and In 0.1–0.8 μg cm−3 in the mixture. 相似文献
94.
S. Capstick A. Švarc L. Tiator J. Gegelia M. M. Giannini E. Santopinto C. Hanhart S. Scherer T. -S. H. Lee T. Sato N. Suzuki 《The European Physical Journal A - Hadrons and Nuclei》2008,35(3):253-266
The physical meaning of bare and dressed scattering matrix singularities has been investigated. Special attention has been
attributed to the role of the well-known invariance of the scattering matrix with respect to the field transformation of the
effective Lagrangian. Examples of evaluating bare and dressed quantities in various models are given. 相似文献
95.
Investigations of the superradiating cascade of sodium vapour 4P-4S-3P
1 = 2.21 µm and
2=1.14 µm) arising on the leading edge of the exciting laser pulse were carried out. The dependences of the actual delay time
D
of the
1 pulse on the population rise time of the laser-excited 4P state were measured and compared with those calculated following the existing theoretical model. The dependence of the actual delay time
D
on the inverse density of excited atoms 1/N* is also presented. Analysis of this dependence revealed the influence of the Doppler dephasing and of the second,
2, transition on the formation of the
1 superradiance. 相似文献
96.
Mittels Aktivierungsanalyse wurde der Gehalt an Arsen, Antimon, Kupfer, Phosphor und Zink in Halbleitersilizium bestimmt. Die Methode besteht aus zwei Schritten: 1. Gruppentrennung durch Anionenaustausch mit einem Gemisch von Salz- und Fluorwasserstoffsäure, 2. Selektive substöchiometrische Extraktion von Arsen und Kupfer mit Diäthyldithiocarbamat, von Antimon mit Cupferron und von Zink mit Dithizon. Phosphor wurde extraktiv als Phosphomolybdat abgetrennt. 相似文献
97.
D. Šokčević Z. Lenac R. Brako M. Šunjić 《Zeitschrift für Physik B Condensed Matter》1977,28(4):273-281
We develop a theory of low energy electron loss spectroscopy of vibrational modes of molecules adsorbed on metal surfaces. Differential and total cross sections are calculated in the Distorted Wave Born Approximation, assuming i) strong elastic scattering on the metal surface, ii) direct electron-molecule interaction via the electric dipole field associated with the molecular vibration. The angular distributions are calculated and discussed for molecules adsorbed at various distances above the metal surface and for several electron energies and impact angles. The influence of electronic screening of dipolar oscillations is discussed and the consequences of the classical induced image dipoles are explored. It is shown that the metal surface selection rule known in IR spectroscopy is only approximately valid in electron scattering. Finally, we give numerical estimates of the inelastic scattering cross sections for the stretching vibrations of CO molecule adsorbed on transition metal surfaces, in reasonable agreement with experiments. 相似文献
98.
The absorption and ESR spectra of multicomponent alumino-phosphate glasses doped with manganese (0·2–20 mol %) has been measured and compared with the absorption spectra of manganous and manganic ions in model solutions. The unirradiated glasses show in ultraviolet region increasing absorption below 200 nm with the shoulder at 235 nm and the absorption bands due to manganous oxygen complexes in octahedral symmetry. They are similar to the absorption bands of Mn2+ in concentrated H3PO4 acid. In irradiated glasses the bands at 200, 235, 275 (only if Mn is present) and a broad band at 540 nm appear. After the annealing at 450 C all radiation-induced bands disappear and the bands at 235 nm is more pronounced. The Mn3+ in H3PO4 solution exhibit the absorption spectrum with a weak band at 530 nm and a very intense band at 270 nm. It is therefore proposed that both the 540 and 275 nm bands in irradiated glasses can be assigned to octahedral oxygen complexes of Mn3+, i.e. to hole centres. The band at 200 nm which is practically independent of the modifiers (Be, Mg, Ca, Sr and Ba) is, therefore, associated with electron centres (electrons trapped in non-bridging oxygen vacancies). It is suggested that the band at 235 nm in irradiated and annealed glasses is associated with irreversible structural changes.The authors wish to express their appreciation to H.Dvoáková for preparing the solutions and E.Linhartová for careful measurements. 相似文献
99.
Z. Šroubek 《Surface science》1974,44(1):47-59
The process by which atoms are ionized as they are sputtered from a metal surface has been analyzed both theoretically and experimentally. In the theoretical part the expressions for ionization coefficient R+ of atoms having the ionization energy much larger than the metal work function have been derived using a molecular orbital method. The effect of the level crossing was estimated in an approximate way. In the experimental part the SIMS experiments on clean Ni and Al surfaces and on Ni surface covered with a submonolayer of adsorbed K, Na and Al are reported. It has been found and it is for the first time reported that the energy distribution of ions sputtered from a submonolayer of adatoms is independent of energy (200–2500 eV) and mass (Ar+ Xe+ of incident ions and depends only upon the adsorption energy of the adatom. The energy distribution of ions sputtered from bulk samples has been found dependent on the primary ion energy. The measurement of the absolute value of R+ has shown that there is a strong correlation between the number of the adatom valence d-electrons and the value of R+, the value of R+ being smaller for atoms with more d-electrons. These experimental data have been compared with the theoretical expressions and the important role of the mechanism which takes into account the bending of the adatom energy level has been assessed. 相似文献
100.
The plastic deformation of Fe-3%Si alloy single crystals made from the melt is studied by the method of etching of dislocations. At a room-temperature and at static stress deformation by slip occurs in the 1/2〈111〉 directions along planes of maximum resolved shear stress. The plastic properties are determined by the motion of screw dislocations which cause the broadening of slip bands. 相似文献