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91.
If Exc is the set of all excessive measures associated with a submarkovian resolvent on a Lusin measurable space and B is a balayage on Exc then we show that for any mExc there exists a basic set A (determined up to a m-polar set) such that B=(BA)* for any Exc, m. The m-quasi-Lindelöf property (for the fine topology) holds iff for any B there exists the smallest basic set A as above. We characterize the case when any B is representable i.e. there exists a basic set such that B=(BA)* on Exc. 相似文献
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We first summarize some results recently published by the authors on the application of classical robust servomechanism problem (RSP) to electrohydraulic servos. We present a solution consisting of three compensators: an integrator of the tracking error, a LQR stabilizing compensator and an antiwindup compensator. In this work we extend the analysis of the proposed solution by investigating the stability of the closed loop system with saturated control. We present here an approach to this problem based on the Lyapunov function method. The domain of attraction of the origin is obtained and it is shown that the system stability is ensured by simply choosing a particular compensator design which solves RSP. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
95.
[2,2-dimethyl-4-(t-butyldimethylsiloxy)-3,4-dihydro-2H-pyran-6-yl] methanal (1) was synthesized from commercially available butopyronoxyl (2). The selectivity of reducing agents such as DIBAL-H and LiAlH4 towards butopyronoxyl was studied. Solvent effects were found to influence 1,2 versus 1,4 reduction. 相似文献
96.
Lucian Coroianu 《Numerical Functional Analysis & Optimization》2013,34(7):713-727
In this article, we investigate the local approximation and shape preserving properties in subintervals for the Meyer-König and Zeller max-product operators. The results obtained put in evidence that in the class of strictly positive continuous functions, the local properties of the nonlinear Meyer-König and Zeller max-product operators are much stronger and more general than those in the case of their linear counterparts. 相似文献
97.
Marcela Stoia Oana ?tef?nescu Gabriela Vlase Lucian Barbu-Tudoran Mirela Barbu Mircea ?tef?nescu 《Journal of Sol-Gel Science and Technology》2012,62(1):31-40
This paper presents a study regarding the formation of hybrid gels starting from tetraethyl orthosilicate (TEOS), polyvinyl
alcohol (PVA) and 1,3-propanediol (PD) and their thermal evolution to mesoporous silica matrices. The possibility of obtaining
homogenously dispersed cobalt ferrite inside the silica matrix starting from (TEOS–PVA–PD–Metal Nitrates) gels was also studied.
The formation of the hybrid gels TEOS/PVA/PD with different compositions was studied by FT-IR spectrometry and thermal analysis,
in order to evidence the interaction between the diol with the organic and the inorganic polymers. Both thermal analysis and
FT-IR spectrometry have evidenced the formation of physical and chemical interaction between polyols and the siloxane network.
Elemental mapping performed by SEM-EDX technique evidenced the formation of homogenous hybrids both in the presence of the
absence of 1,3-propanediol. SEM images of the powders obtained by annealing the hybrid xerogels at 600 °C have evidenced the
formation of mesoporous silica. By thermal treatment of the (TEOS–PVA–PD–Metal Nitrates) gels, 30%CoFe2O4/70%SiO2 (mass percent) nanocomposites uniformly dispersed in silica matrix with characteristic magnetic properties, have been successfully
synthesized. 相似文献
98.
Ana‐Maria Gurban Lucian Rotariu Virgil Emanuel Marinescu Camelia Bala 《Electroanalysis》2012,24(12):2371-2379
A ternary composite material based on Prussian blue, single‐walled carbon nanotubes and 1‐butyl‐3‐methylimidazolium hexafluorophosphate was prepared and tested for electrochemical detection of H2O2. The sensor allows amperometric detection of H2O2 at ?0.05 V, with a sensitivity of 137 mA M?1?cm?2. The nanocomposite provides a favorable microenvironment for immobilization of horseradish peroxidase (HRP). Determination of xenoestrogenic compounds was performed by enzymatic oxidation at the surface of modified screen printed biosensor in the presence of H2O2. The developed electrochemical biosensors exhibited high sensitivity, low detection limits, good operational and storage stability, for detection of 4‐t‐butylphenol, 4‐t‐octylphenol, 4‐n‐nonylphenol and 4‐n‐nonylphenol ethoxylate. 相似文献
99.
Adina Arvinte Lucian Rotariu Camelia Bala Ana Maria Gurban 《Bioelectrochemistry (Amsterdam, Netherlands)》2009,76(1-2):107
Very sensitive, low cost and reliable NADH and H2O2 sensors were realised and used for development of enzyme based biosensors. The active surface of the electrodes was modified with a nanocomposite obtained by modification of SWNT with a proper mediator: Meldola Blue (for NADH) and Prussian Blue (for H2O2). Low applied potential of − 50 mV vs. Ag/AgCl reference electrode proved the synergistic effect of nanocomposite materials towards NADH and H2O2 detection. Biosensors for malic acid and alkylphenols have been developed, using mediator-functionalised-SWNT-based electrodes and two different classes of enzymes: NAD+-dependent dehydrogenases and peroxidases. Immobilization of the enzymes was realised using a series of different procedures — adsorption, Nafion membrane, sol–gel and glutaraldehyde, in order to find the best configuration for a good operational stability. A higher sensitivity comparing with other reported biosensors of about 12.41 mA/M·cm2 was obtained for l-malic acid biosensor with enzyme immobilised in Nafion membrane. Phenol, 4-t-octylphenol and 4-n-nonylphenol were used as standard compounds for HRP based biosensor. Fast biosensor response and comparable detection limit with HPLC methods were achieved. 相似文献
100.
Dr. Sabin‐Lucian Suraru Prof. Dr. Frank Würthner 《Angewandte Chemie (International ed. in English)》2014,53(29):7428-7448
Naphthalene diimides, which have for a long time been in the shadow of their higher homologues the perylene diimides, currently belong to the most investigated classes of organic compounds. This is primarily due to the initial synthetic studies on core functionalization that were carried out at the beginning of the last decade, which facilitated diverse structural modifications of the naphthalene scaffold. Compounds with greatly modified optical and electronic properties that can be easily and effectively modulated by appropriate functionalization were made accessible through relatively little synthetic effort. This resulted in diverse interesting applications. The electron‐deficient character of these compounds makes them highly valuable, particularly in the field of organic electronics as air‐stable n‐type semiconductors, while absorption bands over the whole visible spectral range through the introduction of core substituents enabled interesting photosystems and photovoltaic applications. This Review provides an overview on different approaches towards core functionalization as well as on synthetic strategies for the core expansion of naphthalene diimides that have been developed mainly in the last five years. 相似文献