Migration of Bosonic particles across a Mott insulator to a superfluid phase interface

We consider a boundary between a Mott insulator and a superfluid region of a Bose-Hubbard model at unit filling. Initially both regions are decoupled and cooled to their respective ground states. We show that, after switching on a small tunneling rate between both regions, all particles of the Mott region migrate to the superfluid area. This migration takes place whenever the difference between the chemical potentials of both regions is less than the maximal energy of any eigenmode of the superfluid. We verify our results numerically with density matrix renormalization group simulations and explain them analytically with a master equation approximation, finding good agreement between both approaches. Finally we carry out a feasibility study for the observation of the effect in coupled arrays of microcavities and optical lattices.     

Efficient Suzuki-Miyaura coupling of (hetero)aryl chlorides with thiophene- and furanboronic acids in aqueous n-butanol

An efficient Suzuki cross-coupling protocol enables the reaction of N-hetero and normal aryl chlorides with thiophene- and furanboronic acids. Coupling is effected in aqueous n-butanol as the solvent in near quantitative yield with a catalyst loading of 0.1-1 mol %. For heterocyclic substrates aqueous catalysis is found to be more efficient than Suzuki coupling under anhydrous conditions. The developed Suzuki coupling procedure utilizes biodegradable solvents and is useful for large scale reactions, as it includes the facile product separation from a biphasic solvent mixture without the need for additional organic solvents during workup.     

9-fluorenylphosphines for the Pd-catalyzed sonogashira, suzuki, and Buchwald-Hartwig coupling reactions in organic solvents and water

The lithiation/alkylation of fluorene leads to various 9-alkyl-fluorenes (alkyl=Me, Et, iPr, -Pr, -C18H25) in>95% yields, for which lithiation and reaction with R2PCl (R=Cy, iPr, tBu) generates 9-alkyl, 9-PR2-fluorenes which constitute electron-rich and bulky phosphine ligands. The in-situ-formed palladium-phosphine complexes ([Na2PdCl4], phosphonium salt, base, substrates) were tested in the Sonogashira, Suzuki, and Buchwald-Hartwig reactions of aryl chlorides and aryl bromides in organic solvents. The Sonogashira coupling of aryl chlorides at 100-120 degrees C leads to>90% yields with 1 mol% of Pd catalyst. The Suzuki coupling of aryl chlorides typically requires 0.05 mol% of Pd catalyst at 100 degrees C in dioxane for quantitative product formation. To carry out "green" cross-coupling reactions in water, 9-ethylfluorenyldicyclohexylphosphine was reacted in sulphuric acid to generate the respective 2-sulfonated phosphonium salt. The Suzuki coupling of activated aryl chlorides by using this water-soluble catalyst requires only 0.01 mol% of Pd catalyst, while a wide range of aryl chlorides can be quantitatively converted into the respective coupling products by using 0.1-0.5 mol% of catalyst in pure water at 100 degrees C. Difficult substrate combinations, such as naphthylboronic acid or 3-pyridylboronic acid and aryl chlorides are coupled at 100 degrees C by using 0.1-0.5 mol% of catalyst in pure water to obtain the respective N-heterocycles in quantitative yields. The copper-free aqueous Sonogashira coupling of aryl bromides generates the respective tolane derivatives in>95% yield.     

CONTROLLING THE 3D NANOSCALE ORGANIZATION OF BULK HETEROJUNCTION POLYMER SOLAR CELLS

In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After annealing treatment,either at elevated temperature or during slow solvent evaporation,nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer.Such a tailored morphology acco...     

Diamond Quantum Devices in Biology

The currently available techniques for molecular imaging capable of reaching atomic resolution are limited to low temperatures, vacuum conditions, or large amounts of sample. Quantum sensors based on the spin‐dependent photoluminescence of nitrogen‐vacancy (NV) centers in diamond offer great potential to achieve single‐molecule detection with atomic resolution under ambient conditions. Diamond nanoparticles could also be prepared with implanted NV centers, thereby generating unique nanosensors that are able to traffic into living biological systems. Therefore, this technique might provide unprecedented access and insight into the structure and function of individual biomolecules under physiological conditions as well as observation of biological processes down to the quantum level with atomic resolution. The theory of diamond quantum sensors and the current developments from their preparation to sensing techniques have been critically discussed in this Minireview.     

Generation of mesoscopic entangled states in a cavity coupled to an atomic ensemble

We propose a novel scheme for the efficient production of entangled states for N photons of the form |N>(a)|0>(b) + |0>(a)|N>(b) (NOON states) based on the resonant interaction of a pair of quantized cavity modes with an ensemble of atoms. We show that, in the strong-coupling regime, the adiabatic evolution of the system tends to a limiting state that describes mesoscopic entanglement between photons and atoms which can easily be converted to a purely photonic or atomic NOON state. We also demonstrate the remarkable property that the efficiency of this scheme increases exponentially with the cavity cooperativity factor, which gives efficient access to high number NOON states. The experimental feasibility of the scheme is discussed, and its efficiency is demonstrated numerically.     

Pulsed laser cooling for cavity optomechanical resonators

A pulsed cooling scheme for optomechanical systems is presented that is capable of cooling at much faster rates, shorter overall cooling times, and for a wider set of experimental scenarios than is possible by conventional methods. The proposed scheme can be implemented for both strongly and weakly coupled optomechanical systems in both weakly and highly dissipative cavities. We study analytically its underlying working mechanism, which is based on interferometric control of optomechanical interactions, and we demonstrate its efficiency with pulse sequences that are obtained by using methods from optimal control. The short time in which our scheme approaches the optomechanical ground state allows for a significant relaxation of current experimental constraints. Finally, the framework presented here can be used to create a rich variety of optomechanical interactions and hence offers a novel, readily available toolbox for fast optomechanical quantum control.     

Non-Markovianity-assisted steady state entanglement

We analyze the steady state entanglement generated in a coherently coupled dimer system subject to dephasing noise as a function of the degree of Markovianity of the evolution. By keeping fixed the effective noise strength while varying the memory time of the environment, we demonstrate that non-Markovianity is an essential, quantifiable resource that may support the formation of steady state entanglement whereas purely Markovian dynamics governed by Lindblad master equations lead to separable steady states. This result illustrates possible mechanisms leading to long-lived entanglement in purely decohering, possibly local, environments. We present a feasible experimental demonstration of this noise assisted phenomenon using a system of trapped ions.     

Dark periods in the resonance fluorescence of a single Λ system

We use the quantum jump method to study the photon statistics of a single laser-driven atom in the configuration where both lower levels are strongly coupled to the common upper level. Under certain conditions we show that, for almost degenerate lower levels, light and dark periods occur which are similar to those of the well-known Dehmelt V system. Analytic results for their mean lengths and other statistical properties are given. For large separation of the lower levels we prove an interesting bunching property by the photons in the resonance fluorescence near the dark resonance. We propose a realistic system for which these effects may be observed.