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921.
Chun‐Xiang Zhuo Prof. Dr. Wei Zhang Prof. Dr. Shu‐Li You 《Angewandte Chemie (International ed. in English)》2012,51(51):12662-12686
This Review summarizes the development of catalytic asymmetric dearomatization (CADA) reactions. The CADA reactions discussed herein include oxidative dearomatization reactions, dearomatization by Diels–Alder and related reactions, the alkylative dearomatization of electron‐rich arenes, transition‐metal‐catalyzed dearomatization reactions, cascade sequences involving asymmetric dearomatization as the key step, and nucleophilic dearomatization reactions of pyridinium derivatives. Asymmetric dearomatization reactions with chiral auxiliaries and catalytic asymmetric reactions of dearomatized substrates are also briefly introduced. This Review intends to provide a concept for catalytic asymmetric dearomatization. 相似文献
922.
Influence of Preparation Conditions on Structural Stability of Ordered Mesoporous Carbons Synthesized by Evaporation-induced Triconstituent Co-assembly Method 下载免费PDF全文
Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced triconstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmis-sion electron microscopy, and N2 sorption isotherms techniques. The results show mesostruc-tural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum (2.0 h) and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2~1.2 mol/L HCl, when the acidity is near the isoelectric point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condi-tion, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostructure stability and the highest BET surface areas of 2281 m2/g. 相似文献
923.
Let L be a second order positive, elliptic differential operator that is self-adjoint with respect to some C~∞ density dx on a compact connected manifold M. We proved that if 0 α 1,α/2 s α and f ∈ H~s(M) then the fractional Schr?dinger propagator e~(it Lα/2) on M satisfies e~(it Lα/2) f(x)-f(x) = o(t~(s/α-ε)) almost everywhere as t → 0~+, for any ε 0. 相似文献
924.
Two new cadmium(II) complexes, Cd2(L1)2(NCS)2 (1) and Cd2(L2)2(NCS)2 (2), where L1 and L2 are the deprotonated forms of 2-[(3-dimethylaminopropylimino)methyl]-6-ethoxyphenol and 2-methoxy-6-[(pyridin-2-ylmethylimino)methyl]phenol,
respectively, have been isolated as crystalline products and characterized by elemental analysis, IR spectroscopy, and single
crystal X-ray diffraction method. Both compounds are structurally similar and are phenolate-O-bridged dinuclear cadmium(II)
complexes. Each Cd(II) cation in the complexes is octahedrally coordinated. The Cd Cd distances in (1) and (2) are 3.618(2) d 3.571(2) 相似文献
925.
制备了结构为ITO/CuPc/NPB/Alq3/LiF/Al的常规有机发光二极管, 之后对器件采用波长为442 nm和325 nm的激光线进行照射产生激子, 并在小偏压下(保证器件没有开启)对激子的演化过程进行控制, 同时测量器件的光致磁电导(photo-induced magneto-conductance, PIMC). 实验发现, 不同于电注入产生激子的磁电导效应, PIMC在正、反小偏压下表现出明显不同的磁响应结果. 当给器件加上正向小偏压时, 器件的PIMC在0-40 mT范围内迅速上升; 随着磁场的进一步增大, 该PIMC增加缓慢, 并逐渐趋于饱和. 反向小偏压时, 器件的PIMC随着磁场也是先迅速增大(0-40 mT), 但达到最大值后却又逐渐减小. 通过分析外加磁场对器件光生载流子微观过程的影响, 采用'电子-空穴对'模型和超精细相互作用理论对正向偏压下的PIMC进行了解释; 反向偏压下因各有机层的能级关系, 为激子与电荷相互作用提供了必要条件, 运用三重态激子与电荷的反应机制可以解释PIMC出现高场下降的实验现象. 相似文献
926.
Treatments of Mn(O(2)CR)(2) (R = Me, Ph) with NBu(4)MnO(4) in CH(3)CN or CH(3)CN/CH(2)Cl(2) in the presence of acetic acid, delta(1)-cyclohexenephosphonic acid (C(6)H(9)PO(3)H(2)), and 2,2'-bipyridine or 1,10-phenanthroline result in three novel dodecamanganese(III) clusters [Mn(12)O(8)(O(2)CMe)(6)(O(3)PC(6)H(9))(7)(bipy)(3)] (1), [Mn(12)O(8)(O(2)CPh)(6)(O(3)PC(6)H(9))(7)(bipy)(3)] (2), and [Mn(12)O(8)(O(2)CPh)(6)(O(3)PC(6)H(9))(7)(phen)(3)] (3). They have a similar Mn(12) core of [Mn(III)(12)(mu(4)-O)(3)(mu(3)-O)(5)(mu-O(3)P)(3)] with a new type of topologic structure. Solid-state dc magnetic susceptibility measurements of complexes 1-3 reveal that dominant antiferromagnetic interactions are propagated between the magnetic centers. The ac magnetic measurements suggest an S = 2 ground state for compounds 1 and 3 and an S = 3 ground state for compound 2. 相似文献
927.
928.
Y. J. You Y. X. Zhang R. R. Li C. H. Li 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(12):2188-2191
A novel flower-like photocatalyst CNTs/BiOBr was successfully prepared by a facile hydrothermal method. The morphology and the physicochemical properties of the prepared samples were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectrometry (EDX), and UV-visible diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic activity was evaluated by degradation of Rhodamin B (RhB) dye. It was demonstrated that CNTs/BiOBr photocatalyst could effectively photodegrade RhB under visible light (VL) irradiation. 相似文献
929.
Palladium‐Catalyzed Oxidative Carbonylation of N‐Allylamines for the Synthesis of β‐Lactams 下载免费PDF全文
Wu Li Dr. Chao Liu Prof. Heng Zhang Keyin Ye Guanghui Zhang Wangzheng Zhang Zhengli Duan Prof. Shuli You Prof. Aiwen Lei 《Angewandte Chemie (International ed. in English)》2014,53(9):2443-2446
β‐Lactam scaffolds are considered to be ideal building blocks for the synthesis of nitrogen‐containing compounds. A new palladium‐catalyzed oxidative carbonylation of N‐allylamines for the synthesis of α‐methylene‐β‐lactams is reported. DFT calculations suggest that the formation of β‐lactams via a four‐membered‐ring transition state is favorable. 相似文献
930.
Peel test measurements and simulations of the interfacial mechanical parameters for the Al/Epoxy/Al2O3 system are performed in the present investigation. A series of Al film thicknesses between 20 and 250 microns and three peel angles of 90, 135 and 180 degrees are considered. Two types of epoxy adhesives are adopted to obtain both strong and weak interface adhesions. A finite element model with cohesive zone elements is used to identify the interfacial parameters and simulate the peel test process. By simulating and recording normal stress near the crack tip, the separation strength is obtained, Furthermore, the cohesive energy is identified by comparing the simulated steady-state peel force and the experimental result. It is found from the research that both the cohesive energy and the separation strength can be taken as the intrinsic interfacial parameters which are dependent on the thickness of the adhesive layer and independent of the film thickness and peel angle. 相似文献