Evaluation of atomic fluorescence, absorption and emission techniques for the determination of mercury

Summary Atomic fluorescence (AFS), absorption (AAS) and emission (AES) systems were evaluated for the determination of inorganic mercury. Identical vapour generation and amalgamation procedures were used to permit direct comparison of the performance of a commercial long-path AAS instrument to laboratory constructed non-dispersive AFS as well as He-MIP based AES instruments. Instrumental noise-limited detection limits (LOD) were 0.94, 2.4, 2.8 pg for AAS, AES and AFS techniques, respectively. Methodological LOD's were found to be blank controlled and similar for all three instruments, viz. 9, 25 and 16 pg for AAS, AFS and AES, respectively. All three systems produced accurate results at the low ng/l concentration, as verified by the analysis of a certified river water reference material (NRCC ORMS-1).     

Axial Structure of the Field Intensity in Diffusion-Controlled Surface-Wave Produced Plasmas

Surface-wave gas discharges sustained under the conditions of a diffusion controlled regime are studied on the basis of the fluid plasma model. The self-consistent behaviour of the plasma density and of the field intensity along the discharge length is obtained. It is shown that the nonlinearity in the particle balance equation due to stepwise ionisation determines the plasma density in terms of the field intensity and ensures self-consistent behaviour of the wave ? discharge characteristics in a diffusion controlled regime.     

Dynamic programming in sport: a survey of applications

This paper surveys applications of dynamic programming to decisionproblems faced by active participants in sports.     

Bifurcations in the growth process of a vortex sheet in rotating superfluid

Vortex-sheet growth is considered. Broken symmetry bifurcations are found in the growth process. The collective elasticity theory for a well-developed vortex sheet is presented, which is similar to that of smectic liquid crystals. The bifurcations in the limit of a much folded vortex sheet correspond to the Helfrich instability in smectics and cholesterics.     

Measurement of Hartmann-Hahn cross-polarization dynamics with quenching of proton T1ρ relaxation dependence

A simple modification of the standard cross-polarization method designed for quenching the proton T_1ρ dependence when studying polarization transfer is presented. It is demonstrated that by using this simple procedure, new and subtle details of cross-polarization dynamics, previously hidden by the T_1ρ(¹H) effect, can be observed in dipolar-coupled spin systems.     

Future contributions toJournal of Crystallographic and Spectroscopic Research

Future contributions toJournal of Crystallographic and Spectroscopic Research     

Lie symmetries and exact solutions of nonlinear equations of heat conductivity with convection term

The Lie symmetries of nonlinear diffusion equations with convection term are completely described. The Lie ansatzes and exact solutions of a certain nonlinear generalization of the Murray equation are constructed. An example of the family of non-Lie solutions of the Murray equation is given.