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111.
112.
Dr. Tarun Kumar Yan Yang Sirine Sghaier Dr. Yassir Zaid Dr. Xavier F. Le Goff Dr. Elodie Rousset Dr. Fabien Massicot Dr. Dominique Harakat Agathe Martinez Dr. Marc Taillefer Prof. Laurent Maron Prof. Jean-Bernard Behr Dr. Florian Jaroschik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(12):4016-4021
The development of new fluorine-containing building blocks and their efficient synthetic access is currently a challenging research field. Herein, the highly regio- and stereoselective addition of a large range of aldehydes onto trifluoromethylated benzofulvenes was achieved using a simple La/I2/DIBAL-Cl system via a selective C−F bond activation process. This versatile methodology provided homodienyl alcohols bearing a terminal CF2-alkene with potential further applications, as shown by the dehydration to the first benzofulvenes carrying a difluorovinyl group. In addition, for certain electron-poor aldehydes, unprecedented ipso substitution of the CF3 group in a diene was observed, which, according to DFT studies, is related to the presence of the large, Lewis-acidic lanthanum metal. 相似文献
113.
Henri-Jean Cristau Marc Taillefer Jean-Paul Urbani 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract Phosphonium diylides 1 react with electrophiles leading to new monoylides which permit., by a Wittig reaction, the E stereoselective synthesis of various di- or tri-substituted α,β-unsaturated functionalized compounds. 相似文献
114.
Dr. Aron J. Huckaba Dr. Aswani Yella Dr. Louis E. McNamara April E. Steen J. Scott Murphy Casey A. Carpenter George D. Puneky Prof. Nathan I. Hammer Prof. Mohammad Khaja Nazeeruddin Prof. Michael Grätzel Prof. Jared H. Delcamp 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(43):15536-15542
Desirable components for dye‐sensitzed solar cell (DSC) sensitizers and fluorescent imaging dyes include strong donating building blocks coupled with well‐balanced acceptor functionalities for absorption beyond the visible range. We have evaluated the effects of increasing acceptor strengths and incorporation of dye morphology controlling groups on molar absorptivity and absorption breadth with indolizine donor‐based dyes. Indolizine‐based D –A and D –π–A sensitizers incorporating bis‐rhodanine, tricyanofuran (TCF), and cyanoacrylic acid functionalities were analyzed for performance in DSC devices. The TCF derivatives were also evaluated as near‐infrared (NIR)‐emissive materials with the AH25 emissions extending past 1000 nm. 相似文献
115.
Henri-Jean Cristau Amer Hammami Marc Taillefer Eliane Torreilles 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract The reaction of Ph3P-N-Li(12) with various α,β-unsaturated esters gives access to new N-(α,β-unsaturated acyl) phosphinimines. which can undergo intramolecular aza-Wittig reaction (at 65 - 110°C) to afford the corresponding nitriles. 相似文献
116.
Louis D. Quin Nandakumar Rao 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):371-373
Abstract We recently showed2 that the steroid ring system can be constructed with a phosphorus atom replacing a carbon in the D-ring by the cycloaddition of a phosphorus (III) halide with a diene that is a vinyl dihydrophenanthrene derivative, such as (1). The phosphine oxide (3) resulting from the hydrolysis of the initial cycloadduct (2) has some resemblance to the hormone equilenin, which also has rings A and B in naphthalene form. 相似文献
117.
Louis D. Quin Kenneth C. Caster 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):117-127
Abstract The pathway followed by dimers of P-methylphospholes in their thermal degradation in solution is strongly dependent on the concentration. At low concentrations (around 0.04 M) in n-decane or toluene as solvent, decomposition is extensive after 17 h in the range 120–130°C. The major product is the P-methylphosphole from de-dimerization. At concentrations above 1.0 M, decomposition is faster and intermolecular interactions are more important. These interactions dominate over de-dimerization and lead to the loss of the bridging P in the 7-phosphanorbornene moiety to yield the cis-3a,7a-dihydrophosphindole system. From the dimer of 1,3-dimethylphosphole, isomeric dihydrophosphindoles are formed, which differ in location of the methyl group on the 6-membered ring and in configuration at phosphorus. These seem to result from attack by a phosphine group as a nucleophile on the bridging P, followed by bond rearrangements in the resulting phosphoranide ion. Decomposition was faster in the presence of tri-n-butylphosphine, which apparently acted as a catalyst through a similar mechanism. By using appropriate conditions each dihydrophosphindole isomer (1,3,5- or 1,3,7-trimethyl) could be made to predominate and this allowed their isolation. Characterization of the isomers and of some derivatives by 31P, 1H, and 13C NMR techniques was performed. Most of the thermolysis products were highly complex mixtures and many minor products remain unidentified. The dimer of 1-phenyl-3-methyl-phosphole did not decompose to the phosphole, but the product composition was dependent on concentration. 相似文献
118.
