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51.
Mercey G Verdelet T Saint-André G Gillon E Wagner A Baati R Jean L Nachon F Renard PY 《Chemical communications (Cambridge, England)》2011,47(18):5295-5297
Nerve agents are highly toxic organophosphorus compounds with strong inhibition potency against acetylcholinesterase (AChE). Herein, we describe two first extremely promising uncharged reactivators for poisoned human AChE with a superior or similar in vitro ability to reactivate the enzyme as compared to that of HI-6, obidoxime, TMB-4 and HL?-7. 相似文献
52.
Morón V Gamallo P Martin-Gondre L Crespos C Larregaray P Sayós R 《Physical chemistry chemical physics : PCCP》2011,13(39):17494-17504
A microkinetic model is developed to study the reactivity of an O/O(2) gas mixture over a β-cristobalite (001) surface. The thermal rate constants for the relevant elementary processes are either inferred from quasiclassical trajectory calculations or using some statistical approaches, resting on a recently developed interpolated multidimensional potential energy surface based on density functional theory. The kinetic model predicts a large molecular coverage at temperatures lower than 1000 K, in contrary to a large atomic coverage at higher temperatures. The computed atomic oxygen recombination coefficient, mainly involving atomic adsorption and Eley-Rideal recombination, is small and increases with temperature in the 700-1700 K range (0.01 < γ(O) < 0.02) in good agreement with experiments. In the same temperature range, the estimated chemical energy accommodation coefficient, the main contribution to which is the atomic adsorption process is almost constant and differs from unity (0.75 < β(O) < 0.80). 相似文献
53.
Benoit Enaux Victor Granet Olivier Vermorel Corine Lacour Ludovic Thobois Vincent Dugué Thierry Poinsot 《Flow, Turbulence and Combustion》2011,86(2):153-177
This paper describes a compressible Large Eddy Simulation (LES) used to investigate cyclic variations for nonreacting flow
in an optical single cylinder engine setup. The simulated operating point is part of a large experimental database designed
to validate LES for cycle-to-cycle prediction, and constitutes a first step towards the realization of fired operating points.
The computational domain covers almost the whole experimental setup (intake and exhaust plenums, intake and exhaust ducts,
cylinder) to account for acoustic phenomena. The assessment of the computation is performed in two regions of the domain:
the intake and exhaust duct predictions are compared to the results of a Helmholtz solver and the experiment (pressure transducers
and Particle Image Velocimetry (PIV)) while the in-cylinder dynamics are compared to PIV measurements. The ability of the
developed methodology to capture the correct level of cycle-to-cycle variations is demonstrated considering in-cylinder pressure
and velocity fields predictions. Cycle-to-cycle variations in velocity are highlighted and localized using a proper orthogonal
decomposition analysis. 相似文献
54.
55.
Bigeon Jean Le Digabel Sébastien Salomon Ludovic 《Computational Optimization and Applications》2021,79(2):301-338
Computational Optimization and Applications - The context of this research is multiobjective optimization where conflicting objectives are present. In this work, these objectives are only available... 相似文献
56.
Ludovic Rifford 《Journal of Differential Equations》2006,226(2):429-500
Given an affine control system in R3 subject to the Hörmander's condition at the origin, we prove the existence of a local smooth repulsive stabilizing feedback at the origin. Our construction is based on the classical homogenization procedure, on the existence of a semiconcave control-Lyapunov function, and on the classification of singularities of semiconcave functions in dimension two. 相似文献
57.
Chromatographic resolution of four flavanones is achieved by reversed-phase high-performance liquid chromatography (HPLC) on a chiral stationary phase based on silica coated with a (2-hydroxy-3-methacryloyloxypropyl beta-cyclodextrin-co-N-vinylpyrrolidone) copolymer. The influence of the mobile phase water content and the nature of the organic modifier on the retention and resolution is evaluated. Monosubstituted flavanones are better resolved than the unsubstituted one. Nevertheless, the 6- and 7-methoxy substituents enhance retention and chiral recognition to polymeric beta-cyclodextrin stationary phase less than the 6-hydroxy group. 相似文献
58.
We study three same-spin-state fermions of mass M interacting with a distinguishable particle of mass m in the unitary limit where the interaction has a zero range and an infinite s-wave scattering length. We predict an interval of mass ratio 13.384相似文献
59.
Guo-Ping Bei Antoine Guitton Véronique Brunet Sylvain Dubois Ludovic Thilly 《哲学杂志》2013,93(15):1784-1801
Ti4AlN3, Ti3AlC2 and Ti3Al0.8Sn0.2C2 MAX phases were plastically deformed at room temperature (RT) under gaseous confining pressure. Microstructures of as-grown and deformed samples are carefully analysed using scanning electron microscopy (SEM), atomic force microscopy (AFM) and transmission electron microscopy (TEM). It is demonstrated that high level of plastic deformation can be reached under confining gas pressure; the later suppresses the brittle failure at RT to the profit of plasticity. Multiscale characterization techniques are shown to provide a unique insight into all the scales of the plastic deformation; in particular, the effect of the mesoscale. Indeed, grain shape and orientation relative to the compression axis are shown to play a key role in the deformation process, intergranular stresses leading to a complex stress field in the polycrystalline samples. The TEM results show that dislocation activity highly depends on the grain orientation. The observation of dislocation entanglements unambiguously demonstrates that dislocations may be organized in such a configuration so that their glide in the basal plane can be hindered when deep plastic regime is reached. 相似文献
60.