三状态并—串联系统的优化分配方法

在单目标、单约束条件下,建立了三状态并-串联系统的优化模型,采用选取重要部件的方法优化系统可靠度,并相应地给出优化算法,最后通过例子,验证了该算法的有效性.     

凝汽器性能的数值模拟与布管原则

针对目前国内使用最为广泛的300 MW机组凝汽器,采用具有分布阻力和分布质量汇的多孔介质模型,数值研究了菱型、卵型、将军帽型、双峰型等典型布管凝汽器的性能,比较了不同布管形式凝汽器的壳侧压降和抽气量,总结出了凝汽器布管的一些基本原则,如管束外形以窄长锲型或山峰形为好、外围应设置辅助进汽通道、需要设置渐缩型空冷区等。     

Synthesis of N~(11)-anchoring biotinylated artemisinin derivatives and their preliminary biological assessment

Unique endoperoxide moiety of artemisinin and its derivatives has been considered the functionality exhibiting highly potent antimalarial and anticancer activities.To investigate the mechanisms of their biological actions,development of suitable molecular probes including biotinylated derivatives is of extreme significance.The synthesis and preliminary biological assessment of four new biotinylated artemisinin derivatives have been reported in this work.     

生物相容性聚碳酸酯聚氨酯微纤维人工血管的研究

以分子量为2000的聚碳酸酯(PCDL)、1,4-丁二醇(BD)和4,4-二环己基甲烷二异氰酸酯(H12MDI)为原料合成出了一系列聚碳酸酯聚氨酯(PCU)。通过NMR、红外(FT-IR)、拉力实验、差示扫描量热仪(DSC)表征了该聚氨酯的化学结构、机械性能和热性能。在25度时,PCU的杨氏模量随硬段含量增加而略有升高。在有酶催化和没有酶的条件下,考察了材料的降解性能,发现吸水率和重量损失分别低于4%和1%。细胞毒性和血液相容性检测表明材料是生物相容、无毒的。经过喷纺技术制备的人工血管具有微孔结构,初步进行体内植入研究,PCU血管具有超细纤维交联的结构,并提供开放孔。研究结果表明聚碳酸酯聚氨酯具有优异的物理性能、高生物稳定性和良好的生物相容性,因此聚碳酸酯聚氨酯是人工血管合适材料。     

蔬菜重金属污染研究进展与防治措施

通过对国内外蔬菜重金属污染的研究现状、污染来源、蔬菜对重金属的吸收与富集规律、重金属对蔬菜生理生化效应的影响等方面的论述,探讨了蔬菜中重金属污染的控制方法,为开展蔬菜重金属污染防治提供参考和借鉴.     

示波极谱滴定法测定显影液中米吐尔和对苯二酚含量

用１．５ｍｏｌ／Ｌ乙酸铵－氨（ｐＨ８．２）－无水乙醇（２：１，Ｖ／Ｖ）混合溶液为极谱底液，以Ｋ２ＣｒＯ４与米吐尔和对苯二酚的氧化还原反应为基础，用Ｋ２ＣｒＯ４作为滴定剂，以示波极谱图上ＣｒＯ４＾２－切口出现指示终点，测定显影液中米吐尔和对苯二酚的含量。本法简便易行，灵敏准确，终点直观，应用于Ｄ－７２和Ｄ－７６显影液中米吐尔和对苯二酚的测定，获得满意结果。     

Covalent Organic Frameworks with trans-Dimensionally Vinylene-linked π-Conjugated Motifs

Vinylene-linked covalent organic frameworks(COFs) are a class of promising porous organic materials that feature fully π-conjugated structures, high crystallinity, permanent porosity, ultrahigh chemical stability, and extraordinary optoelectronic properties. Over the past 5 years, this kind of material has been witnessed rapid development either in chemical synthesis or in potential applications. In this review, we summarize the chemistry to synthesize vinylene-linked COFs, especially the synthetic strategies involving activation of aryl methyl groups for condensation reaction. We then scrutinize the state-of-the-art development in properties and functions of this kind of COFs. Our own opinions on the further development of the vinylene-linked COFs are also presented for discussion.     

