Cr-AlPO4-5的合成及其对苯直接氧化制苯酚反应的催化性能

 以Cr(NO3)3为Cr源用水热法合成了Cr-AlPO4-5分子筛,并用XRD,FT-IR和XPS对分子筛进行了表征. 结果表明,Cr已进入到Cr-AlPO4-5分子筛骨架结构中; 焙烧后分子筛样品的L酸中心和B酸中心数量均大幅度增加,Cr主要以Cr(Ⅴ)形式存在. 将分子筛样品用于催化H2O2氧化苯制苯酚反应,苯酚收率最高可达4.7%,选择性可达99.5%以上. 非骨架Cr物种是导致H2O2无效分解和选择性下降的主要因素,而骨架Cr物种是反应的活性中心. 提出了以骨架Cr过氧化物为中间物种的可能的反应机理,并用原位红外光谱初步验证了中间物种的存在.     

2级VMI集成的Shapley指数收益分配方案

本文在回顾了VMI集成相关文献基础之上,将解决多人合作博弈问题的Shapley值方法用于解决两级VMI联盟的收益分配问题,从而提出了一种各方均可接受且稳定的收益分配方案.在此收益分配方案下,供应链各方均会从VMI集成中得到利润水平上的提升,而且兼顾到了各方公平.     

Entanglement Dynamics of Three Superconducting Charge Qubits Coupled to a Cavity

We investigate the entanglement dynamics of a quantum system consisting of three superconducting charge qubits (SCQs) interacting with a microwave field. For separable and entangled states of the SCQs, the evolutions are studied under various photon numbers of cavity field. The results show that the amplitude and period of the bipartite entanglement square concurrences can be controlled by the choice of initial states of SCQs and photon numberof cavity field, respectively. This simple model of a quantum register allows us to understand the dynamic process of the quantum storage of information carried by charge qubit.     

几种应变检测的光力学测试方法及其比较

应变测量技术在工程应用中有重要意义.一是它可以直接用来获得应力场,可以用来评价材料的安全性和可靠性;二是应变梯度很大的部位往往又是材料破坏的起始点,所以应变测量又可以用于进行材料的无损检测.当前几种光力学方法受到了重视,即云纹干涉法、电子剪切散斑干涉法和数字相关散斑法,对上述方法的原理、光路设计、特点作了介绍,以便这些传统方法的进一步推广,文中还特别介绍了一种作者近来在国内率先开展的微压痕应变花法.这一方法可以方便用于金属等材料上,可以较精确定量研究测试物体的应变而且对刚体位移不敏感,应用起来更加直接和方便,更有推广和应用前景.本文有利于针对研究对象的特点,选用更加合适的应变测量方法.     

Optical absorption in asymmetric double quantum wells driven by two intense terahertz fields

Optical absorption is investigated for asymmetric double quantum wells driven by a resonant terahertz field and a varied terahertz field both polarized along the growth direction. Rich nonlinear dynamics of the replica peak and the Autler-Townes splitting of various dressed states are systematically studied in undoped asymmetric double quantum wells by taking account of multiple factors, such as the frequency of the varied terahertz field and the strength of the resonant terahertz field. Each electron subband splits into two dressed states when the resonant terahertz field is applied in the absence of the varied terahertz field, the optical absorption spectrum shows the first order Autler-Townes splitting of the electron subbands. When a varied terahertz field is added into the resonant system, the replica peak and the second order Autler-Townes splitting of the dressed states near the band edge respectively emerge when the varied terahertz field is non-resonant and resonant with these dressed states. When the strength of the resonant terahertz field is increased, the first order Autler-Townes double peaks and the replica peak in the optical absorption spectrum shift with the shifts of the dressed states. The presented results have potential applications in electro-optical devices.     

Disk-shaped Symmetric Hexa-substituted Triphenylene Derivatives: Synthesis,Physical Properties and Self-assembly

A series of triphenylene derivatives with six symmetric substituents was synthesized from hexabromotriphenylene. The synthesis was conducted by six-fold palladium-catalyzed Hagihara-Sonogashira cross- coupling reactions to yield the hexa-alkynyl substituted triphenylene derivatives of HTP1, HTP2, HTP3 and HTP4. The six symmetric substituents can not only endow the triphenylene the longer π-conjugated range, but also increase the solubility of the compounds. Their photophysical, electrochemical, thermal properties were investigated respectively. With the comparison of their properties, the structure-property relationships were established which demonstrated the influences of different substituents on the electronic nature and the mesomorphic phase of these disk-shaped molecules. In addition, with the scanning electron microscopy(SEM) and polarized optical microscopy(POM) characterization, the self-assembly behaviors of the compounds were also investigated.     

