任意发光类型的多色光照明下光栅塔尔博特效应的研究

利用部分相干光理论对多色光源照明下光栅的菲涅耳衍射进行了理论分析,得到了适用于任意发光类型(脉冲或连续发光)的多色光源的衍射光强的一般公式,理论结果表明菲涅耳衍射区的平均衍射光强的形式只与光源的频谱分布有关,这对借助于连续发光光源来研究脉冲光源照明下光栅的塔尔博特效应以及用来确定脉冲光源的性能参量提供了有力的参考依据。此外,详细讨论了光源的频谱分布对光栅塔尔博特效应的影响并进行了相应的数值计算。实验中通过选用不同频率的激光分别照明光栅,拍摄到对应于不同频率的衍射光强分布图像,从而间接获得多色光同时照明光栅时总的衍射光强分布。实验结果表明,理论和实验符合较好。     

测定固体材料物理量的光学方法

本给出了用光学测量固体材料物理量的三种方法,并对其不同结果进行比较。其光纤测量方法结果误差最小。     

Luminescent properties of SrMg<Subscript>2</Subscript>(PO<Subscript>4</Subscript>)<Subscript>2</Subscript>:Eu<Superscript>2+</Superscript>, and Mn<Superscript>2+</Superscript> as a potential phosphor for ultraviolet light-emitting diodes

Eu²⁺ and Mn²⁺ co-doped SrMg₂(PO₄)₂ phosphors with blue and red two emission bands were prepared by the high temperature solid state method and their luminescent properties have been investigated as a function of activator and co-activator concentrations. Resonance-type energy transfers from Eu²⁺ to Mn²⁺ were discovered by directly overlapping the Eu²⁺ emission spectrum and the excitation spectrum of Mn²⁺. Efficiencies of energy transfer were also calculated according to the changes of relative intensities of Eu²⁺ and Mn²⁺ emission. According to the principle of energy transfer, we demonstrated that the phosphor SrMg₂(PO₄)₂:Eu²⁺,Mn²⁺ with double emission bands exhibited a great potential as a phosphor for ultraviolet light-emitting diodes and the relative intensities of blue and red emission could be tuned by adjusting the contents of Eu²⁺ and Mn²⁺. PACS 78.55.-m     

激光脉冲在等离子体中的压缩分裂

通过数值求解一维非线性薛定谔方程,研究了圆偏振入射激光脉冲在初始密度范围为1/4到略低于1倍临界密度的等离子体中的自压缩和分裂现象. 提高等离子体密度和入射激光强度以及减小脉冲宽度可以在更短的传输距离获得有效的激光脉冲压缩,压缩后的脉冲半高宽度可达到初始脉冲半高宽度的1/35,甚至更小. 这种压缩是激光脉冲在等离子体中形成高阶孤子的过程中产生的,可以获得比在稀薄等离子体中更好的压缩比例. 数值计算的结果给出了该情况下激光脉冲在等离子体中自压缩后形成的高阶孤子分裂. 利用一维粒子数值模拟程序(particle-in-cell,PIC)也观察到了脉冲的压缩和分裂现象,得到了与数值计算一致的结果. 关键词： 非线性薛定谔方程 自压缩 脉冲分裂 粒子模拟     

The influence of surface microchemistry in protective film formation on multi-phase magnesium alloys

The high strength:weight ratio of magnesium alloys makes them an ideal metal for automotive and aerospace applications where weight reduction is of significant concern. Unfortunately, magnesium alloys are highly susceptible to corrosion particularly in salt-spray conditions. This has limited their use in the automotive and aerospace industries, where exposure to harsh service conditions is unavoidable. The simplest way to avoid corrosion is to coat the magnesium-based substrate by a process such as electroless plating, which is a low-cost, non line of sight process.Magnesium is classified as a difficult to plate metal due to its high reactivity. This means that in the presence of air magnesium very quickly forms a passive oxide layer that must be removed prior to plating. Furthermore, high aluminium content alloys are especially difficult to plate due to the formation of intermetallic species at the grain boundaries, resulting in a non-uniform surface potential across the substrate and thereby further complicating the plating process.The objective of this study is to understand how the magnesium alloy microstructure influences the surface chemistry of the alloy during both pretreatment and immersion copper coating of the substrate.A combination of scanning electron microscopy, energy dispersive spectroscopy and scanning Auger microscopy has been used to study the surface chemistry at the various stages of the coating process. Our results indicate that the surface chemistry of the alloy is different on the aluminum rich β phase of the material compared to the magnesium matrix which leads to preferential deposition of the metal on the aluminum rich phase of the alloy.     

