On-fiber photodegradation after solid-phase microextraction of p,p'-DDT and two of its major photoproducts,p,p'-DDE and p,p'-DDD

The potential of performing photochemical studies in solid phase microextraction (SPME) fibers, "photo-SPME", to study the photodegradation of p,p'-DDT and two of its major degradation products, p,p'-DDE and p,p'-DDD, is shown. Analyses were carried out by gas chromatography mass spectroscopy detection. DDT was extracted from aqueous solutions using five different commercial coatings. The fibers were then exposed to UV light emitted by a low-pressure mercury lamp. After 30 min of irradiation, the degradation of DDT only occurred in polydimethylsiloxane fibers. The on-fiber degradation kinetics of p,p'-DDT was studied from 2 to 60 min. A large number of photoproducts were generated and their kinetic behavior was studied. In order to clarify the possible photoreaction pathways for DDT, individual water solutions containing p,p'-DDD or p.p'-DDE were prepared and photo-SPME was performed for each compound at different irradiation times. On the basis of the photoproducts identified, some photodegradation pathways are proposed. Finally, aqueous photodegradation studies followed by SPME were performed and compared to the photo-SPME. This work will show the enormous potential of photo-SPME to perform photodegradation studies.     

New Examples of Willmore Surfaces in S n

A surface x: M S ⁿ is called a Willmore surface if it is a criticalsurface of the Willmore functional _M (S – 2H ²)dv, where H isthe mean curvature and S is the square of the length of the secondfundamental form. It is well known that any minimal surface is aWillmore surface. The first nonminimal example of a flat Willmoresurface in higher codimension was obtained by Ejiri. This example whichcan be viewed as a tensor product immersion of S ¹(1) and a particularsmall circle in S ²(1), and therefore is contained in S ⁵(1) gives anegative answer to a question by Weiner. In this paper we generalize theabove mentioned example by investigating Willmore surfaces in S ⁿ (1)which can be obtained as a tensor product immersion of two curves. We inparticular show that in this case too, one of the curves has to beS ¹(1), whereas the other one is contained either in S ²(1) or in S ³(1). In the first case, we explicitly determine the immersion interms of elliptic functions, thus constructing infinetely many newnonminimal flat Willmore surfaces in S ⁵. Also in the latter casewe explicitly include examples.     

Lipschitz Kernel of a Closed Set-Valued Map

This paper deals with Lipschitz selections of set-valued maps with closed graphs. First, we characterize Lipschitzianity of a closed set-valued map in the differential games framework in terms of a discriminating property of its graph. This allows us to consider the -Lipschitz kernel of a given set-valued map as the largest -Lipschitz closed set-valued map contained in the initial one, to derive an algorithm to compute the collection of Lipschitz selections, and to extend the Pasch–Hausdorff envelope to set-valued maps.     

Accelerating flames in tubes—an analysis

Flame acceleration in tubes is studied. A tube filled with flammable mixture is closed at one end and open to the atmosphere at its second end. When ignition takes place near the closed end, it is well-known from experiments that the flame may accelerate, oscillate and eventually reach considerable speeds. A one-dimensional analysis is presented, based upon the assumption that the flame front propagates at a speed that is small compared to the speed of sound. The analysis leads to a construction of the complete unsteady solution. Results from the analysis and from a numerical simulation are compared. They are similar enough to validate the analysis. The tube acoustics are set in motion by the expansion of the fluid due to ignition at the closed end. Subsequently, both spectrum and amplitude evolve because of the motion of the temperature interface, and because of forcing by the flame front, which the analysis precisely quantifies. Oscillations in the front position are strong enough to result in flow reversal. In addition, the induced periodic acoustic acceleration of the temperature and density interface will periodically make the flame front Rayleigh–Taylor unstable, which should result in the dramatic increase in the propagation speed seen in experiments.     

Metabolic compartmentalization in the human cortex and hippocampus: evidence for a cell- and region-specific localization of lactate dehydrogenase 5 and pyruvate dehydrogenase

Background  

For a long time now, glucose has been thought to be the main, if not the sole substrate for brain energy metabolism. Recent data nevertheless suggest that other molecules, such as monocarboxylates (lactate and pyruvate mainly) could be suitable substrates. Although monocarboxylates poorly cross the blood brain barrier (BBB), such substrates could replace glucose if produced locally.     

Stability of the vortex defect in the Landau–de Gennes theory for nematic liquid crystals

We analyze the radially symmetric solution corresponding to the vortex defect (the so-called melting hedgehog) in the Landau–de Gennes theory for nematic liquid crystals. We prove the existence, uniqueness and stability results of the melting hedgehog.     

Existence of solutions in variational relation problems without convexity

Two main existence conditions for solutions of variational relation problems are established without convexity. The first one is based on a finite solvability property and the second one on generalized KKM mappings. These conditions unify and strengthen several existing results in the literature on the topic. A model of satisficing process by rejection is considered which gives an economic interpretation of the introduced concepts.     

An asymptotic preserving scheme for the Kac model of the Boltzmann equation in the diffusion limit

In this article, we propose a numerical scheme to solve the Kac model of the Boltzmann equation for multiscale rarefied gas dynamics. Formally, this scheme is shown to be uniformly stable with respect to the Knudsen number, consistent with the fluid-diffusion limit for small Knudsen numbers, and with the Kac equation in the kinetic regime. Our approach is based on the micro–macro decomposition which leads to an equivalent formulation of the Kac model that couples a kinetic equation with macroscopic ones. This method is validated with various test cases and compared to other standard methods.     

Polymorphism of sorbitol

The polymorphism of sorbitol was investigated, confirming the existence of four anhydrous crystalline phases plus the hydrate. The crystallised melt (CM), the alpha form, and the gamma form were obtained via a dry route. The CM was confirmed to be a crystalline state with a spherulite morphology. The alpha form was obtained via direct conversion from the CM, in contrast to more complicated routes previously reported, and was found to have a very high crystallinity. Gamma crystals were obtained by seeding the melt at high temperature; however, crystallinity was clearly less than for alpha crystals.