全文获取类型
收费全文 | 9561篇 |
免费 | 1986篇 |
国内免费 | 3433篇 |
专业分类
化学 | 6590篇 |
晶体学 | 434篇 |
力学 | 657篇 |
综合类 | 347篇 |
数学 | 1532篇 |
物理学 | 5420篇 |
出版年
2024年 | 23篇 |
2023年 | 84篇 |
2022年 | 366篇 |
2021年 | 329篇 |
2020年 | 367篇 |
2019年 | 309篇 |
2018年 | 383篇 |
2017年 | 497篇 |
2016年 | 365篇 |
2015年 | 469篇 |
2014年 | 642篇 |
2013年 | 835篇 |
2012年 | 751篇 |
2011年 | 864篇 |
2010年 | 837篇 |
2009年 | 902篇 |
2008年 | 984篇 |
2007年 | 842篇 |
2006年 | 845篇 |
2005年 | 659篇 |
2004年 | 523篇 |
2003年 | 433篇 |
2002年 | 419篇 |
2001年 | 405篇 |
2000年 | 484篇 |
1999年 | 262篇 |
1998年 | 130篇 |
1997年 | 104篇 |
1996年 | 126篇 |
1995年 | 72篇 |
1994年 | 104篇 |
1993年 | 82篇 |
1992年 | 76篇 |
1991年 | 59篇 |
1990年 | 53篇 |
1989年 | 46篇 |
1988年 | 45篇 |
1987年 | 27篇 |
1986年 | 28篇 |
1985年 | 21篇 |
1984年 | 24篇 |
1983年 | 20篇 |
1982年 | 17篇 |
1981年 | 19篇 |
1980年 | 12篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1975年 | 3篇 |
1964年 | 3篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Cheng Lu ZHANG Xiao Lei ZHU Ying Ge MA Li Wei ZOU 《中国化学快报》2006,17(2):163-164
12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb… 相似文献
92.
93.
Design of Two-Dimensional Photonic Crystal Edge Emitting Laser for Photonic Integrated Circuits
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
An edge emitting laser based on two-dimensional photonic crystal slabs is proposed. The device consists of a square lattice microcavity, which is composed of two structures with the same period but different radius of air-holes, and a waveguide. In the cavity, laser resonance in the inner structure benefits from not only the anomalous dispersion characteristic of the first band-edge at the M point in the first Brillouin-zone but also zero photon states in the outer structure. A line defect waveguide is introduced in the outer structure for extracting photons from the inner cavity. Three-dimensional finite-difference time-domain simulations apparently show the in-plane laser output from the waveguide. The microcavity has an effective mode volume of about 3.2(λ/nslab)^3 for oscillation mode and the quality factor of the device including line defect waveguide is estimated to be as high as 1300. 相似文献
94.
ZHANG Jing wen * ZHAO Jian zhang ZHANG Xiao long JIANG Yu lin MA Xiu li SUN Yun xiu JIANG Wen pu LI Yao xian XU Zhi luo 《高等学校化学研究》1998,(2)
ChemoselectiveCatalyticHydrogenationofα,β┐UnsaturatedKetonesandα,β┐UnsaturatedCarboxylicEstersZHANGJing-wen*,ZHAOJian-zhang,Z... 相似文献
95.
5-甲基吡咯-2-羧酸酯在磺酰氢,溴或四乙酸铅作用下,生成相应的在5-甲基上含取代基的产物,后者不经分离不便可自缩合得标题化合物,核磁共振氢谱研究和分子构象木匠,当3,3位的取代基为甲酸(酯)基或乙酸(酯)基时,可形成3,3位酯基与另一吡咯环上的氮氢之间的分子内氢键,而3,3位是其它取代基,如乙酰基,丙酸(酯)基,丁酸(酯)基时不能形成类似的分子内氢键。 相似文献
96.
97.
98.
Polyethylene terephthalate(PET)/polycaprolactone(PCL) segmented copolymers with different hard segment contents and a blend of two of them were studied by using DSC, WAXS, TEM and IR techniques and dynamic mechanical, stress-strain and isothermal crystallization measurements. Emphasis was laid on the studies of influence of compositional heterogeneity on the morphology and properties of these segmented copolymers. It was found that the solution cast specimens of the more heterogeneous sample exhibit better segregation of segments, high crystallinity and melting temperature. They have higher thermal stability of mechanical properties at small deformations. However, they are less stable against large deformations and may become softer than the more homogeneous ones. 相似文献
99.
合成了6种钨硅杂多配合物异构体α、βi-M3H2[SiW11(NbO2)O39]·H2O(M=Me4N+(TMA),Bu4N+(TBA),Et4N+(TEA);βi=β1,β2,β3)。IR光谱、UV光谱、极谱、I--S2O32-滴定证明合成的杂多配合物中有NbO2基存在, 183W NMR光谱证明其阴离子具有Keggin结构,催化实验结果表明,合成的化合物对烯烃环氧化反应具有催化活性,且过氧杂多配合物的催化活性高于非过氧杂多配合物,β异构体的催化活性高于α。 相似文献
100.
ZHANG Wei-wei CHEN Yu-chun LUO Zhao-feng WANG Ju-ying MA De-yi 《高等学校化学研究》2007,23(4):404-407
In this study, surface plasmon resonance (SPR) for monitoring 17β-eatradiol (E2) was developed. The small molecule E2 was immobilized on a CM5 sensor chip for an indirect competitive immunoassay to detect E2. The SPR response bahed on the antigen-antibody reaction was measured by injecting the sample solution into the flow system. The limitation of detection was 0.445 μg/L. The developed SPE-SPR system was applied to analyze the seawater samples. Recovery of E2 was 91.6%-93. 1%. Relative standard deviations(RSD) for the E2 assay were between 10.9%-15.1% (n = 3). The range of determination of E2 samples from the sewage in the coastal marine environ-ment was between ND(lower than detection limit) and ca. 11.78 ng/L. 相似文献