一维自聚焦透镜及其应用

利用平板自聚焦透镜材料进行离子交换,制成一维自聚焦透镜.分析了平板自聚焦透镜的离子交换原理和折射率分布形成过程,测量了不同厚度时,折射率分布常量A的值.介绍了透镜的应用,并用一维自聚焦透镜制成小型半导体激光器耦合器件.     

具有格点各向异性的一维铁磁链中的量子孤子和内禀局域模(英文)

基于Hartree-Fock方法和多标度方法,我们考察了具有格点各向异性的一维铁磁链中的量子孤子和内禀局域模,量子磁振子的波函数由量子包络孤子来描述.在布里渊区边界,量子包络孤子变成了量子内禀局域模,它的量子本征频率在简谐波带的顶部上方,量子磁振子主要集中在中心位置j=j0的附近.     

高超音速推进用吸热型烃类燃烧的热稳定性研究 Ⅱ．添加剂的合成与评价

结合燃料的自氧化机理，指出了抗氧剂，金属减活剂以及清净分散剂三种单元添加剂在燃烧自氧化过程中的抗沉积原理，自行合成了一种新型清净分散剂－聚异丁烯硫磷酸的季戊四醇酯PETPA，对酯化产物用FT－IR和NMR进行了结构分析，给出了合成过程中硫磷化，水解，及本经化阶段的反应历程，考察了三种单元添加剂抗氧剂A，清净分散剂D和金属减活剂M，以及由单元添加剂组成的添加剂包的抗沉积效果，结果表明，抗沉积效果AMD＞MD＞AD＞AM＞D＞M＞A，其中清净分散剂为主要添加剂，三种单元添加剂组成的添加剂包的抗沉积效果最为明显，在RT－3，MCH及THDCPD燃料体系中，沉积量分别减少了87．10％，90．91％和89．12％，PETPA无论是单独还是复合使用其效果均优于聚异丁烯丁二酰亚胺T154。     

ELECTRODEPOSITION OF POLYCRYSTALLINE Cd-RICH Hg_(1-x)Cd_xTe AND PHOTOELECTROCHEMICAL BEHAVIOR OF Hg_(0.09)Cd_(0.91)Te THIN FILM

Electrodeposition process of polycrystalline Cd-rich Hg_(1-z)Cd_xTe (x>0.5) in acidic bath of CdSO_4+HTeO_2~+HgCl_2 was investigated. The simultaneous electrodeposition technique of three kinds of ions at the same potential has been achieved. The XRD, SEM and EDAX analysis of the thin film electrodeposited on titanium substrate showed a typical cubic zinc blende polycrystalline structure and homogeneous dispersion. The photoelectrochemical behavior of (1-x)=0.09 polycrystalline thin film in a polysulfide redox couple solution was examined. Under illumination of 100 mW/cm~2, the short circuit photocurrent I_(sc)=1.88 mA/cm~2, the open circuit photovoltage V_(oc)=0.25 V, the fill factor F·F=0.22. The bandgap E_g measured with photoelectrochemical spectroscopy is 1.26 eV. Flatband potential φ_(tb), Obtained from Mott-Schottky curve is -1.26 Ⅴ (vs. SCE). Therefore, the obtainable maximum open circuit photovoltage could be 0.49 Ⅴ. The Cd-rich Hg_(1-x)Cd_x Te thin film should be a potential photoactive el     

双环戊二烯加氢异构化合成金刚烷

 采用固定床反应器考察了双环戊二烯连续催化加氢合成桥式四氢双环戊二烯反应性能,筛选出具有良好催化性能的23％Ni／γ－Al2O3催化剂．以桥式四氢双环戊二烯为原料,采用不同类型的沸石催化剂研究了金刚烷的合成,并考察了沸石骨架阳离子改性和表面负载过渡金属等对其催化性能的影响．在n（cat）／n（reactant）＝0．25,p（H2）＝1．1MPa,θ＝250℃,t＝3h的条件下,采用三元负载型催化剂0．8％Pt－0．2％Re－3％Co／ReUSY可得到收率为27．7％的金刚烷．     

