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971.
A route to the total synthesis of koumine has been suggested. Five 4-substituted 1, 2-d hydropyridine derivatives, which are supposed to be a conjugated diene of Diels-Alder reaction to produce the isoquinuclidine ring of koumine, have been synthesized. Only two of them were found to be able to undergo the Diels-Alder reaction. The stereochemistry of the reaction product has also been examined. 相似文献
972.
G. L. Litvinov 《Journal of Mathematical Sciences》1987,38(2):1734-1761
973.
The effect of crack tip sharpness on crack propagation in vulcanized rubbers has been studied. For very sharp cracks, tearing is found to occur on a small scale at very low energies not far above the threshold required for the onset of mechanical crack growth. The “small-scale” tearing energies show relatively little variation for rubbers that differ widely in tear strength as normally measured. Thus the latter property appears to be strongly influenced by variations in the ability of rubbers to promote tip blunting. The small-scale tear behavior is of relevance to other fracture phenomena, including cutting by sharp objects and tensile failure. Natural variations in tip sharpness occur during cyclic or time-dependent mechanical crack growth and influence the form of the crack growth characteristics. 相似文献
974.
A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented.
Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems
of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions,
acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled
reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic
transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated
in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise
concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described. 相似文献
975.
J. Mass M. Avella J. Jimnez M. Callahan E. Grant K. Rakes D. Bliss B. Wang 《Superlattices and Microstructures》2007,42(1-6):306
Understanding the luminescence of ZnO is very important for some applications. In spite of the many studies carried out, there are still some points concerning the origin of some of the luminescence emissions in ZnO crystals that require additional study; in particular, the role of extended defects remains to be a matter of controversy. We present here a cathodoluminescence analysis of the defects generated by Vickers indentation in hydrothermal HTT crystals. Special emphasis was paid to the luminescence band peaking around 3.3 eV. The origin of this band is a matter of controversy, since it has been related to different causes, extended defects being one of the candidates for this emission. The CL images were acquired around crystal defects. It is observed that the 3.3 eV emission is enhanced around the crystal defects; though it is also observed, but weaker, out of the defect regions, which suggests that there exist two luminescence emissions peaking very close to 3.3 eV. The two emissions, one related to structural defects and the other to the LO phonon replica of the free excitonic band, appear very close each other and their relative intensity should determine the shape of the spectrum. 相似文献
976.
X.C. Li J. Wu K. Xu A.Q. Liu J.T. Lin 《Applied Physics A: Materials Science & Processing》2007,89(2):327-332
This paper presents the theoretical model and the optimization method to suppress the sidelobes of side-coupled photonic crystal
filters. Numerical verification shows a good agreement between the theoretical method and the finite-difference time-domain
simulation, but the theoretic method does not involve the time-consuming computation. The theoretical method also presents
a better physical image for choosing the critical parameters, such as the quality factor, phase shift and the number of resonators.
Based on the theoretical model, two optimization methods (chirp and cascading) are proposed to deeply suppress the sidelobes.
They also show more flexibility in controlling the bandwidth and steepness of the roll-off in the filter.
PACS 42.70.Qs 相似文献
977.
Using the concept of a twisted trace density on a cyclic groupoid, a trace is constructed on a formal deformation quantization of a symplectic orbifold. An algebraic index theorem for orbifolds follows as a consequence of a local Riemann-Roch theorem for such densities. In the case of a reduced orbifold, this proves a conjecture by Fedosov, Schulze, and Tarkhanov. Finally, it is shown how the Kawasaki index theorem for elliptic operators on orbifolds follows from this algebraic index theorem. 相似文献
978.
This article concerns the question, Which subsets of ?m can be represented with linear matrix inequalities (LMIs)? This gives some perspective on the scope and limitations of one of the most powerful techniques commonly used in control theory. Also, before having much hope of representing engineering problems as LMIs by automatic methods, one needs a good idea of which problems can and cannot be represented by LMIs. Little is currently known about such problems. In this article we give a necessary condition that we call “rigid convexity,” which must hold for a set ?? ? ?m in order for ?? to have an LMI representation. Rigid convexity is proved to be necessary and sufficient when m = 2. This settles a question formally stated by Pablo Parrilo and Berndt Sturmfels in [15]. As shown by Lewis, Parillo, and Ramana [11], our main result also establishes (in the case of three variables) a 1958 conjecture by Peter Lax on hyperbolic polynomials. © 2006 Wiley Periodicals, Inc. 相似文献
979.
The behaviour of the amplitude-frequency characteristics of families of periodic solutions, produced from the equilibrium position of a system, is established by a qualitative investigation of the equation of the oscillations of a pendulum, the length of which is an arbitrary periodic function of time. The non-local conditions for their stability and instability, expressed in terms of the amplitude and frequency of the oscillations, are obtained. The results are used when discussing the parametric and self-excited oscillatory model of a swing. In the parametric model the length of a swing is a specified periodic function of time, and in the self-excited oscillatory model it is a function of the phase coordinates of the system. For an appropriate choice of these functions, both systems have a common periodic solution. It is shown that the parametric model leads to an erroneous conclusion regarding the instability of the periodic mode, which is in fact realized in the oscillations of a swing, whereas the self-excited oscillatory model indicates its stability. 相似文献
980.
J. -R. Chazottes P. Collet C. Külske F. Redig 《Probability Theory and Related Fields》2007,137(1-2):201-225
We present a new and simple approach to concentration inequalities in the context of dependent random processes and random
fields. Our method is based on coupling and does not use information inequalities. In case one has a uniform control on the
coupling, one obtains exponential concentration inequalities. If such a uniform control is no more possible, then one obtains
polynomial or stretched-exponential concentration inequalities. Our abstract results apply to Gibbs random fields, both at
high and low temperatures and in particular to the low-temperature Ising model which is a concrete example of non-uniformity
of the coupling.
相似文献