Nanoscale chemical analysis of beam-sensitive polymeric materials by cryogenic electron microscopy

Nanoscale chemical analysis of functional polymer systems by electron microscopy, to gain access into degradation processes during the materials life cycle, is still a formidable challenge due to their beam sensitivity. Here a systematic study on the different stages of degradation in a P3HT-PCBM organic photovoltaic (OPV) model system is presented. To this end pristine samples, samples with (reversibly) physisorbed oxygen and water and samples with (irreversibly) chemisorbed oxygen and water are imaged utilizing the full capabilities of cryogenic STEM-EELS. It is found that oxygen and water are largely physisorbed in this system leading to significant effects on the band structure, especially for PCBM. Quantification proves that degradation concomitantly decreases the amount of CC bonds and increases the amount of C O C bonds in the sample. Finally, it is shown that with a pulsed electron beam utilizing a microwave cavity, beam damage can be significantly reduced which likely extends the possibilities for such studies in future.     

Linewidth of collimated wavelength-converted emission in Rb vapour

We present a study of the spectral linewidth of collimated blue light (CBL) that results from wave mixing of low-power continuous-wave laser radiation at 780 and 776 nm and an internally generated mid-IR field at 5.23 μm in Rb vapour. Using a high-finesse Fabry–Perot interferometer, the spectral width of the CBL is found to be <1.3 MHz for a wide range of experimental conditions. We demonstrate using frequency-modulated laser light that the CBL linewidth is mainly limited by the temporal coherence of the applied laser fields rather than the atom–light interaction itself. The obtained result allows the same 1.3 MHz upper limit to be set for the linewidth of the collimated mid-IR radiation at 5.23 μm, which has not been directly detected.     

VUV spectroscopy of magnetically trapped atomic hydrogen

We discuss the experimental and theoretical aspects of absorption spectroscopy of cold atomic hydrogen gas in a magnetostatic trap using a pulsed narrow-band source (bandwidth 100 MHz) at the Lyman- wavelength (121.6 nm). A careful analysis of the measured absorption spectra enables us to determine non-destructively the temperature and the density of the trapped gas. The development of this diagnostic technique is important for future attempts to reach Bose-Einstein condensation in trapped atomic hydrogen.     

Electromagnetically induced transparency in Rb-filled coated hollow-core photonic crystal fiber

We report the observation of lambda-configuration electromagnetically induced transparency as well as optical pumping in rubidium-filled kagome-structure hollow-coated-core photonic crystal fiber. We show that a polydimethylsiloxane coating of the fiber core reduces the linewidth of the transparency below that which could be expected for an uncoated fiber. The measured 6 MHz linewidth was dominated by optical broadening.     

High-performance iodine fiber frequency standard

We have constructed a compact and robust optical frequency standard based around iodine vapor loaded into the core of a hollow-core photonic crystal fiber (HC-PCF). A 532 nm laser was frequency locked to one hyperfine component of the R(56) 32-0 (127)I(2) transition using modulation transfer spectroscopy. The stabilized laser demonstrated a frequency stability of 2.3×10(-12) at 1 s, almost an order of magnitude better than previously reported for a laser stabilized to a gas-filled HC-PCF. This limit is set by the shot noise in the detection system. We present a discussion of the current limitations to the performance and a route to improve the performance by more than an order of magnitude.     

Ultracold electron source

We propose a technique for producing electron bunches that has the potential for advancing the state-of-the-art in brightness of pulsed electron sources by orders of magnitude. In addition, this method leads to femtosecond bunch lengths without the use of ultrafast lasers or magnetic compression. The electron source we propose is an ultracold plasma with electron temperatures down to 10 K, which can be fashioned from a cloud of laser-cooled atoms by photoionization just above threshold. Here we present results of simulations in a realistic setting, showing that an ultracold plasma has an enormous potential as a bright electron source.     

Laser control of electron matter waves

In recent years laser light has been used to control the motion of electron waves. Electrons can now be diffracted by standing waves of light. Laser light in the vicinity of nanostructures is used to affect free electrons, for example, femto‐second and atto‐second laser‐induced electrons are emitted from nanotips delivering coherent fast electron sources. Optical control of dispersion of the emitted electron waves, and optically controlled femto‐second switches for ultrafast electron detection are proposed. The first steps towards electron accelerators and matter optics on‐a‐chip are now being taken. New research fields are driven by these new technologies. One example is the optical generation of electron pulses on‐demand and quantum degenerate pulses. Another is the emerging development of interaction free electron microscopy. This review will focus on the field of free electron quantum optics with technologies at the interplay of lasers, electron matter waves, and nanostructures. Questions that motivate their development will also be addressed.

     

Interferometric selection of frequency comb modes

We demonstrate a scheme to split an optical frequency comb into four separate frequency combs, each with four times the repetition rate of the original, but which are offset in frequency from each other. These spectrally rarified “daughter” combs are generated using fibre interferometers that are actively stabilised. We describe how these “daughter” combs can be used to resolve ambiguities that occur when comparing an arbitrary frequency continuous-wave signal against an optical frequency comb.