Synergistic Catalysis of Enzymes and Biomimetic MOFs:Immobilizing Cyt c on Two-dimensional MOFs to Enhance the Performance of Peroxidase

Metal-organic frameworks(MOFs) have been widely regarded as promising carriers for enzyme immobilization owing to their advantages in improving loading and regulating interaction with enzymes. However, they are still suffering from the problems of slow mass transfer and compromising activity. In this paper, the active two-dimensional(2D) MOF of Cu-TCPP(Fe)[TCPP=tetrakis(4-carboxy-phenyl)porphyrin], which possesses the biomimetic architecture of peroxidase, was adopted to anchor cytochrome(Cyt c) for the enhancement of catalytic activity. The atomic/nanometer thickness and micrometer lateral dimension of 2D MOFs can ensure the full exposure of immobilized enzymes and a shorter diffusion distance for the reactant molecules. Besides, the active carrier can provide synergistic catalysis and activity compensation during the reaction. When tested in the decomposition reaction of H₂O₂, Cyt c/Cu-TCPP(Fe) exhibited nearly twice catalytic activity and an accelerated catalytic rate compared to free Cyt c.     

GF-1与GF-6 WFV影像在滇池悬浮物浓度反演中的对比分析

总悬浮物(TSM)是水环境评价的重要参数之一,也是遥感水质反演的重要指标。GF-1/WFV和GF-6/WFV作为高分系列对外免费开放的卫星数据,在遥感监测中的应用较为广泛,但目前针对两种数据的对比分析以及GF-6/WFV新增波段在水体水质参数反演中的适用性研究较少。以云南滇池水域为研究区域,对与水体实测数据同步过境(或时相相近)的GF-1/WFV和GF-6/WFV遥感影像采用统计分析的方法进行相同波段(蓝、绿、红、近红外)一致性分析,在此基础上运用经验回归方法分别构建两种数据的TSM反演模型,并将加入GF-6/WFV新增波段的模型与GF-1/WFV构建的模型进行对比分析,选择最优模型应用于滇池2020年的6幅GF-6/WFV图像得到滇池TSM分布图。结果表明：GF-1/WFV与GF-6/WFV的蓝、绿、红、近红外波段的相关系数分别为0.98, 0.98, 0.97和0.99,两种数据的表观反射率具有很高的一致性。GF-1/WFV基于蓝、绿、近红外波段构建的差值模型“B2+B4-B1”反演精度较高,模型反演的均方根误差为6.35 mg·L^-1,平均绝对百分比误差为2...     

基于SiPLS-SPA波长优选的血红蛋白定量分析研究

血红蛋白是人体的一项重要生理指标,浓度异常会导致人体产生各种疾病。红外光谱技术具有简单、无损、快速等优点,非常适合用于生理参数的定量分析。由于光谱背景复杂、有效信息弱,如何提取有效特征变量,构建精准定量模型是个难题。针对此问题,以血液样本和血红蛋白仿体溶液样本光谱数据为研究对象,采用SPXY法、 K＿S法、 duplex法、等间隔划分法四种数据集划分方法划分数据并通过建模对比,优选出最佳数据集划分方法为SPXY法。遍历了SavitzkyGolay一阶求导滤波(S＿G1)+小波变换、小波变换+S＿G1、标准正态变量变换(SNV)+S＿G1三种预处理方法,优选出SNV+S＿G1预处理方法。结合串联思想,提出组合区间偏最小二乘法(SiPLS)与连续投影算法(SPA)串联的特征波长优选方法,构建SiPLS-SPA-PLS预测模型,用两组数据对模型进行验证,依据评价指标判断模型的优劣,并与全谱PLS, SPA-PLS和SiPLS三种定量模型相比较。实验结果表明：(1)使用SiPLS-SPA-PLS模型进行定量分析,血液样本的R_c,R_p, RMSEC和R...