以睾酮为探针采用高效液相色谱法测定细胞色素CYP450 3A4的酶活性

建立了一种快速、高效的以睾酮作为探针药物评价细胞色素P450 3A4(CYP3A4)酶活性的高效液相色谱-紫外检测方法。采用的色谱柱为Phenomenex C18柱(4.6 mm×150 mm,5 μm),梯度洗脱,流速1.0 mL/min,紫外检测波长245 nm,柱温30 ℃。睾酮与大鼠肝微粒体温孵后,过已活化好的C18固相萃取小柱,收集甲醇洗脱液,于37 ℃水浴中通N2吹干,用50%甲醇复溶后进样分析测定。研究结果表明,6β-羟基睾酮的 保留时间为11.60 min,线性范围为0.5～32 μg/mL,最低检出质量浓度为0.02 μg/mL,提取率为88.41%～92.73%,方法的回收率为99.07%～101.30%;睾酮的保留时间为19.27 min,线性范围为0.5～40 μg/mL,最低检出质量浓度为0.01 μg/mL,提取率为89.59%～92.66%,方法的回收率为96.50%～98.03%。两者的日内、日间相对标准偏差均小于10%,温孵体系中的其他内源性物质不干扰测定。该方法快速、稳定、灵敏度高,适合体外睾酮及其代谢物6β-羟基睾酮的测定,可应用于体外CYP3A4酶活性的评价及酶动力学的研究。     

Quantum Solitary Wave Solutions in a Ferromagnetic Chain with Nearest- and Next-Nearest-Neighbor Interaction

The quantum solitary wave solutions in a one-dimensional ferromagnetic chain is investigated by using the Hartree-Fock approach and the multiple-scale method. It is shown that quantum solitary wave solutions can exist in a ferromagnetic system with nearest- and next-nearest-neighbor exchange interaction, and at the certain value of the first Brillouin zone, the solitary wave solution of the Hartree wave function becomes the intrinsic localized mode.     

关于高等数学中极限思想的研究

本文针对在工科高等数学的教学中 ,学生对极限这一重要概念难以把握和理解的现象 ,提出了分三个层次并从哲学的角度来理解这一思想 ,为学生最终解决这一难点提供了一种有效的方法 .     

利用目标试验因子分析法确定化学反应的级数及速率常数

利用目标试验因子分析(TTFA)结合数值遗传算法(NGA).解析反应过程中在线测得的动力学谱-光谱数据矩阵,可在未知各组分纯光谱及动力学模型情况下同时求解出各组分的纯光谱、反应级数及速率常数。提出用近似计算法计算各组分的动力学谱,使该方法能适用于任意反应级数的体系。针对两步连续反应模型,对反应物、中间体和最终产物均有吸收及某一种组分没有吸收的体系的模拟实验数据矩阵进行了处理,表明该方法均能适用。利用该方法对邻苯二甲酸二甲酯在碱性介质中的水解反应及日落黄水溶液的电解降解反应过程中测得的数据矩阵进行解析,均获得了可靠结果。     

以乙二胺为手臂分子制备的DNA修饰电极及其伏安性能

Carboxyl was formed on the surface of glassy carbon electrode(GCE) by electrochemical oxidation. Ethylenediamine(En) was used as the arm molecule to link carboxyl with dsDNA using 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide hydrochloride (EDC) and N- hydroxysuccinimide (NHS) as the activators to prepare dsDNA modified electrode(dsDNA/En/GCE). It was shown that dsDNA couM be covalently immobilized on the surface of GCE. ssDNA modified electrode(ssDNA/En/GCE) was obtained via the thermal denaturation of dsDNA/En/GCE. The dsDNA/En/GCE and ssDNA/En/GCE were characterized by voltammetry with methylene blue(MB) as the indicator. The results indicated that the currents of the redox peaks of MB at ssDNA/En/GCE were larger than those at dsDNA/En/GCE, and the currents of the redox peaks at En/GCE were the smallest. The peak-currents of MB at the DNA modified electrode had good reproducibility after multi-denaturation and hybridization cycles.