知识共享与间接互惠:基于计算实验方法的研究

团队中,个体知识共享行为的回报往往来自第三方而非受助者,而以直接互惠为视角的知识共享研究却不足以解释此类现象。采用基于计算机仿真实验方法,通过赋予Agent记忆、推理、决策和沟通等能力,研究受表型背叛、组织信任氛围及声誉传播机制影响下,间接互惠机制对团队大范围知识共享行为的维系机理。研究发现,由于辨别者的存在,即使无条件共享者会成为绝对多数,隐藏者并不会大量侵入群体。这意味着间接互惠机制维系了团队大范围知识共享行为。在低的组织信任氛围水平下,辨别者和隐藏者虽然能够共存,团队内的知识共享行为却没有出现。即使只有少数成员能观察到周围同事的知识共享行为,只要声誉信息能够有效传播,间接互惠对广泛知识共享行为的维系作用就能够发挥。     

耐高温氧化锆-刚玉-莫来石复相陶瓷的制备及其抗热震性

以煤系高岭土、α-Al2O3和部分稳定氧化锆(PSZ, 3;molY2O3)为原料,制备了耐高温氧化锆-刚玉-莫来石复相陶瓷.采用XRD、SEM等测试技术对样品的物相组成及显微结构进行了表征,研究了PSZ添加量(分别为5wt;、10wt;、15wt;、20wt;、25wt;、30wt;)对样品物理性能、高温塑性变形及抗热震性的影响.结果表明:由于采用含3;molY2O3的PSZ,Y2O3在高温下起到了烧结助剂的作用,致使样品的烧成温度显著降低;同时随着PSZ添加量的增加,样品的抗折强度增加.经最佳烧成温度烧成的各样品的抗折强度分别达到147.4 MPa、161.3 MPa、205.9 MPa、234.4 MPa、294.0 MPa、385.0 MPa.当PSZ的最佳添加量为10wt;时,样品具有较低的高温塑性变形及良好的抗热震性;当PSZ添加量继续增加,样品在高温易产生液相,抗蠕变及抗热震性降低.SEM显微结构研究表明,随着氧化锆添加量增加,样品结构越致密,增强效果越显著.XRD分析结果表明,复相陶瓷具有良好的耐高温性能,热震前后样品的物相组成不变,均为莫来石、刚玉、m-ZrO2和t-ZrO2.     

低阈值852nm半导体激光器的温度特性

通过金属有机化学气相淀积(MOCVD)和半导体后工艺技术制备了852 nm半导体激光器,它在室温下的阈值电流为57.5 m A,输出的光谱线宽小于1 nm。测试分析了激光器的输出光功率、阈值电流、电压、输出中心波长随温度的变化。测试结果表明,当温度变化范围为293~328 K时,阈值电流的变化速率为0.447m A/K,特征温度T0为142.25 K,输出的光功率变化率为0.63 m W/K。通过计算求得理想因子n为2.11,激光器热阻为77.7 K/W,中心波长漂移速率是0.249 29 nm/K,实验得出的中心波长漂移速率与理论计算结果相符。实验结果表明,该半导体器件在293~303 K的温度范围内,各特性参数能够保持相对良好的状态。器件如果工作在高温环境,需要添加控温设备以保证器件在良好状态下运行。     

基于PSD的微摆镜角度自准直测试系统设计

基于压电陶瓷的微摆镜是一种典型的二维角驱动部件,微摆镜系统的实用化需要进行微角度的测量,以便得到驱动电压与微偏转角之间的对应关系。设计了一种基于位置敏感探测器(PSD)的微摆镜角度测试系统,应用激光自准直原理,采用两次45°折返式结构,缩小了系统的体积并解决了传统折返式系统难以精准搭建的问题;采用多层前馈神经网络法对PSD进行了非线性校正,修正后整个系统的测量精度可达0.5″,测量范围为±400″。符合微摆镜角度测量的要求。