Cobalt phthalocyanine derivatives supported on TiO2 by sol–gel processing: Part 2. Activity in sulfide and ethanethiol oxidation

The catalytic activity of cobalt(II) 2,9,16,23-tetrasulphophthalocyanine and cobalt(II) 2,9,16,23-tetra(chlorosulphonyl)phthalocyanine covalently bonded to a TiO₂ matrix by sol–gel processing was investigated for sulfide and ethanethiol (CH₃CH₂SH) liquid-phase oxidation. A comparison of the kinetic data as well as the state of active component by using electron spectroscopy in dependence on precursors was carried out. Kinetic data shows that the most stable and active catalysts for ethanethiol oxidation are both CoPc(SO₃H)₄ and CoPc(SO₂Cl)₄ in TiO₂ from Ti(OⁱPr)₄, whereas in the case of Na₂S oxidation in neutral medium the activity of the former is higher.     

On galois descent for Hochschild and cyclic homology

LetG be a finite group acting by automorphisms on an algebraS over some commutative ringk. We show that if the action ofG restricted to the center ofS is Galois in the sense of [C-H-R], thenHH _*(S ^G)≊HH _* (S) ^G. An analogous result holds for cyclic homology, provided the order ofG is invertible ink. The author was supported in part by a grant from the NSF.     

Ueber die Trübung des Chlorsilbers und zur Theorie des latenten Bildes

Ohne Zusammenfassung     

Kolloidstudien über die Harzleimung des Papieres,I

Ohne Zusammenfassung     

Über die Größe der Kationen der Alkalimetalle

Zeitschrift für Physik A Hadrons and nuclei -     

Reynold''s Transport Theorem for Differential Inclusions

The well-known Reynold's Transport Theorem deals with the integral over a time-dependent set (that is evolving along a smooth vector field) and specifies its semiderivative with respect to time. Here reachable sets of differential inclusions are considered instead. Dispensing with any assumptions about the regularity of the compact initial set, we give sufficient conditions on the differential inclusion for the absolute continuity (of the integral) with respect to time and its weak derivative is formulated as a Hausdorff integral over the topological boundary.