Transient binding and dissipation in cross-linked actin networks

In contrast with entangled actin solutions, transiently cross-linked actin networks can provide highly elastic properties while still allowing for local rearrangements in the microstructure-on biological relevant time scales. Here, we show that thermal unbinding of transient cross-links entails local stress relaxation and energy dissipation in an intermediate elasticity dominated frequency regime. We quantify the viscoelastic response of an isotropically cross-linked actin network by experimentally tuning the off rate of the transiently cross-linking molecules, their density, and the solvent viscosity. We reproduce the measured frequency response by a semiphenomenological model that is predicated on microscopic unbinding events.     

Highly thermal stable transparent conducting SnO2:Sb epitaxial films prepared on α-Al2O3 (0 0 0 1) by MOCVD

Antimony-doped tin oxide (SnO₂:Sb) single crystalline films have been prepared on α-Al₂O₃ (0 0 0 1) substrates by metal organic chemical vapor deposition (MOCVD). The antimony doping was varied from 2% to 7% (atomic ratio). Post-deposition annealing of the SnO₂:Sb films was carried out at 700-1100 °C for 30 min in atmosphere ambient. The effect of annealing on the structural, electrical and optical properties of the films was investigated in detail. All the SnO₂:Sb films had good thermal stability under 900 °C, and the 5% Sb-doped SnO₂ film exhibited the best opto-electrical properties. Annealed above 900 °C, the 7% Sb-doped SnO₂ film still kept high thermal stability and showed good electrical and optical properties even at 1100 °C.     

Copper-Catalyzed Enantioselective Trifluoromethoxylation of Propargyl Sulfonates

Due to the strong electron-withdrawing nature and high lipophilicity of trifluoromethoxy group (OCF₃), methods for introducing OCF₃ into organic molecules are in high demand. However, the research area of direct enantioselective trifluoromethoxylation is still in the embryonic stage, with limited enantioselectivity and/or reaction types. Here, we describe the first copper-catalyzed enantioselective trifluoromethoxylation of propargyl sulfonates using trifluoromethyl arylsulfonate (TFMS) as the trifluoromethoxy source in up to 96 % ee.     

Superhydrophobic and Conductive Wire Membrane for Enhanced CO2 Electroreduction to Multicarbon Products

Gas-liquid-solid triple-phase interfaces (TPI) are essential for promoting electrochemical CO₂ reduction, but it remains challenging to maximize their efficiency while integrating other desirable properties conducive to electrocatalysis. Herein, we report the elaborate design and fabrication of a superhydrophobic, conductive, and hierarchical wire membrane in which core–shell CuO nanospheres, carbon nanotubes (CNT), and polytetrafluoroethylene (PTFE) are integrated into a wire structure (designated as CuO/F/C(w); F, PTFE; C, CNT; w, wire) to maximize their respective functions. The realized architecture allows almost all CuO nanospheres to be exposed with effective TPI and good contact to conductive CNT, thus increasing the local CO₂ concentration on the CuO surface and enabling fast electron/mass transfer. As a result, the CuO/F/C(w) membrane attains a Faradaic efficiency of 56.8 % and a partial current density of 68.9 mA cm⁻² for multicarbon products at −1.4 V (versus the reversible hydrogen electrode) in the H-type cell, far exceeding 10.1 % and 13.4 mA cm⁻² for bare CuO.