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231.
Sánchez-Prado L Llompart M Lores M Fernández-Alvarez M García-Jares C Cela R 《Analytical and bioanalytical chemistry》2006,384(7-8):1548-1557
In this study the photoinduced degradation of triclosan has been investigated by photo-solid-phase microextraction (photo-SPME). In photo-SPME, photodegradation is carried out on the SPME fibre containing the target compound. Triclosan was extracted from aqueous solutions by use of polydimethylsiloxane SPME fibres and these were subsequently exposed to UV irradiation (power 8 W, wavelength 254 nm) for different times (from 2 to 60 min). The photodegradation kinetics of triclosan were investigated, the photoproducts generated were tentatively identified, and the photochemical behaviour of these products was studied by use of this on-fibre approach followed by gas chromatographic–mass spectrometric analysis. Eight photoproducts were tentatively identified, including chlorinated phenols, chlorohydroxydiphenyl ethers, 2,8-dichlorodibenzo-p-dioxin, and a possible dichlorodibenzodioxin isomer or dichlorohydroxydibenzofuran. The main photodegradation mechanisms were postulated and photodegradation pathways proposed. The effect of pH on triclosan degradation and on triclosan-to-dioxin conversion was also investigated. Triclosan degradation occurred, and generation of 2,8-dichlorodibenzo-p-dioxin was confirmed, throughout the pH range studied (from 3 to 9).
相似文献
232.
A parametrization methodology for evaluating the solvation free energy, using the polarizable continuum model implemented in Gamess software, is presented in a formulation which makes use of a group contribution conception to construct the cavities. The systems studied include alkanes, alcohols, aldehydes and ketones embeded in a continuous medium simulating the water as the solvent. For each family, the CH2, OH, and C=O moieties of atoms are put together in single spheres forming a group. The cavities are constructed in two different ways, one for the electrostatic component and the other for nonelectrostatic contributions, i.e., the cavitation, dispersion, and repulsion components of free energy of solvation. A multivariate analysis is performed to obtain an assembly of variables, for each homologous series, able to give the results which are close to experiment. The analysis is addressed in order to (i) compare the theoretical free energy of solvation with the experimental trends of the solutes in aqueous media, when the chain is increased, (ii) compare the behavior of each component of free energy with the increasing CH2 number, (iii) investigate the influence of the oxygen atom on the components, and (iv) quantify the relative contribution of each component to the final free energy of solvation for some homologous series. 相似文献
233.
234.
This article concerns the antisymmetry, uniqueness, and monotonicity properties of solutions to some elliptic functionals involving weights and a double well potential. In the one-dimensional case, we introduce the continuous odd rearrangement of an increasing function and we show that it decreases the energy functional when the weights satisfy a certain convexity-type hypothesis. This leads to the antisymmetry or oddness of increasing solutions (and not only of minimizers). We also prove a uniqueness result (which leads to antisymmetry) where a convexity-type condition by Berestycki and Nirenberg on the weights is improved to a monotonicity condition. In addition, we provide with a large class of problems where antisymmetry does not hold. Finally, some rather partial extensions in higher dimensions are also given. 相似文献
235.
236.
We define a divisor theory for graphs and tropical curves endowed with a weight function on the vertices; we prove that the Riemann–Roch theorem holds in both cases. We extend Baker’s Specialization Lemma to weighted graphs. 相似文献
237.
Bento Fábio R. Corradini Patricia G. Mascaro Lucia H. 《Journal of Solid State Electrochemistry》2019,23(6):1861-1870
Journal of Solid State Electrochemistry - A versatile and low-cost methodology for fabricating free-standing carbon graphite (CG)/SnO2/single-walled carbon nanotube (SWCNT) composites as anode... 相似文献
238.
239.
Andrea Sartori Lucia Battistini Gloria Rassu Giovanni Casiraghi 《Tetrahedron》2008,64(51):11697-11705
The direct Mukaiyama-Michael addition of vinylogous tetramate donors to a number of different Michael acceptors has been easily executed, by employing the TMSOTf/Et3N mixture as soft Lewis acid/base promoter agent. Richly functionalized, highly manipulable γ-substituted pyrrolinone products were practically synthesized in acceptable to excellent yields, and with diastereoselectivities heavily relying upon the substituent at the nitrogen atom of the pyrrolinone donor. 相似文献
240.
Dr. Ida Ritacco Dr. Maria Voccia Dr. Salvatore Impemba Dr. Matteo Farnesi Camellone Prof. Stefano Milione Prof. Lucia Caporaso 《欧洲无机化学杂志》2023,26(8):e202200588
In this work the mechanism of L-lactide polymerization promoted by NSSN zirconium complexes was investigated through DFT methods with the aim to understand as the electronic and steric features of the ligand affect the energy reaction. It was observed that the rate determining step of the process is the opening of the L-lactide ring and that by increasing the steric hindrance, evaluated by changing geometric parameters and topographic steric maps, or the electron-withdrawing properties of the ligand, the corresponding energy barrier increases. On the other hand, calculations foresee that a small and electron-releasing substituent on the nitrogen atom of the ligand, such as the methyl group, is desirable in order to obtain NSSN zirconium based catalysts with improved activity in the ROP of the L-lactide. 相似文献