全文获取类型
收费全文 | 430篇 |
免费 | 19篇 |
国内免费 | 6篇 |
专业分类
化学 | 288篇 |
晶体学 | 1篇 |
力学 | 12篇 |
数学 | 54篇 |
物理学 | 100篇 |
出版年
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 14篇 |
2014年 | 11篇 |
2013年 | 31篇 |
2012年 | 25篇 |
2011年 | 35篇 |
2010年 | 17篇 |
2009年 | 15篇 |
2008年 | 26篇 |
2007年 | 19篇 |
2006年 | 13篇 |
2005年 | 23篇 |
2004年 | 14篇 |
2003年 | 15篇 |
2002年 | 9篇 |
2001年 | 5篇 |
2000年 | 9篇 |
1999年 | 15篇 |
1998年 | 11篇 |
1996年 | 8篇 |
1994年 | 5篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 10篇 |
1990年 | 6篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1985年 | 6篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 4篇 |
1959年 | 1篇 |
排序方式: 共有455条查询结果,搜索用时 7 毫秒
181.
182.
Philip E. Sonnet Daniel A. Netzel Robert Mendoza 《Journal of heterocyclic chemistry》1979,16(5):1041-1047
Several octahydroindolizines including the four geometrical isomers of 3-butyl-5-methyloctahydroindolizine, which is an attractant of Pharaoh's and [Monomorium pharaonis(L.)], have been examined by 1H and 13C nmr spectroscopy. The conformations of these compounds are discussed. 相似文献
183.
The effects on the radiation response of Harwell polymethylmethacrylate (PMMA) dosimeters of dose-rate, radiation type, temperature during irradiation and post-irradiation storage, and post-irradiation stability, are of importance to the operators of commercial irradiation facilities.
This paper describes recent studies of the effects of some of these parameters on the radiation response of Harwell Red 4034, Amber 3042, and Gammachrome YR Perspex dosimeters, and provides data on batch to batch variation and shelf-life. 相似文献
184.
Javier de Mendoza Tomás Torres M. Dolores Badía 《Monatshefte für Chemie / Chemical Monthly》1988,119(8-9):1041-1045
Lead tetraacetate oxidation of 4-amino-1,2,4-triazoles, 1-amino- and 2-amino-1,2,3-triazoles affords mainly fragmentation to nitriles or acetylenes, even in the presence of intramolecularly attached double bonds.
Über die Bleitetraacetatoxidation von 4-Amino-1,2,4-triazolen, 1-Amino- und 2-Amino-1,2,3-triazolen (Kurze Mitteilung)
Zusammenfassung Bei der Oxidation von 4-Amino-1,2,4-triazolen, 1-Amino- und 2-Amino-1,2,3-triazolen mit Bleitetraacetat entstanden hauptsächlich Nitrile bzw. Acetylene durch Fragmentierung — trotz der Gegenwart von intramolekularen Doppelbindungen.相似文献
185.
Dye-sensitized solar cells based on nanocrystalline TiO2 films surface treated with Al3+ ions: photovoltage and electron transport studies 总被引:1,自引:0,他引:1
Alarcón H Boschloo G Mendoza P Solis JL Hagfeldt A 《The journal of physical chemistry. B》2005,109(39):18483-18490
Nanocrystalline TiO2 films, surface modified with Al3+, were manufactured by depositing a TiO2 suspension containing small amounts of aluminum nitrate or aluminum chloride onto conducting glass substrates, followed by drying, compression, and finally heating to 530 degrees C. Electrodes prepared with TiO2 nanoparticles coated with less than 0.3 wt % aluminum oxide with respect to TiO2 improved the efficiency of the dye sensitized solar cell. This amount corresponds to less than a monolayer of aluminum oxide. Thus, the Al ions terminate the TiO2 surface rather than form a distinct aluminum oxide layer. The aluminum ion surface treatment affects the solar cell in different ways: the potential of the conduction band is shifted, the electron lifetime is increased, and the electron transport is slower when aluminum ions are present between interconnected TiO2 particles. 相似文献
186.
Rodas Mendoza B Morera Pons S Castellote Bargalló AI López-Sabater MC 《Journal of chromatography. A》2003,1018(2):197-202
A rapid, sensitive method has been developed for the simultaneous determination of retinol acetate, delta-, gamma-, alpha-tocopherol and alpha-tocopherol acetate. We compare two experimental procedures for simultaneous direct solvent extraction of these vitamins without previous saponification. Method I: the fat milk sample was extracted with ethanol-hexane and injected directly into the chromatographic column. Method II: the power milk sample was extracted with ethanol-hexane and also injected directly into the column. Under optimum conditions the limits of detection for retinol acetate, delta-, gamma-, alpha-tocopherol and alpha-tocopherol acetate were 0.33, 21.2, 32.9, 32.5 and 3.2 ng and the limits of quantification were 0.42, 25.3, 37.9, 36.8 and 6.3 ng, respectively. The precision results showed that the relative standard deviations of repeatability and reproducibility were between 0.74 and 5.7%. 相似文献
187.
Fernández-Carneado J Van Gool M Martos V Castel S Prados P de Mendoza J Giralt E 《Journal of the American Chemical Society》2005,127(3):869-874
Oligoguanidinium-based cell delivery systems have gained broad interest in the drug delivery field since one decade ago. Thus, arginine-containing peptides as Tat or Antp, oligoarginine peptides, and derived peptoids have been described as shuttles for delivering nonpermeant drugs inside cancer cells. Herein we report a new family of tetraguanidinium cell penetrating vectors efficiently internalized in human tumor cells. Their high internalization, studied by confocal microscopy and flow cytometry, as well as their specific accumulation in mitochondria makes these new vectors likely vehicles for the targeted delivery of anticancer drugs to mitochondria. 相似文献
188.
Avila Rodríguez M Barrón Zambrano JA Alatorre Ordaz A Navarro Mendoza R Saucedo Medina TI 《Talanta》1998,45(5):875-882
Liquid-liquid extraction of Co(II) and Zn(II) by methylisobutylcetone (MIBK) has been studied systematically from NH(4)SCN/H(2)SO(4) media. The influence of sulphuric acid concentration on the percentage of extraction of Co(II) and Zn(II) has been discussed. It is shown that sulphuric acid concentration has not the same effect on distribution curves of Co(II) and Zn(II). Thus, it is possible to have a separation of Zn(II) of Co(II) when [NH(4)SCN] is 0.5 mol l(-1) and [H(2)SO(4)] is about 2 mol l(-1). Under these conditions the separation factor (S(Zn/Co)) is around 580. The results are treated in terms of thermodynamic activities in aqueous phase, to determine the composition of the extracted complexes (M:SCN(-)) and to discuss the extraction mechanism. 相似文献
189.
J. Melo Quintero K. L. Salcedo Rodríguez G. A. Pasquevich P. Mendoza Zélis S. J. Stewart C. E. Rodríguez Torres L. A. Errico 《Hyperfine Interactions》2016,237(1):63
We present a combined Mössbauer and ab initio study on the influence of oxygen-vacancies on the hyperfine and magnetic properties of the ZnFe 2 O 4 spinel ferrite. Samples with different degree of oxygen-vacancies were obtained from zinc ferrite powder that was thermally treated at different temperatures up to 650 °C under vacuum.Theoretical calculations of the hyperfine parameters, magnetic moments and magnetic alignment have been carried out considering different defects such as oxygen vacancies and cation inversion. We show how theoretical and experimental approaches are complementary to characterize the local structure around Fe atoms and interpret the observed changes in the hyperfine parameters as the level of defects increases. 相似文献
190.