Molecular and impedance spectroscopy of Na 2 Mo 2 O 7 ceramics

The fine (i.e. 38 nm) powder of polycrystalline Na₂Mo₂O₇ was prepared by the high-temperature solid-state reaction technique. The formation of the compound in orthorhombic system is confirmed by preliminary structural analysis using X-ray diffraction (XRD) data. Spectroscopic studies of the compound have been carried out by vibration spectroscopy (Raman/FTIR) to understand its molecular structure at microscopic level. The complex impedance spectroscopy (CIS) technique has been used to study the electrical properties of the material as a function of frequency (10²–10⁶ Hz) at different temperatures (23–450^°C), and also to investigate the fundamental mechanism involved in the material. Impedance analysis also indicates that below 300^°C, the electrical conduction in the material is due to grain interior only. At and above 325^°C, the contribution of grain boundary is clearly evident. The electrical processes in the material are found to be temperature-dependent and are due to the relaxation phenomena in it. A frequency-dependent maximum of the imaginary electrical impedance is found to obey the Vogel–Fulcher law.     

METAL-COPOLYMER COMPLEXES OF N-ISOPROPYLACRYLAMIDE FOR AFFINITY PRECIPITATION OF PROTEINS

ABSTRACT

Copolymers of N-isopropylacrylamide (NIPAM) with styrene derivative of iminodiacetic acid (st-IDA) and 1-vinylimidazole (VI) were synthesized by radical copolymerization and metal complexation characteristics of the copolymers were investigated. The theromoprecipitation property of the copolymers indicate the application of Cu(II) loaded copolymer of poly(VI/NIPAM) as a potential carrier for the metal chelate affinity precipitation of proteins. The studies carried out on the purification of protein inhibitors from different cereals, suggest the specific interaction of metal ions bound on the copolymer and the histidine residues on the surface of the target protein. The recovered copolymers could be reloaded with metal ions and can be reused number of times with high efficiency.     

Measuring the ‘complexity’ of sound

Sounds in the natural environment form an important class of biologically relevant non-stationary signals. We propose a dynamic spectral measure to characterize the spectral dynamics of such non-stationary sound signals and classify them based on rate of change of spectral dynamics. We categorize sounds with slowly varying spectral dynamics as simple and those with rapidly changing spectral dynamics as complex. We propose rate of spectral dynamics as a possible scheme to categorize sounds in the environment.     

A near-infrared zero-order achromatic retarder

Phase retarders normally show strong wavelength dependence. Achromatic retarders which exhibit nearly identical characteristics over a wide wavelength spectrum is used in polychromatic light. The present investigation deals with a technique to design and study the characteristics of an achromatic combination of birefringent plates in 800–2000 nm range. The retarder has been designed using calcite, crystalline quartz and ADP. The thicknesses of the plates are 19.38 μm, 446.14 μm and 12.57 μm respectively. The new arrangement of three birefringent plates proposed has the promise of producing a zero-order quarter wave achromatic combination with fairly good accuracy.     

Influence of near-edge processes in the elemental analysis using X-ray emission-based techniques

The near-edge processes, such as X-ray absorption fine structure (XAFS) and resonant Raman scattering (RRS), are not incorporated in the available theoretical attenuation coefficients, which are known to be reliable at energies away from the shell/subshell ionization thresholds of the attenuator element. Theoretical coefficients are generally used to estimate matrix corrections in routine quantitative elemental analysis based on various X-ray emission techniques. A tabulation of characteristic X-ray energies across the periodic table is provided where those X-rays are expected to alter the attenuation coefficients due to XAFS from a particular shell/subshell of the attenuator element. The influence of XAFS to the attenuation coefficient depends upon the atomic environment and the photoelectron wave vector, i.e., difference in energies of incident X-ray and the shell/subshell ionization threshold of the attenuator element. Further, the XAFS at a shell/subshell will significantly alter the total attenuation coefficient if the jump ratio at that shell/subshell is large, e.g., the K shell, L₃ subshell and M₅ subshell. The tabulations can be considered as guidelines so as to know what can be expected due to XAFS in typical photon-induced X-ray emission spectrometry.     

水介质中药物-AOT混合物的温度依赖的混合胶束化行为(英文)

The mixed micellization behavior of an amphiphilic antidepressant drug amitriptyline hydrochloride(AMT)in the presence of the conventional anionic surfactant sodium bis(2-ethylhexyl)sulfosuccinate(AOT)was studied at five different temperatures and compositions by the conductometric technique.The critical micelle concentration(cmc)and critical micelle concentration at the ideal state(cmcid)values show mixed micelle formation between the components(i.e.,drug and AOT).The micellar mole fractions of the AOT(X1)values calculated using the Rubingh,Motomura,and Rodenas models show a higher contribution of AOT in the mixed micelles.The interaction parameter(β)is negative at all temperatures and the compositions show attractive interactions between the components.The activity coefficients(f1and f2)calculated using the different proposed models are always less than unity indicating non-ideality in the systems.TheΔGmΘ values were found to be negative for all the binary mixed systems.However,ΔHmΘ values for the pure drug as well as the drug-AOT mixed systems are negative at lower temperatures(293.15-303.15 K)and positive at higher temperatures(308.15 K and above).TheΔSmΘ values are positive at all temperatures but their magnitude was higher at T=308.15 K and above.The excess free energy of mixing(ΔGex)determined using the different proposed models also explains the stability of the mixed micelles compared to the pure drug(AMT)and surfactant micelles.     