Louis D. Quin Ronald C. Stocks 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):151-156
Abstract The cycloaddition of phenylphosphonous dichloride and trans, trans-2,4-hexadiene, or the addition of chlorine to trans-1-phenyl-cis-2,5-dimethyl-3-phospholene, gave 1-chloro-1-phenyl-2,5-dimethyl-2-phospholenium chloride. This compound shows no evidence in its 31P and 1H nmr spectra for the existence of cis, trans isomers, yet on hydrolysis or dehalogenation with magnesium the resulting oxide and phosphine, respectively, are seen to be isomer mixtures. This phenomenon is explained by a rapid equilibration of the cis, trans form of the I-chloro ion through a pentacovalent species. Structures of the oxides and phosphines were assigned by 1H and 13C nmr relations. The 1-phenyl-cis-2,5-dimethyl-3-phospholenium ion and related compounds were also characterized. 相似文献
119.
Two novel amphiphilic BAB-type block copolymers, ADN-PEG3400-ADN and Py-PEG3400-Py containing deep blue and bluish-green fluorescent moieties were prepared using atom transfer radical polymerization (ATRP) (where, ADN = poly(9,10-di(1-naphthalenyl)-2-vinylanthracene), Py = poly(1-vinyl pyrene) and PEG3400 = poly(ethylene glycol) with Mn = 3400 g/mol). The GPC number averaged molecular weights (MW) of the block copolymers were Mn = 9600 and 13,800 g/mol, respectively, based on polystyrene MW standards. The PEG3400 segment has a melting temperature (Tm peak) at 64–65 °C, whereas the glass transition temperatures (Tg midpoint) of the ADN and Py segments were found to be 230 °C and 193 °C, respectively, and are similar to their respective homopolymers indicating complete microphase segregration. The photoluminescence (PL) emission of the copolymers ADN-PEG3400-ADN exhibited two maxima at 423.5 nm and 441.5 nm while Py-PEG3400-Py has a maximum at 488.5 nm. Both copolymers form individual spherical micelles with diameter from 30 to 90 nm for Py-PEG3400-Py and 40–160 nm for ADN-PEG3400-ADN. The micelles, however, transform into cross-linked pearl-necklace-like aggregates at polymer concentrations above 1000 ppm, which may be attributed to the physical cross-linking between adjacent spherical micelles caused by the PEG3400 segments. 相似文献
120.
Louis P. Lee Daniel J. Cole Mike C. Payne Chris‐Kriton Skylaris 《Journal of computational chemistry》2013,34(6):429-444
First principles electronic structure calculations are typically performed in terms of molecular orbitals (or bands), providing a straightforward theoretical avenue for approximations of increasing sophistication, but do not usually provide any qualitative chemical information about the system. We can derive such information via post‐processing using natural bond orbital (NBO) analysis, which produces a chemical picture of bonding in terms of localized Lewis‐type bond and lone pair orbitals that we can use to understand molecular structure and interactions. We present NBO analysis of large‐scale calculations with the ONETEP linear‐scaling density functional theory package, which we have interfaced with the NBO 5 analysis program. In ONETEP calculations involving thousands of atoms, one is typically interested in particular regions of a nanosystem whilst accounting for long‐range electronic effects from the entire system. We show that by transforming the Non‐orthogonal Generalized Wannier Functions of ONETEP to natural atomic orbitals, NBO analysis can be performed within a localized region in such a way that ensures the results are identical to an analysis on the full system. We demonstrate the capabilities of this approach by performing illustrative studies of large proteins—namely, investigating changes in charge transfer between the heme group of myoglobin and its ligands with increasing system size and between a protein and its explicit solvent, estimating the contribution of electronic delocalization to the stabilization of hydrogen bonds in the binding pocket of a drug‐receptor complex, and observing, in situ, the n → π* hyperconjugative interactions between carbonyl groups that stabilize protein backbones. © 2012 Wiley Periodicals, Inc. 相似文献