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121.
Zhen CHEN* Ren Yun WANG Li Lian ZHU Xiao Tian LIANG Institute of Materia Medica Peking Union Medical College The Chinese Academy of Medical Sciences Beijing 《中国化学快报》2001,(4)
When isolating 1,4-dideoxy-1,4-imino-D-arabinitol using Dowex 1(2 (OH- form) or CM-Sephadex C-25 (NH4+ form), we found another compound always accompanied with it. It was apparent that the two compounds had similar structures from their 1HNMR and 13CNMR in D2O (Fig. 1). At first, we guessed the two compounds were isomerides. But when acid was added into the solution of the two compounds, the signals for the minor compound disappeared.Figure 1 13CNMR of 1,4-dideoxy-1,4-imino-D-arabin… 相似文献
122.
LI Jing SHANG Yan-mei XIAO Chuan SONG Zhi-guang LI Ye-zhi HUANG Hua-min .College of Chemistry Jilin University .School of Public Health Changchun P.R.China .Key Laboratory for Supramolecular Structure Materials of Ministry of Education Changchun 《高等学校化学研究》2009,25(1)
(R)-4-Hydroxymethyl-2-thioxo thiazolidine as a new chiral catalyst in the asymmetric addition of diethyl-zinc to benzaldehyde was synthesized from (R)-4-hydroxymethyl-2-thioxo thiazolidine carboxylic acid and its crystal structure was determined by X-ray diffraction method. The compound was crystallized in the orthorhombic system, space group P212121 with unit cell dimensions a=0.67253(12) nm; b=0.89164(17) rim; c=1.06146(19) nm, volume 0.6365(2) nm3; Z=4, calculated denisity 1.557 Mg/m3; absorption coefficient 0.733 mm-1; F(000)=312. The X-ray crystal structure analysis reveals that the compound has a thione group. 相似文献
123.
Jian Ping LI* Qian Fu LUO Yi Yang SHEN Yu Lu WANG Hong WANG College of Chemistry Environmental Science Henan Normal University Xinxiang Department of Chemistry Luoyang Teacher''''s College Luoyang 《中国化学快报》2001,(2)
The subject of organic solid-state synthesis is a fascinating one. It has many advantages such as high efficiency and selectivity, easy separation and purification, mild reaction conditions, and environmental acceptability1. In recent years, this method has been widely used in a variety of organic reactions including substitution2, condensation3, oxidation-reduction4, rearrangement5 and elimination6. However, the solid state reaction using K3Fe(CN)6/KOH to oxidize substituted semicarbazides… 相似文献
124.
Xue Sen FAN Yan Zhen LI Xin Ying ZHANG Xue Yuan HU Jian Ji WANG School of Chemical Environmental Sciences Henan Key Laboratory for Environmental Pollution Control Henan Normal University Xinxiang 《中国化学快报》2005,(7)
Room temperature ionic liquids with low melting point (<100℃) salts represent a new class of non-molecular, ionic solvents. Especially those based on the 1-N-alkyl-3- methylimidazolium cations, have shown great promise as an attractive alternative to conventional solvents for catalytic reactions1. On the other hand, FeCl3·6H2O was considered to be an environmentally benign Lewis acid and has been used successfully in several kinds of organic reactions2. Recently we have focused our interes… 相似文献
125.
XU GaoChao LIU RuiQuan & WANG Jin College of Chemistry Chemical Engineering Xinjiang University Urumqi China 《中国科学B辑(英文版)》2009,(8)
Samaria-doped ceria Ce0.8Sm0.2O2-δ(SDC) and SmFe0.7Cu0.3-xNixO3 have been synthesized by the sol-gel method and characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM) and scanning electron microscopy(SEM).The electrochemical synthesis of ammonia was investigated at atmospheric pressure and low temperature,using the SFCN materials as the cathode,a Nafion membrane as the electrolyte,nickel-doped SDC(Ni-SDC) as the anode and silver-platinum paste as the current collector.Ammonia was synt... 相似文献
126.
OBUL Abdukadir College of Mathematics System Sciences Xinjiang University Urumqi China PANG YaLi 《中国科学A辑(英文版)》2008,(6)
By using Frobenius maps and F-stable representations,we count the number of isomor- phism classes of indecomposable representations with the fixed dimension vector of a species of type _n over a finite field,first,and then,as an application,give a q-analogue of the Weyl-Kac denominator identity of type _n. 相似文献
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129.
A convenient route for the synthesis of 3,4-dihydrocoumarin derivates from salicylaldehyde derivates and 1,3-dicarbonyl compounds under solvent-free microwave irradiation conditions was described. In this way, a range of compounds was obtained in moderate to good yields in a short reaction time. 相似文献
130.
<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods. 相似文献