FLEXURAL INTENSITY MEASUREMENT ON FINITE PLATES USING MODAL SPECTRUM IDEAL FILTERING

Flexural intensities on various plate-like structures with arbitrary boundary conditions are calculated using measured and FEM yielded mobility. In doing so, a two-dimensional spatial Fourier transform has been implemented along with a refined k-spectral filtering concept. Intensity is decomposed into individual contributions from bending moments, twisting moments and shear forces. The source and energy sink localization and energy flow have been analyzed through these contributions. The effect of reflections from the plate edges and that of the uncorrelated noise, on the intensity, are discussed. It is shown that the width of the k -filters may have a non-negligible influence on the shape of the intensity field. Damping in the structure can efficiently control the edge reflections and therefore help to localize the energy sources and sinks. A link has been found, at certain excitation conditions, between the radiated acoustic intensity and the active flexural intensity. It is also observed that the classical method of studying the vibration transmission, using vibration amplitude measurements, does not reflect the transmitted vibration energy but rather provides information on non-propagating, reactive energy. The FEM study, further explains some of the experimental observations and suggests the possibility of applying intensity to complex analytical models.     

Nonlinear interaction of ultraintense laser pulse with relativistic thin plasma foil in the radiation pressure-dominant regime

We present a study of the effect of laser pulse temporal profile on the energy /momentum acquired by the ions as a result of the ultraintense laser pulse focussed on a thin plasma layer in the radiation pressure-dominant (RPD) regime. In the RPD regime, the plasma foil is pushed by ultraintense laser pulse when the radiation cannot propagate through the foil, while the electron and ion layers move together. The nonlinear character of laser–matter interaction is exhibited in the relativistic frequency shift, and also change in the wave amplitude as the EM wave gets reflected by the relativistically moving thin dense plasma layer. Relativistic effects in a high-energy plasma provide matching conditions that make it possible to exchange very effectively ordered kinetic energy and momentum between the EM fields and the plasma. When matter moves at relativistic velocities, the efficiency of the energy transfer from the radiation to thin plasma foil is more than 30% and in ultrarelativistic case it approaches one. The momentum /energy transfer to the ions is found to depend on the temporal profile of the laser pulse. Our numerical results show that for the same laser and plasma parameters, a Lorentzian pulse can accelerate ions upto 0.2 GeV within 10 fs which is 1.5 times larger than that a Gaussian pulse can.     

Two-texture zeros and near-maximal atmospheric neutrino mixing angle

We study the implications of a large value of the effective Majorana neutrino mass for a class of two-texture zero neutrino mass matrices in the flavour basis. We find that these textures predict near-maximal atmospheric neutrino mixing angle in the limit of large effective Majorana neutrino mass. We present the symmetry realization of these textures using the discrete cyclic group Z₃. It is found that the texture zeros realized in this work remain stable under the renormalization group running of the effective neutrino mass matrix at one-loop level.     

Signature splitting in two quasiparticle rotational bands of <Superscript>180,182</Superscript>Ta

The signature splittings in K^π = 1 ⁺: 7 /2[404] _π?9 /2[624] _ν, K^π = 0^?: 9 /2[514] _π?9 /2[624] _ν bands of ¹⁸⁰Ta and K^π = 0^?: 7 /2[404] _π?7 /2[503] _ν, K^π = 1^?: 5 /2[402] _π?3 /2[512] _ν, K^π = 1⁺: 7 /2[404] _π?9 /2[624] _ν bands of ¹⁸²Ta are analysed within the framework of two-quasiparticle rotor model. The phase as well as magnitude of the experimentally observed signature splitting in K^π = 1⁺ band of ¹⁸⁰Ta, which could not be explained in earlier calculations, is successfully reproduced. The conflict regarding placement of a 12 ⁺ level in K^π = 1 ⁺: 7 /2 ⁺[404] _π?9 /2 ⁺[624] _ν ground-state rotational band of ¹⁸⁰Ta is resolved and tentative nature of K^π = 0^?: 7 /2[404] _π?7 /2[503] _ν, K^π = 1⁺: 7 /2[404] _π?9 /2[624] _ν bands observed in ¹⁸²Ta is confirmed. As a future prediction for experimentalists, these two-quasiparticle structures observed in ¹⁸⁰Ta and ¹⁸²Ta are extended to higher spins.