Determination of residual monomers in acrylate dispersions by gas chromatography

The content of residual monomers is one of the most important characteristics of polymer dispersions. As a result of the similar physicochemical parameters of ethyl acrylate and methyl methacrylate, it is very difficult to determine the residual monomers in acrylate dispersions obtained by emulsion polymerization of both monomers. Gas chromatography with capillary columns, however, permits separation of these monomers and their quantitative determination in acrylate dispersions.     

A grid‐free upwind relaxation scheme for inviscid compressible flows

A new grid‐free upwind relaxation scheme for simulating inviscid compressible flows is presented in this paper. The non‐linear conservation equations are converted to linear convection equations with non‐linear source terms by using a relaxation system and its interpretation as a discrete Boltzmann equation. A splitting method is used to separate the convection and relaxation parts. Least squares upwinding is used for discretizing the convection equations, thus developing a grid‐free scheme which can operate on any arbitrary distribution of points. The scheme is grid free in the sense that it works on any arbitrary distribution of points and it does not require any topological information like elements, faces, edges, etc. This method is tested on some standard test cases. To explore the power of the grid‐free scheme, solution‐based adaptation of points is done and the results are presented, which demonstrate the efficiency of the new grid‐free scheme. Copyright © 2005 John Wiley & Sons, Ltd.     

The Convergence and Stability of Splitting Finite-Difference Schemes for Nonlinear Evolutionary Equations

We consider a splitting finite-difference scheme for an initial-boundary value problem for a two-dimensional nonlinear evolutionary equation. The problem is split into nonlinear and linear parts. The linear part is also split into locally one-dimensional equations. We prove the convergence and stability of the scheme in L ₂ and C norms. Printed in Lietuvos Matematikos Rinkinys, Vol. 45, No. 3, pp. 413–434, July–September, 2005.     

The linear polarization constant of R n

Summary He present work deals with estimations of the n-th linear polarization constant c(H)_n of an n-dimensional real Hilbert space H. We provide some new lower bounds on the value of sup_║y║=1 │1,y> ... n,y>│, where x₁, ... ,x_n are unit vectors in H. In particular, the results improve an earlier estimate of Marcus. However, the intriguing conjecture c(H) _n= n^n/2 remains open.     

In-plane loading of a cracked elastic solid by a disc inclusion with a Mindlin-type constraint

The paper examines the problem related to the axisymmetric interaction between an external circular crack and a centrally placed penny-shaped rigid inclusion located in the plane of the crack. The interface between the inclusion and the elastic medium exhibits a Mindlin-type imperfect bi-lateral contact. Analytical results presented in the paper illustrate the manner in which the lateral translational stiffness of the inclusion and the stress intensity factor at the boundary of the external circular crack are influenced by the inclusion/crack radii ratio.     

ΓD‐convergence for a class of quasilinear elliptic equations in thin structures

We study the asymptotic behaviour of the solution of a stationary quasilinear elliptic problem posed in a domain Ω^(ε) of asymptotically degenerating measure, i.e. meas Ω^(ε) → 0 as ε → 0, where ε is the parameter that characterizes the scale of the microstructure. We obtain the convergence of the solution and the homogenized model of the problem is constructed using the notion of convergence in domains of degenerating measure. Proofs are given using the method of local characteristics of the medium Ω^(ε) associated with our problem in a variational form. Copyright © 2005 John Wiley & Sons, Ltd.