Enhancement of thermal stability and photoluminescent performance of blue light emitting material by incorporating adamantane moieties into carbazole system

A facile route to improve photoluminescent performance and service lifetime of a promising blue light emitting material is reported and demonstrated here using a copolymer system of N-(2-ethylhexyl)-2,7-carbazole (Cz) and 1,3,5,7-tetrakis- (4-bromophenyl) adamantane (TBA). The copolymers were successfully synthesized by palladium-catalyzed Suzuki coupling reactions. Structure and molecular weight of the materials were characterized by FT-IR and ¹H-NMR spectroscopies, elemental analysis and gel permeation chromatography. The influence of adamantane content on the thermal stability and photoluminescent performance of the synthesized copolymers was investigated in detail. DSC results showed that glass transition temperature increased dramatically, from 68°C for neat carbazole, to 88°C, 120°C and 152°C, after the addition of 10%, 20%, and 30% TBA, respectively. The same trend was found when thermal decomposition temperature at 5% weight loss was evaluated from TGA data. Importantly, this increased stability can be extended to thermo-optical performance, with the Cz-TBA system showing higher color purity and stronger emission intensity within blue light wavelength than carbazole alone. Nevertheless, measurements of emitting spectral stability at a broader temperature range (100–200°C) and photoluminescence quantum yield suggested that there is a delicate trade-off between the performance and adamantane content.     

Variational study of vacuum structure with fermions ind+1 dimensional Hamiltonian lattice gauge theory

The physical vacuum state and general expression for the Hamiltonian ofd+1 dimensional lattice gauge theory are given by incorporating the exact ground state of pure gauge theory and the variational fermion vacuum state. The applications toSU(2) andSU(3) gauge theories in 2+1 and 3+1 dimensions are demonstrated and the fermion condensates \(\left\langle {\bar \psi \psi } \right\rangle \) as functions of 1/g ² are calculated.     

LB薄膜中四新戊氧基酞菁锌和四壬基酞菁铜分子聚集体的吸收光谱的温度特性

本文制备了四新戊氧基酞菁锌(Tetra-neopentoxy phthalocyanine zine)(TNPPeZn)和四壬基酞菁铜(Tetra-nonyl phthalocyanine copper)(TNPeCu)两种酞菁衍生物的Langmuir-Blodgett(LB)薄膜.通过测量10～473K温度下的吸收光谱,研究了两种薄膜的分子聚集状态.TNPPeZn的LB薄膜中,存在着分子单体和分子二聚体,在吸收光谱中分别表现为680nm和620nm的吸收峰.随着温度的升高,分子单体逐渐转变为分子二聚体,这个过程是不可逆的.TNPeCu的LB薄膜中,除了分子单体和分子二聚体以外,还有吸收为740nm的分子J聚集体存在.随着温度的变化,J聚集体发生可逆变化.     

Curie温度附近稀磁半导体(Ga,Mn)As的电学噪声谱性质

建立了自发噪声谱测量系统来研究稀磁半导体（Ga,Mn）As的电学噪声性质.通过测量（Ga,Mn）As材料的自发噪声谱,发现（Ga,Mn）As的自发涨落会随温度升高而逐渐增大,同时,外加磁场会降低（Ga,Mn）As的自发涨落,这来源于外加磁场导致的（Ga,Mn）As磁畴部分有序化.此外,不同频率的噪声随温度的变化规律有很大差异：当频率低于30 kHz的时候,噪声谱和温度的变化关系和热噪声很相似,但数值上明显大于热噪声的值;当频率在30 kHz左右的时候,噪声大小和温度成线性关系;当频率大于30 kHz以后,在相变点附近噪声大小和温度的关系出现了明显的转折,高频高温噪声的大小和热噪声的理论值非常接近.这些结果有助于深入理解（Ga,Mn）As磁性起源的物理机制. 关键词： 自旋电子学 稀磁半导体 自发涨落谱     

Gamma Vibrational Bands and Chiral Doublet Bands in A≈100 Neutron-rich Nuclei

The level structures of neutron-rich ~(105)Mo,~(106)Mo,~(108)Mo and 110Ru nuclei in A≈100 region have been carefully investigated by coincidence measurements of the prompt γ-rays populated in the spontaneous fission of ~(252)Cf with the Gammasphere detector array.In 105Mo,one-phonon K =9/2 and two-phonon K=13/2 γ-vibrational bands have been identified.In ~(108)Mo,one-phonon γ-vibrational band is expanded and two-phonon γ-vibrational band has been identified.Two similar sets of bands in ~(106)Mo and ~(110)Ru are observed to high spins,which have been proposed as the soft chiral γ-vibrational bands.The characteristics for these γ-vibrational bands and chiral doublet bands have been discussed.     

一类Marcinkiewicz积分交换子的端点估计

本文得到Ω满足Dini型条件时,Marcinkiewicz积分交换子μΩ,b(f)的端点估计:|{x∈R~n:μΩ,b(f)(x)＞λ}|≤c‖b‖BMO∫_(R~n)(|f(x)|)/λ(1+log+(|f(x)|)/λ)dx．     

Chetaev型约束力学系统Appell方程的Lie对称性与守恒量

研究Chetaev型约束力学系统Appell方程的Lie对称性和Lie对称性直接导致的守恒量.分析Lagrange函数和A函数的关系;讨论Chetaev型约束力学系统Appell方程的Lie对称性导致的守恒量的一般研究方法;在群的无限小变换下,给出Appell方程Lie对称性的定义和判据;得到Lie对称性的结构方程以及Lie对称性直接导致的守恒量的表达式.举例说明结果的应用. 关键词： Appell方程 Chetaev 型约束力学系统 Lie对称性 守恒量     

The queueing model for quantum key distribution network

This paper develops a QKD (quantum key distribution)-based queueing model to investigate the data delay on QKD link and network, especially that based on trusted relays. It shows the mean packet delay performance of the QKD system. Furthermore, it proposes a key buffering policy which could effectively improve the delay performance in practice. The results will be helpful for quality of service in practical QKD systems.     

The characteristics of O＋HD （v = 0, j = 0） reaction dynamics

The analytical potential energy function of HDO is constructed at first using the many-body expansion method.The reaction dynamics of O+HD(v = 0,j = 0) in five product channels are all studied by quasi-classical trajectory(QCT) method.The results show that the long-lived complex compound HDO is the dominant product at low collision energy.With increasing collision energy,O+HD → OH+D and O+HD → OD+H exchange reactions will occur with remarkable characteristics,such as near threshold energies,different reaction probabilities,and different reaction cross sections,implying the isotopic effect between H and D.With further increasing collision energy(e.g.,up to 502.08 kJ/mol),O+HD → O+H+D will occur and induce the complete dissociation into single O,H,and D atoms.